4-(phenylmethyl)-1,3-benzenedicarboxylic acid | 53937-45-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(phenylmethyl)-1,3-benzenedicarboxylic acid
• 英文别名: 4-benzyl-isophthalic acid；Diphenylmethan-dicarbonsaeure-(2.4)；4-Benzyl-isophthalsaeure；4-Benzylbenzene-1,3-dicarboxylic acid
• CAS: 53937-45-4
• 化学式: C₁₅H₁₂O₄
• 分子量: 256.258
• InChiKey: ZVMUDJULUBVJFN-UHFFFAOYSA-N

物化性质

• 沸点：
  472.2±40.0 °C(Predicted)
• 密度：
  1.321±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  4-(phenylmethyl)-1,3-benzenedicarboxylic acid 在 硫酸 作用下， 反应 4.5h， 生成 methyl 9-anthrone-2-carboxylate
  参考文献：
  名称：

  Kinetics of decomposition of rigid diazo compounds: substituent effects on the rates of thermolysis of 10-diazoanthrones

  摘要：

  DOI：

  10.1021/jo00350a052
• 作为产物：
  描述：

  4-苯甲酰基间苯二甲酸 在 ammonium hydroxide 、 copper(II) sulfate 、 锌 作用下， 反应 26.0h， 以77%的产率得到4-(phenylmethyl)-1,3-benzenedicarboxylic acid
  参考文献：
  名称：

  Kinetics of decomposition of rigid diazo compounds: substituent effects on the rates of thermolysis of 10-diazoanthrones

  摘要：

  DOI：

  10.1021/jo00350a052

文献信息

• RESIN COMPOSITION AND METHOD FOR PRODUCING SAME
  申请人：TEIJIN LIMITED

  公开号：EP2006332A1

  公开（公告）日：2008-12-24

  The object of this invention consists in providing a polyamide resin composition excellent in insulating properties, mechanical properties and dimensional stability. This invention is a resin composition containing 100 parts by weight of a polyamide resin and 0.01 to 50 parts by weight of boron nitride nanotubes.

  本发明的目的是提供一种在绝缘性能、机械性能和尺寸稳定性方面都非常出色的聚酰胺树脂组合物。 本发明是一种树脂组合物，含有 100 重量份的聚酰胺树脂和 0.01 至 50 重量份的氮化硼纳米管。
• POLYAMIDE RESIN AND FILM COMPRISING SAME
  申请人：UBE Industries, Ltd.

  公开号：EP3424981A1

  公开（公告）日：2019-01-09

  Provided is a polyamide resin having excellent heat shrinkability. A polyamide resin which contains three or more types of units, wherein the polyamide resin comprises (A) units derived from a lactam and/or an aminocarboxylic acid, and (B) units derived from an equimolar salt of a diamine and a dicarboxylic acid, wherein (B) the units derived from an equimolar salt of a diamine and a dicarboxylic acid comprise (B-1) units having no alicyclic structure and (B-2) units having an alicyclic structure.

  本发明提供了一种具有优异热收缩性的聚酰胺树脂。一种含有三种或三种以上单元的聚酰胺树脂，其中聚酰胺树脂包括（A）由内酰胺和/或氨基羧酸衍生的单元，以及（B）由二胺和二羧酸的等摩尔盐衍生的单元，其中（B）由二胺和二羧酸的等摩尔盐衍生的单元包括（B-1）无脂环结构的单元和（B-2）有脂环结构的单元。
• Zincke; Blatzbecker, Chemische Berichte, 1876, vol. 9, p. 1763
  作者：Zincke、Blatzbecker

  DOI：——

  日期：——
• RESIN COMPOSITION AND PROCESS FOR THE PRODUCTION THEREOF
  申请人：Kuwahara Hiroaki

  公开号：US20090221734A1

  公开（公告）日：2009-09-03

  The object of this invention is to provide a polyamide resin composition excellent in insulating properties, mechanical properties and dimensional stability. This invention is a resin composition containing 100 parts by weight of a polyamide resin and 0.01 to 50 parts by weight of boron nitride nanotubes. The invention also includes a formed article from the resin composition and processes for the production of the resin composition and the formed article.
• POLYAMIDE RESIN AND FILM COMPRISING THE SAME
  申请人：UBE INDUSTRIES, LTD.

  公开号：US20190055403A1

  公开（公告）日：2019-02-21

  Provided is a polyamide resin having excellent heat shrinkability. A polyamide resin which contains three or more types of units, wherein the polyamide resin comprises (A) units derived from a lactam and/or an aminocarboxylic acid, and (B) units derived from an equimolar salt of a diamine and a dicarboxylic acid, wherein (B) the units derived from an equimolar salt of a diamine and a dicarboxylic acid comprise (B-1) units having no alicyclic structure and (B-2) units having an alicyclic structure.