4-bromo-2,6-diphenylaniline | 647835-34-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-bromo-2,6-diphenylaniline
• 英文别名: [1,1':3',1''-Terphenyl]-2'-amine, 5'-bromo-
• CAS: 647835-34-5
• 化学式: C₁₈H₁₄BrN
• 分子量: 324.22
• InChiKey: BEQUGURIORILON-UHFFFAOYSA-N

物化性质

• 沸点：
  404.2±40.0 °C(Predicted)
• 密度：
  1.359±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4-bromo-2,6-diphenylaniline 在 四(三苯基膦)钯 氢氧化钾 、 正丁基锂 、 四丁基溴化铵 作用下， 以 四氢呋喃 为溶剂， 反应 24.0h， 生成
  参考文献：
  名称：

  Isolation and Magnetic Properties of Heterocycle-Carrying N-Alkoxyarylaminyl Radicals¹

  摘要：

  Two N-tert-butoxy-2,6-diaryl-4-(4-pyridyl)phenylaminyls (1) and three N-tert-butoxy-2,6-diaryl-4-(1H-imidazol-1-yl)phenylaminyls (2) were prepared by the reaction of the lithium salts of the corresponding anilines with tertbutyl peroxybenzoate. Although 1 could not be isolated as radical crystals, 2 was successfully obtained as red crystals. The X-ray crystallographic analysis and magnetic susceptibility measurements were performed for one isolated radical.

  DOI：

  10.1021/jo0302105
• 作为产物：
  描述：

  2,6-二苯基苯胺 在 benzyltrimethylammonium tribromide 、 calcium carbonate 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 反应 2.0h， 以82%的产率得到4-bromo-2,6-diphenylaniline
  参考文献：
  名称：

  Isolation and Magnetic Properties of Heterocycle-Carrying N-Alkoxyarylaminyl Radicals¹

  摘要：

  Two N-tert-butoxy-2,6-diaryl-4-(4-pyridyl)phenylaminyls (1) and three N-tert-butoxy-2,6-diaryl-4-(1H-imidazol-1-yl)phenylaminyls (2) were prepared by the reaction of the lithium salts of the corresponding anilines with tertbutyl peroxybenzoate. Although 1 could not be isolated as radical crystals, 2 was successfully obtained as red crystals. The X-ray crystallographic analysis and magnetic susceptibility measurements were performed for one isolated radical.

  DOI：

  10.1021/jo0302105

文献信息

• [EN] NOVEL ORGANIC ANTHRACENE COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE COMPRISING SAME<br/>[FR] NOUVEAU COMPOSÉ ANTHRACÈNE ORGANIQUE ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE LE COMPRENANT<br/>[KO] 신규한 유기 안트라센 화합물 및 이를 포함하는 유기발광소자
  申请人：SFC CO LTD

  公开号：WO2023096387A1

  公开（公告）日：2023-06-01

  본 발명은 유기발광소자에 사용될 수 있는, [화학식 A] 또는 [화학식 B]로 표시되는 유기 발광 화합물 및 이를 포함하는 유기발광소자에 관한 것이며, 이때 상기 [화학식 A] 및 [화학식 B]는 발명의 상세한 설명에 기재된 바와 동일하다.

  该发明涉及可用于有机发光器件的有机发光化合物，其表示为[化学式A]或[化学式B]，以及包含其的有机发光器件，其中，上述[化学式A]和[化学式B]与发明的详细说明中所述的相同。
• ORGANOMETALLIC COMPOUND, LIGHT-EMITTING DEVICE INCLUDING THE SAME AND ELECTRONIC APPARATUS INCLUDING THE LIGHT-EMITTING DEVICE
  申请人：Samsung Display Co., Ltd.

  公开号：US20220209142A1

  公开（公告）日：2022-06-30

  A light-emitting device includes: a first electrode; a second electrode facing the first electrode; an interlayer between the first electrode and the second electrode and including an emission layer; and at least one organometallic compound of Formula 1, as defined herein. The first electrode includes an anode, and the second electrode includes a cathode.
• Isolation and Magnetic Properties of Heterocycle-Carrying <i>N</i>-Alkoxyarylaminyl Radicals¹
  作者：Yozo Miura、Toshiyuki Nishi、Yoshio Teki

  DOI：10.1021/jo0302105

  日期：2003.12.1

  Two N-tert-butoxy-2,6-diaryl-4-(4-pyridyl)phenylaminyls (1) and three N-tert-butoxy-2,6-diaryl-4-(1H-imidazol-1-yl)phenylaminyls (2) were prepared by the reaction of the lithium salts of the corresponding anilines with tertbutyl peroxybenzoate. Although 1 could not be isolated as radical crystals, 2 was successfully obtained as red crystals. The X-ray crystallographic analysis and magnetic susceptibility measurements were performed for one isolated radical.