Z-(Me3Si)((C6H4Cl-p)Se)CC(H)(Se(C6H4Cl-p)) | 888027-56-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Z-(Me3Si)((C6H4Cl-p)Se)CC(H)(Se(C6H4Cl-p))
• 英文别名: [(Z)-1,2-bis[(4-chlorophenyl)selanyl]ethenyl]-trimethylsilane
• CAS: 888027-56-3
• 化学式: C₁₇H₁₈Cl₂Se₂Si
• 分子量: 479.241
• InChiKey: GVSRNTJPPGYCHN-SFQUDFHCSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.07
• 重原子数：
  22
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  乙烯双(三苯基磷)铂 、 Z-(Me3Si)((C6H4Cl-p)Se)CC(H)(Se(C6H4Cl-p)) 在 tris(4-methoxyphenyl)phosphine sulfide 作用下， 以 氘代苯 为溶剂， 生成 trans-[Pt(triphenylphosphine)2(Se(C6H4Cl-p))2]
  参考文献：
  名称：

  无环乙烯基硒化物氧化加成到M（0）络合物的第一个确定性例子

  摘要：

  The principle of C–S bond activation of acyclic vinlyl sulfide by platinum(0)-complex was applied to the C–Se bond fission of vinyl selenide. The substrate possessing Ph and ArSe (Ar = C6H4Cl-p) substituents at the β-carbon successfully reacted with Pt(0)-complex at 25 °C to produce the vinyl platinum in good yield and its structure was unambiguously determined by X-ray crystallographic analysis. When

  DOI：

  10.1016/j.jorganchem.2005.12.058

文献信息

• The first definitive example of oxidative addition of acyclic vinyl selenide to M(0) complex
  作者：Hitoshi Kuniyasu、Tomohiro Kato、Masafumi Inoue、Jun Terao、Nobuaki Kambe

  DOI：10.1016/j.jorganchem.2005.12.058

  日期：2006.4

  The principle of C–S bond activation of acyclic vinlyl sulfide by platinum(0)-complex was applied to the C–Se bond fission of vinyl selenide. The substrate possessing Ph and ArSe (Ar = C6H4Cl-p) substituents at the β-carbon successfully reacted with Pt(0)-complex at 25 °C to produce the vinyl platinum in good yield and its structure was unambiguously determined by X-ray crystallographic analysis. When

  The principle of C–S bond activation of acyclic vinlyl sulfide by platinum(0)-complex was applied to the C–Se bond fission of vinyl selenide. The substrate possessing Ph and ArSe (Ar = C6H4Cl-p) substituents at the β-carbon successfully reacted with Pt(0)-complex at 25 °C to produce the vinyl platinum in good yield and its structure was unambiguously determined by X-ray crystallographic analysis. When