[[4-[(E)-[[2,6-bis[bis(trimethylsilyl)methyl]-4-[tris(trimethylsilyl)methyl]phenyl]-bromosilylidene]-bromosilyl]-3,5-bis[bis(trimethylsilyl)methyl]phenyl]-bis(trimethylsilyl)methyl]-trimethylsilane | 1071937-25-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [[4-[(E)-[[2,6-bis[bis(trimethylsilyl)methyl]-4-[tris(trimethylsilyl)methyl]phenyl]-bromosilylidene]-bromosilyl]-3,5-bis[bis(trimethylsilyl)methyl]phenyl]-bis(trimethylsilyl)methyl]-trimethylsilane
• CAS: 1071937-25-1
• 化学式: C₆₀H₁₃₄Br₂Si₁₆
• 分子量: 1464.9
• InChiKey: QAXVVWFHLKLWMC-ZOPJMJKSSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  21.75
• 重原子数：
  78
• 可旋转键数：
  22
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  [[4-[(E)-[[2,6-bis[bis(trimethylsilyl)methyl]-4-[tris(trimethylsilyl)methyl]phenyl]-bromosilylidene]-bromosilyl]-3,5-bis[bis(trimethylsilyl)methyl]phenyl]-bis(trimethylsilyl)methyl]-trimethylsilane 在 叔丁基锂 作用下， 以 四氢呋喃 为溶剂， 反应 4.5h， 生成
  参考文献：
  名称：

  Synthesis and Reactions of a Stable 1,2-Diaryl-1,2-dibromodisilene: A Precursor for Substituted Disilenes and a 1,2-Diaryldisilyne

  摘要：

  Synthesis and isolation of the stable diaryldibromodisilene, Bbt (Br)Si =(Br)Bbt, has been accomplished for the first time. The dibromodisilene underewent substitution reactions with organometallic reagents on the low-coordinated silicon atom to afford the corresponding substituted disilenes. Futhermore, the reaction of 1 with t-BuLi afforded the corresponding 1,2-diaryldisilyne, BbtSi SiBbt, the characters of which were revealed by spectroscopic and crystallographic analyses.

  DOI：

  10.1021/ja8061002
• 作为产物：
  描述：

  BbtSiBr3 在 lithium dihydronaphthylide radical 作用下， 以 四氢呋喃 为溶剂， 反应 5.5h， 以52%的产率得到[[4-[(E)-[[2,6-bis[bis(trimethylsilyl)methyl]-4-[tris(trimethylsilyl)methyl]phenyl]-bromosilylidene]-bromosilyl]-3,5-bis[bis(trimethylsilyl)methyl]phenyl]-bis(trimethylsilyl)methyl]-trimethylsilane
  参考文献：
  名称：

  Synthesis and Reactions of a Stable 1,2-Diaryl-1,2-dibromodisilene: A Precursor for Substituted Disilenes and a 1,2-Diaryldisilyne

  摘要：

  Synthesis and isolation of the stable diaryldibromodisilene, Bbt (Br)Si =(Br)Bbt, has been accomplished for the first time. The dibromodisilene underewent substitution reactions with organometallic reagents on the low-coordinated silicon atom to afford the corresponding substituted disilenes. Futhermore, the reaction of 1 with t-BuLi afforded the corresponding 1,2-diaryldisilyne, BbtSi SiBbt, the characters of which were revealed by spectroscopic and crystallographic analyses.

  DOI：

  10.1021/ja8061002

文献信息

• Reactions of Diaryldibromodisilenes with N-Heterocyclic Carbenes: Formation of Formal Bis-NHC Adducts of Silyliumylidene Cations
  作者：Tomohiro Agou、Naoki Hayakawa、Takahiro Sasamori、Tsukasa Matsuo、Daisuke Hashizume、Norihiro Tokitoh

  DOI：10.1002/chem.201403083

  日期：2014.7.21

  2‐dibromodisilenes ((E)‐Ar(Br)SiSi(Br)Ar) with N‐heterocyclic carbenes (NHC) afforded NHC–arylbromosilylene adducts or bromide salts of the corresponding bis‐NHC adducts of the formal arylsilyliumylidene cations ([ArSi:]+). In some cases, an NHC was able to replace a bromide anion in the coordination sphere of the arylbromosilylene–NHC adduct.

  稳定的1,2-二溴二ilenes （（E）-Ar（Br）SiSi（Br）Ar）与N-杂环卡宾（NHC）的反应提供了NHC-芳基溴亚甲硅烷基加合物或相应的双NHC加合物的溴化物盐正式的芳基亚甲硅烷基阳离子（[ArSi：] +）。在某些情况下，NHC能够取代芳基溴代甲硅烷基-NHC加合物的配位区内的溴化物阴离子。