(E)-2-((4-iodophenyl)diazenyl)-1H-imidazole | 1255921-62-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (E)-2-((4-iodophenyl)diazenyl)-1H-imidazole
• CAS: 1255921-62-0
• 化学式: C₉H₇IN₄
• 分子量: 298.086
• InChiKey: JRZPSFZHRZMARR-BUHFOSPRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.43
• 重原子数：
  14.0
• 可旋转键数：
  2.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  53.4
• 氢给体数：
  1.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  (E)-2-((4-iodophenyl)diazenyl)-1H-imidazole 、 cadmium(II) nitrate 以 甲醇 为溶剂， 以80%的产率得到[Cd(IC6H4NNC3H3N2)2(nitrate)2]
  参考文献：
  名称：

  Aryl azo imidazole assisted self-assembly of d10 metal complexes: Influence of halogen substitution and counter ions

  摘要：

  A series of eight coordination networks has been obtained by the self-assembly of the aryl azo imidazole based building block and with d(10) metal [Zn(II), Cd(II), and Hg(II)] and counter anion (Cl-, NO3-, SCN-) in order to rationalize the effect of coordination behavior of the metal ion, the size of the anions and the substitution effects of ligands upon the structure adopted by these metal complexes. Influences of halogen (Cl-, Br-, and I-) substitutions are reflected in the precise molecular level architecture in the individual complexes. The parameters related to the coordination sphere depend on the metal-to-ligand ratios and are also influenced by the solvent of crystallization. A competition between the coordinating capabilities of the counter anion with ligands and its shape led to neutral and anionic metal complexes. Furthermore, various physicochemical studies viz, thermal behaviors, absorption spectra have been conducted to rationalize their structure in solution phase. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.08.004