bis(O,O'-dibenzyldithiophosphato)(2,2'-bipyridine)nickel(II) | 848421-78-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: bis(O,O'-dibenzyldithiophosphato)(2,2'-bipyridine)nickel(II)
• 英文别名: bis(phenylmethoxy)-sulfanylidene-sulfido-λ5-phosphane;nickel(2+);2-pyridin-2-ylpyridine
• CAS: 848421-78-3
• 化学式: C₃₈H₃₆N₂NiO₄P₂S₄
• 分子量: 833.616
• InChiKey: MMPDJFQSDQZHDY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  bis(O,O'-dibenzyldithiophosphato)(2,2'-bipyridine)nickel(II) 、 水 以 乙醇 、 水 为溶剂， 以96%的产率得到bis(O,O'-dibenzyldithiophosphato)(2,2'-bipyridine)nickel(II) dihydrate
  参考文献：
  名称：

  Synthesis, Crystal Structure and Thermal Studies ofbis(O,O′‐Dibenzyldithiophosphato)‐(2,2′‐Bipyridine)nickel(II) Complex

  摘要：

  The bis(O,O'-dibenzyldithiophosphato)Ni(II) adduct, [(PhCH2O)(2)PS2](2) Ni(bpy), was synthesized by the reaction of [(PhCH2O)(2)PS2](2)Ni. with 2,2'-bipyridine in the solid state. Single crystals of the title compound as the dihydrate were obtained by recrystallization in ethanol-distilled water (v/v = 9: 1). The structure characterization was performed by means of IR; elemental analyses, and single crystal x-ray analysis. The crystal of the title compound consists of two disconnected structural units, each of which includes two non-coordination water molecules. The coordination geometry of each Ni atom is a distorted octahedron. The thermogravimetric (TG) data indicate that thermal decomposition of the title compound takes place in four steps and the residue is Ni(OPS2)(2).

  DOI：

  10.1081/sim-200026301
• 作为产物：
  描述：

  sodium O,O'-(dibenzyl)phosphorodithioate 以 水 为溶剂， 生成 bis(O,O'-dibenzyldithiophosphato)(2,2'-bipyridine)nickel(II)
  参考文献：
  名称：

  Synthesis, Crystal Structure and Thermal Studies ofbis(O,O′‐Dibenzyldithiophosphato)‐(2,2′‐Bipyridine)nickel(II) Complex

  摘要：

  The bis(O,O'-dibenzyldithiophosphato)Ni(II) adduct, [(PhCH2O)(2)PS2](2) Ni(bpy), was synthesized by the reaction of [(PhCH2O)(2)PS2](2)Ni. with 2,2'-bipyridine in the solid state. Single crystals of the title compound as the dihydrate were obtained by recrystallization in ethanol-distilled water (v/v = 9: 1). The structure characterization was performed by means of IR; elemental analyses, and single crystal x-ray analysis. The crystal of the title compound consists of two disconnected structural units, each of which includes two non-coordination water molecules. The coordination geometry of each Ni atom is a distorted octahedron. The thermogravimetric (TG) data indicate that thermal decomposition of the title compound takes place in four steps and the residue is Ni(OPS2)(2).

  DOI：

  10.1081/sim-200026301