[Cu(3-(4-chlorophenylazo)pentane-2,4-dione(-1H))2] | 88667-88-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Cu(3-(4-chlorophenylazo)pentane-2,4-dione(-1H))2]
• CAS: 88667-88-3
• 化学式: C₂₂H₂₀Cl₂CuN₄O₄
• 分子量: 538.877
• InChiKey: IGVPZIDLIUHDFL-FZHLCEHXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Cu(3-(4-chlorophenylazo)pentane-2,4-dione(-1H))2] 以 neat (no solvent) 为溶剂， 生成 copper(II) oxide
  参考文献：
  名称：

  Thermodynamic characteristic of complex formation of some metals with 3-(4-chlorophenylazo)pentane-2,4-dione in aqueous ethanol

  摘要：

  Effective charges of atoms in tautomeric forms (enol-azo, keto-azo, hydrazo) of 3-(4-chlorophenylazo) pentane-2,4-dione (L) have been determined by MO LCAO in the Huckel approximation. The complex formation of a series of metals with L in aqueous ethanol has been investigated by potentiometric and conductometric titration. Based on the results of potentiometric titration, the standard thermodynamic functions of complex formation have been established. They vary in the following order:|Delta G(0)|:Fe > Cu > Co > Ni > UO2 > Cd > Zn > Mn > Mg > Ca, |Delta H-0|: Fe > Cu > UO2 > Ni > Co > Zn > Cd > Mn > Mg > Ca, Delta S-0: Ca > Mg > Mn > Cd > Co > Zn > Ni > Cu > Fe > UO2.The complex of copper(II) with L has been identified by X-ray diffraction, and its thermal properties have been studied.

  DOI：

  10.1134/s0036023609090113
• 作为产物：
  描述：

  copper(ll) sulfate pentahydrate 、 3-[(4-氯苯基)二氮烯基]戊烷-2,4-二酮 以 乙醇 、 水 为溶剂， 生成 [Cu(3-(4-chlorophenylazo)pentane-2,4-dione(-1H))2]
  参考文献：
  名称：

  Thermodynamic characteristic of complex formation of some metals with 3-(4-chlorophenylazo)pentane-2,4-dione in aqueous ethanol

  摘要：

  Effective charges of atoms in tautomeric forms (enol-azo, keto-azo, hydrazo) of 3-(4-chlorophenylazo) pentane-2,4-dione (L) have been determined by MO LCAO in the Huckel approximation. The complex formation of a series of metals with L in aqueous ethanol has been investigated by potentiometric and conductometric titration. Based on the results of potentiometric titration, the standard thermodynamic functions of complex formation have been established. They vary in the following order:|Delta G(0)|:Fe > Cu > Co > Ni > UO2 > Cd > Zn > Mn > Mg > Ca, |Delta H-0|: Fe > Cu > UO2 > Ni > Co > Zn > Cd > Mn > Mg > Ca, Delta S-0: Ca > Mg > Mn > Cd > Co > Zn > Ni > Cu > Fe > UO2.The complex of copper(II) with L has been identified by X-ray diffraction, and its thermal properties have been studied.

  DOI：

  10.1134/s0036023609090113