4-[3,5-bis(4-carbazol-9-ylphenyl)phenyl]-N,N-diphenylaniline | 1097915-67-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-[3,5-bis(4-carbazol-9-ylphenyl)phenyl]-N,N-diphenylaniline
• CAS: 1097915-67-7
• 化学式: C₆₀H₄₁N₃
• 分子量: 804.006
• InChiKey: CVNKZWFHYWFVSV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.2
• 重原子数：
  63
• 可旋转键数：
  8
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  13.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  4-溴三苯胺 在 四(三苯基膦)钯 、 正丁基锂 、 caesium carbonate 作用下， 以 四氢呋喃 、 乙醇 、 水 、 甲苯 为溶剂， 反应 72.0h， 生成 4-[3,5-bis(4-carbazol-9-ylphenyl)phenyl]-N,N-diphenylaniline
  参考文献：
  名称：

  Synthesis and characterization of highly stable and efficient star-molecules

  摘要：

  A series of well-defined star-shaped molecules have been synthesized by Pd-catalyzed Suzuki cross-coupling starting from very simple reactants with 1,3,5-trisubstituted benzene, 2,4,6-trisubstituted pyridine and trisubstituted phenylcarbazole as the backbones. These star-molecules are all soluble in common organic solvents and electrochemically stable with reversible cyclic voltammographs and high lying HOMOs. They exhibit excellent blue-fluorescence with quantum yield up to 0.87 and high glass transition temperatures. These molecules offer potential as pure blue-light emitting, hole-transport or host materials for optoelectronic applications. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2012.11.014

文献信息

• Synthesis and characterization of highly stable and efficient star-molecules
  作者：Hai-Fang Huang、Shi-Hua Xu、Yan-Bo He、Cai-Cai Zhu、He-Liang Fan、Xue-Hua Zhou、Xi-Cun Gao、Yan-Feng Dai

  DOI：10.1016/j.dyepig.2012.11.014

  日期：2013.3

  A series of well-defined star-shaped molecules have been synthesized by Pd-catalyzed Suzuki cross-coupling starting from very simple reactants with 1,3,5-trisubstituted benzene, 2,4,6-trisubstituted pyridine and trisubstituted phenylcarbazole as the backbones. These star-molecules are all soluble in common organic solvents and electrochemically stable with reversible cyclic voltammographs and high lying HOMOs. They exhibit excellent blue-fluorescence with quantum yield up to 0.87 and high glass transition temperatures. These molecules offer potential as pure blue-light emitting, hole-transport or host materials for optoelectronic applications. (C) 2012 Elsevier Ltd. All rights reserved.