bis(2-phenylnaphthalen-1-yl)amine | 1396175-74-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: bis(2-phenylnaphthalen-1-yl)amine
• 英文别名: 2-phenyl-N-(2-phenylnaphthalen-1-yl)naphthalen-1-amine
• CAS: 1396175-74-8
• 化学式: C₃₂H₂₃N
• 分子量: 421.541
• InChiKey: KZYVHVBUOBGPFL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.2
• 重原子数：
  33
• 可旋转键数：
  4
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  bis(2-phenylnaphthalen-1-yl)amine 在 正丁基锂 、 三氯化硼 作用下， 以 正己烷 、 甲苯 、 正庚烷 为溶剂， 反应 2.58h， 生成
  参考文献：
  名称：

  Azaboradibenzo[6]helicene: Carrier Inversion Induced by Helical Homochirality

  摘要：

  Azaboradibenzo[6]helicene, a new semiconductor material possessing helical chirality, has been synthesized via a tandem bora-Friedel Crafts-type reaction. Unprecedented carrier inversion between the racemate (displaying p-type semiconductivity) and the single enantiomer (displaying n-type semiconductivity) was observed and can be explained by changes in the molecular packing induced by helical homochirality.

  DOI：

  10.1021/ja310372f
• 作为产物：
  描述：

  1-溴-2-萘酚 在 2-双环己基膦-2',6'-二甲氧基联苯 、 吡啶 、 tris(dibenzylideneacetone)dipalladium(0) chloroform complex 、 lithium amide 、 [1,3-双(二苯基膦基)丙烷]二氯化钯(II) 、 lithium bromide 、 sodium t-butanolate 作用下， 以 1,4-二氧六环 、 乙醚 、 二氯甲烷 为溶剂， 反应 23.5h， 生成 bis(2-phenylnaphthalen-1-yl)amine
  参考文献：
  名称：

  Azaboradibenzo[6]helicene: Carrier Inversion Induced by Helical Homochirality

  摘要：

  Azaboradibenzo[6]helicene, a new semiconductor material possessing helical chirality, has been synthesized via a tandem bora-Friedel Crafts-type reaction. Unprecedented carrier inversion between the racemate (displaying p-type semiconductivity) and the single enantiomer (displaying n-type semiconductivity) was observed and can be explained by changes in the molecular packing induced by helical homochirality.

  DOI：

  10.1021/ja310372f

文献信息

• MATERIAL FOR ORGANIC ELECTROLUMINESCENT ELEMENTS, ORGANIC ELECTROLUMINESCENT ELEMENT, DISPLAY DEVICE, AND LIGHTING DEVICE
  申请人：JNC Corporation

  公开号：US20150097162A1

  公开（公告）日：2015-04-09

  Provided is an organic electroluminescent element which has improved driving voltage and improved current efficiency. An organic electroluminescent element having the above-mentioned improved characteristics is provided by using, as a material for organic electroluminescent elements, a polycyclic aromatic compound in which a nitrogen atom and another heteroatom or a metal atom (X) are adjacent to each other in a non-aromatic ring.

  提供一种具有改进驱动电压和改进电流效率的有机电致发光元件。通过使用多环芳香化合物作为有机电致发光元件的材料，其中一个氮原子和另一个杂原子或金属原子（X）相邻于非芳香环中，提供了具有上述改进特性的有机电致发光元件。
• POLYCYCLIC AROMATIC COMPOUND
  申请人：Kyoto University

  公开号：EP2752418B1

  公开（公告）日：2017-11-29
• US9166176B2
  申请人：——

  公开号：US9166176B2

  公开（公告）日：2015-10-20
• US9741950B2
  申请人：——

  公开号：US9741950B2

  公开（公告）日：2017-08-22
• Azaboradibenzo[6]helicene: Carrier Inversion Induced by Helical Homochirality
  作者：Takuji Hatakeyama、Sigma Hashimoto、Tsuyoshi Oba、Masaharu Nakamura

  DOI：10.1021/ja310372f

  日期：2012.12.5

  Azaboradibenzo[6]helicene, a new semiconductor material possessing helical chirality, has been synthesized via a tandem bora-Friedel Crafts-type reaction. Unprecedented carrier inversion between the racemate (displaying p-type semiconductivity) and the single enantiomer (displaying n-type semiconductivity) was observed and can be explained by changes in the molecular packing induced by helical homochirality.