6-octyloxy-2-naphthoyl chloride | 58601-39-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 6-octyloxy-2-naphthoyl chloride
• 英文别名: 6-octyloxynaphthalene-2-carboxylic acid chloride；6-n-Octyloxynaphthalene-2-carbonylchloride；6-Octoxynaphthalene-2-carbonyl chloride
• CAS: 58601-39-1
• 化学式: C₁₉H₂₃ClO₂
• 分子量: 318.843
• InChiKey: GJPRSUURHPVTIS-UHFFFAOYSA-N

物化性质

• 沸点：
  437.2±18.0 °C(Predicted)
• 密度：
  1.101±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  22
• 可旋转键数：
  9
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  6-octyloxy-2-naphthoyl chloride 在 一水合肼 作用下， 以 四氢呋喃 为溶剂， 反应 24.0h， 生成
  参考文献：
  名称：

  Symmetrical mesogenic 2,5-bis(6-naphthalen-2-yl)-1,3,4-thiadiazoles

  摘要：

  Two series of new symmetrical 1,3,4-oxadiazoles 1a-n and 1,3,4-thiadiazoles 1b-n were prepared and their mesomorphic properties investigated by optical microscopy, differential scanning calorimetry, and powder X-ray diffractometry. Compounds 1b-n are kinetically more stable than compounds 1a-n. Compounds 1a-n exhibited monotropic nematic or smectic C phases, whereas, compounds 1b-n exhibited enantiotropic nematic or smectic A/smectic C phases. Compounds 1b-n have higher clearing temperatures and the larger temperature ranges of mesophases, which might be attributed to the better linearity and/or larger dipole, resulted from a more polarized sulfur atom than oxygen atom incorporated. The fluorescent properties of these two series of 1,3,4-thiadiazole/oxadiazole-based derivatives were also examined. The lambda(max) peaks of the photoluminescence spectra for compounds 1a-6 and 1b-6 measured in THF occurred at ca. 385 nm and 423 nm, respectively. Both series were blue emitters. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2012.06.092
• 作为产物：
  描述：

  6-羟基-2-萘甲酯 在 氯化亚砜 、 potassium carbonate 、 potassium iodide 、 potassium hydroxide 作用下， 以 乙醇 、 丙酮 为溶剂， 反应 52.0h， 生成 6-octyloxy-2-naphthoyl chloride
  参考文献：
  名称：

  Symmetrical mesogenic 2,5-bis(6-naphthalen-2-yl)-1,3,4-thiadiazoles

  摘要：

  Two series of new symmetrical 1,3,4-oxadiazoles 1a-n and 1,3,4-thiadiazoles 1b-n were prepared and their mesomorphic properties investigated by optical microscopy, differential scanning calorimetry, and powder X-ray diffractometry. Compounds 1b-n are kinetically more stable than compounds 1a-n. Compounds 1a-n exhibited monotropic nematic or smectic C phases, whereas, compounds 1b-n exhibited enantiotropic nematic or smectic A/smectic C phases. Compounds 1b-n have higher clearing temperatures and the larger temperature ranges of mesophases, which might be attributed to the better linearity and/or larger dipole, resulted from a more polarized sulfur atom than oxygen atom incorporated. The fluorescent properties of these two series of 1,3,4-thiadiazole/oxadiazole-based derivatives were also examined. The lambda(max) peaks of the photoluminescence spectra for compounds 1a-6 and 1b-6 measured in THF occurred at ca. 385 nm and 423 nm, respectively. Both series were blue emitters. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2012.06.092

文献信息

• Some new azobenzene liquid crystals involving chalcone and ester linkages
  作者：Xueyou Zhu、Fengnan Yin、Haiying Zhao、Shufeng Chen、Zhanxi Bian

  DOI：10.1039/c7ra06958h

  日期：——

  X-ray diffraction studies, the compounds containing ferrocene and the compounds with three or no terminal alkoxy chains on the side of the ester group all showed no liquid crystal behaviour. However, the compounds with a terminal alkoxy chain on the side of the ester group or a terminal alkoxy chain at both ends of the molecule exhibited enantiotropic mesophases, but the latter had a narrow mesogenic

  合成并表征了五个新系列的含噻吩，萘或二茂​​铁并带有查尔酮和酯键的偶氮苯衍生物。在紫外光下，通过紫外可见光谱监测光敏性偶氮苯基的光异构化。含二茂铁的化合物的循环伏安图显示了准可逆和扩散控制的氧化还原过程。根据热重法测量，这些化合物显示出高的热稳定性。根据差示扫描量热法，热偏振显微镜和粉末X射线衍射研究，含二茂铁的化合物和酯基侧具有三个或不具有末端烷氧基链的化合物均未显示液晶行为。然而，在酯基团的侧面具有末端烷氧基链或在分子的两端具有末端烷氧基链的化合物表现出对映中间相，但是后者具有狭窄的介晶域。通过用萘环取代苯环来增加介晶单元的长度，导致清除点的增加和中间相域的增加。
• Optically active tetrahydropyrane derivatives, liquid crystal
  申请人：Kashima Oil Company

  公开号：US05368771A1

  公开（公告）日：1994-11-29

  There are disclosed a novel optically active tetrahydropyrane derivatives (for example, (2R,5R,6R)-tetrahydro-6-trifluoromethyl-2-hexyloxy-5-(4"-hexyloxybiphenyl) -4'-carbonyloxy)pyrane; (2S,5R,6R)-tetrahydro-6-trifluoromethyl-2-hexyloxy-5-(4"-hexyloxybiphenyl) -4'-carbonyloxy)pyrane, etc. may be mentioned.) represented by the formula (I): ##STR1## or (I'): ##STR2## wherein symbols in the formula are as described in the specification, which is available as a liquid crystal material used for a display device or an electro-optic device, a liquid crystal composition and a liquid crystal device containing the same. The optically active tetrahydropyrane derivative of the present invention can improve high speed response particularly when it is made a composition, and is available as a compositional component for a ferroelectric liquid crystal which induces a large spontaneous polarization.

  本发明公开了一种新型光学活性四氢吡喃衍生物(例如，(2R,5R,6R)-四氢-6-三氟甲基-2-己氧基-5-(4"-己氧基联苯)-4'-羰氧基)吡喃；(2S,5R,6R)-四氢-6-三氟甲基-2-己氧基-5-(4"-己氧基联苯)-4'-羰氧基)吡喃等)，其由式(I)或式(I')表示：##STR1##或##STR2## 公式中的符号如说明书所述，可作为液晶材料用于显示器件或电光器件、液晶组合物和含有液晶组合物的液晶器件。本发明的光学活性四氢吡喃衍生物在制成组合物时可提高高速响应性，可作为诱导大自发极化的铁电液晶的组合成分。
• OPTICALLY ACTIVE NAPHTHALENE COMPOUNDS AND LIQUID CRYSTAL COMPOSITIONS CONTAINING THEM
  申请人：SECRETARY OF STATE FOR DEFENCE IN HER BRITANNIC MAJESTY'S GOV. OF THE UNITED KINGDOM OF GREAT BRITAIN AND NORTHERN IRELAND

  公开号：EP0302875B1

  公开（公告）日：1991-02-27
• Mesomorphic Homologous Series 4-Formylphenyl 6-n-Alkoxy-2-Naphthalenecarboxylates (I) and 2-Acetylnaphthalen-6-yl 4-n-Alkoxybenzoates (II)
  作者：K. N. Trivedi、D. M. Thakkar

  DOI：10.1080/00268948408080181

  日期：1984.4
• Synthesis and Physico-Chemical Properties of Polar Liquid Crystal Materials Incorporating a Coumarin Skeleton at the Terminal Position
  作者：Yuki Morita、Hiroyuki Ushijima、Kyohei Era、Kazuo Kasatani、Hiroaki Okamoto

  DOI：10.1080/15421400802430000

  日期：2008.12.2

  This paper described the synthesis and physico-chemical properties of homologous series of 2-oxo-2H-chromen-6-yl 6-alkoxy-naphthalene-2-carboxylate (compounds 1-n). Compounds 1-n show a monotropic nematic (N) phase, where the average of the N-isotropic (1) phase transition temperatures is ca. 140 degrees C. The mesomorphic properties were also examined by binary phase diagrams for the mixture of 1-n (n = 4 or 8) and 4-(cyano-4'-octyloxybiphenyl (8 OCB), or 4-heptyloxyphenyl 4-nonyloxybenzoate. The physico-chemical properties for compounds 1-n are compared with the corresponding 4-alkoxybenzoate derivatives (compounds 2-n) and 4-alkoxybiphenyl-4'-carboxylate ones (compounds 3-n). These results are discussed in terms of molecular structures and the electrostatic natures of the molecules.