5-chloromethyl-2-norbornene | 95-09-0

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: 5-chloromethyl-2-norbornene
• 英文别名: 5-(chloromethyl)norbornene；chloromethylnorbornene；5-chloromethylbicyclo[2.2.1]hept-2-ene；norbornene chloromethane；2-Chlormethyl-bicyclo<2.2.1>hept-5-en；exo,endo-5-Chlormethyl-norbornen-2；5-(chloromethyl)bicyclo[2.2.1]hept-2-ene
• CAS: 95-09-0
• 化学式: C₈H₁₁Cl
• mdl: MFCD00770044
• 分子量: 142.628
• InChiKey: UVFFMASFIIKUOD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,1,3,3,5,5-六甲基三硅氧烷 、 5-chloromethyl-2-norbornene 在 dihydrogen hexachloroplatinate 作用下， 以 四氢呋喃 为溶剂， 反应 3.0h， 生成 bis[[[6-(chloromethyl)-2-bicyclo[2.2.1]heptanyl]-dimethylsilyl]oxy]-dimethylsilane
  参考文献：
  名称：

  Zavin; Pilipkova; Kireev, Russian Journal of General Chemistry, 1996, vol. 66, # 2, p. 260 - 262

  摘要：

  DOI：
• 作为产物：
  描述：

  5-降冰片烯-2-甲醇 在 三苯基膦 作用下， 以 四氯化碳 为溶剂， 生成 5-chloromethyl-2-norbornene
  参考文献：
  名称：

  Imidazole derivatives and salts thereof and pharmaceutical formulations

  摘要：

  Imidazoles的化学式（I）##STR1##其中A是化学键或直链或支链、饱和或不饱和的、具有1至6个碳原子的脂肪残基，其中这些碳原子中的1、2或3个可以被氧、硫和氮等异原子取代，提供（在2或3个异原子的情况下）任何这样的异原子不位于另一个这样的异原子或异原子旁边R是融合的、饱和的或不饱和的、非芳香性碳环多环环系统；一个饱和或不饱和的、碳环螺环系统，可选地含有一个或多个氧、硫和氮等环异原子；或者是一个饱和或不饱和的、碳环桥联多环环系统，可选地含有一个或多个氧、硫和氮等环异原子并具有一个或多个桥梁；或者AR一起表示一个直链或支链、饱和或不饱和、具有3至6个碳原子的脂肪残基，其中这些碳原子中的1、2或3个可以被氧、硫和氮等异原子取代，提供（在2或3个异原子的情况下）任何这样的异原子不位于另一个这样的异原子或异原子旁边；这种脂肪残基被至少两个可能相同或不同的从上述R中指定的基团取代。其酸盐和药学上可接受的生物前体。揭示了制备咪唑的方法。咪唑及其酸盐和生物前体在治疗或预防血栓栓塞症方面是有用的。

  公开号：

  US04328234A1

文献信息

• Norbornene compounds with cross-linkable groups and their derivatives
  申请人：National Taiwan University of Science & Technology

  公开号：US07132565B2

  公开（公告）日：2006-11-07

  The present invention provided a norbornene compound with cross-linkable groups and their derivative polymers, wherein said cross-linkable groups were olefin or epoxy groups. Norbornene polymers with cross-linkable side chain and their block copolymers as well as modified derivatives were prepared via living ring-open metathesis polymerization method. The resulting polymers with excellent solubility and optic properties had narrow molecular weight distribution, well-controlled molecular weight, small refraction ration and high transparency. They were also suitable for preparing hybrid materials with high thermal stability and chemical resistance.

  本发明提供了一种具有可交联基团的去环戊烯化合物及其衍生聚合物，其中所述可交联基团为烯烃或环氧基团。通过活性环开拆聚合方法制备了具有可交联侧链的去环戊烯聚合物及其嵌段共聚物以及改性衍生物。所得聚合物具有优异的溶解性和光学性能，具有窄分子量分布、良好控制的分子量、小的折射率和高透明度。它们还适用于制备具有高热稳定性和化学抗性的混合材料。
• Batch Stille Coupling with Insoluble and Recyclable Stannylated Polynorbornenes
  作者：Sheila Martínez-Arranz、Nora Carrera、Ana C. Albéniz、Pablo Espinet、Alejandro Vidal-Moya

  DOI：10.1002/adsc.201200624

  日期：2012.12.14

  The Stille coupling can be carried out in a batch process using insoluble tin supports. The new type of support consists of stannylated polymers based on the vinylic polynorbornene skeleton that allow one to use a set-up where the tin reagent is immobilized in a column. The immobilized stannylated polymeric reagent can be easily reused. The coupling products are thus obtained by a very simple work-up

  斯蒂勒偶联可以使用不溶性锡载体以间歇方式进行。新型载体由基于乙烯基聚降冰片烯骨架的甲氧基化聚合物组成，该聚合物可用于将锡试剂固定在色谱柱中的装置。固定化的苯乙烯化聚合物试剂可以容易地重复使用。因此，可以通过非常简单的后处理程序获得耦合产品，并且锡污染水平非常低。
• NORBORNANE SKELETON STRUCTURE-CONTAINING ORGANOSILICON COMPOUND AND METHOD OF PRODUCING SAME
  申请人：TSUCHIDA Kazuhiro

  公开号：US20090124821A1

  公开（公告）日：2009-05-14

  Disclosed are a radiation-polymerizable functional group-containing organosilicon compound, including (A) a norbornane skeleton structure, (B) a hydrolyzable silyl group bonded directly to the norbornane skeleton structure, and (C) a radiation-polymerizable functional group bonded to the norbornane skeleton structure, either directly or via a carbon atom, a hetero atom, or a combination thereof, and a method of producing the radiation-polymerizable functional group-containing organosilicon compound. Also disclosed are a haloalkyl group-containing organosilicon compound, including (D) a norbornane skeleton structure, (E) a hydrolyzable silyl group bonded directly to the norbornane skeleton structure, and (F) a haloalkyl group, which is bonded directly to the norbornane skeleton structure and either contains or does not contain a hetero atom, and a method of producing the haloalkyl group-containing organosilicon compound. These organosilicon compounds are useful as silane coupling agents having superior heat resistance stability.

  本发明涉及一种辐射聚合功能基含有的有机硅化合物，包括（A）诺博尔烷骨架结构，（B）与诺博尔烷骨架结构直接键合的可水解硅基团，以及（C）与诺博尔烷骨架结构直接或通过碳原子、杂原子或其组合键合的辐射聚合功能基团，以及制备该辐射聚合功能基含有的有机硅化合物的方法。本发明还涉及一种含有卤代烷基的有机硅化合物，包括（D）诺博尔烷骨架结构，（E）与诺博尔烷骨架结构直接键合的可水解硅基团，以及（F）直接键合到诺博尔烷骨架结构上的含有或不含有杂原子的卤代烷基团，以及制备该含有卤代烷基的有机硅化合物的方法。这些有机硅化合物可用作具有优异耐热稳定性的硅烷偶联剂。
• Thermoplastic norbornene resin based optical film
  申请人：——

  公开号：US20040242823A1

  公开（公告）日：2004-12-02

  An optical film is provided, which displays a positive wavelength dependency across the entire wavelength region from 400 to 800 nm, and is capable of imparting a specified retardation to transmitted light with a single sheet of film. The optical film particularly, includes a thermoplastic norbornene-based resin with a specified structure formed of a structural unit (I) which imparts a positive birefringence and a structural unit (II) which imparts a negative birefringence, and which satisfies particular conditions with respect to &Dgr;N I (&lgr;), &Dgr;N II (&lgr;), &Dgr;N I (800) and &Dgr;N II (800) wherein &Dgr;N I (&lgr;) and &Dgr;N II (&lgr;) represent the difference between a refractive index Nx(&lgr;) in an x axis direction at a wavelength &lgr;, and a refractive index Ny(s) in a y axis direction, and &Dgr;N I (800) and &Dgr;N II (800) represent the difference in refractive indexes at a wavelength of 800 nm, and the x axis represents the stretching direction and the y axis represents the in-plane direction perpendicular to the x direction.

  提供了一种光学薄膜，其在整个波长范围从400到800纳米内显示正波长依赖性，并能够通过单张薄膜赋予传输光以指定的延迟。该光学薄膜特别包括一种热塑性诺本烯基树脂，其具有特定的结构，由赋予正双折射的结构单元（I）和赋予负双折射的结构单元（II）组成，并满足与&Dgr;NI(&lgr;)、&Dgr;NII(&lgr;)、&Dgr;NI(800)和&Dgr;NII(800)相关的特定条件，其中&Dgr;NI(&lgr;)和&Dgr;NII(&lgr;)表示在波长&lgr;处x轴方向上的折射率Nx(&lgr;)与y轴方向上的折射率Ny(s)之间的差异，而&Dgr;NI(800)和&Dgr;NII(800)表示在波长为800纳米时的折射率差异，其中x轴代表拉伸方向，y轴代表垂直于x方向的平面方向。
• Method for producing an olefin type copolymer having a cyclic structure
  申请人：MARUZEN PETROCHEMICAL CO., LTD.

  公开号：US20020058767A1

  公开（公告）日：2002-05-16

  A method for producing an olefin type copolymer having a cyclic structure, which comprises copolymerizing ethylene (M1) and dicyclopentadiene or tricyclopentadiene (M2), and, as optionally introduced, a cyclic olefin (M3), wherein, as a catalyst, a catalyst comprising a metallocene compound (A) of the following formula [1]: H 2 C(R′ m CP)(R″ n Cp)Mx 2 [1] wherein M is zirconium or hafnium, Cp is a group having a cyclopentadienyl skeleton, each of R′ and R″ is a hydrocarbon group having 1 to 10 carbon atoms, each of two X's which may be the same or different from each other, is a halogen atom, a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogenated hydrocarbon group, an alkylamino group, an alkoxy group, an aryloxy group of the formula —O—Ar—Y p (wherein Ar is an aromatic ring, Y is a halogen atom, a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogenated hydrocarbon group, an alkoxy group, an alkylamino group, a cyano group or a nitro group, and p is an integer of from 1 to 5), a thioalkyl group, or a thioaryl group of the formula —S—Ar—Y p (wherein Ar, Y and p are as defined above), and each of m and n is an integer of from 0 to 4, provided that m and n are not equal, and m+n is an integer of from 3 to 6, and an aluminoxane (B), is used.

  一种制备具有环状结构的烯烃共聚物的方法，包括共聚乙烯（M1）和二环戊二烯或三环戊二烯（M2），以及作为可选引入的环状烯烃（M3），其中，作为催化剂使用以下式子（1）的金属茂化合物（A）：H2C(R′mCP)(R″nCp)Mx2（1），其中M为锆或铪，Cp为具有环戊二烯基骨架的基团，R′和R″各自为具有1至10个碳原子的碳氢基团，两个X可以相同也可以不同，是卤素原子、氢原子、具有1至20个碳原子的碳氢基团、卤代碳氢基团、烷基氨基基团、烷氧基、苯氧基（式中Ar为芳香环，Y为卤素原子、氢原子、具有1至20个碳原子的碳氢基团、卤代碳氢基团、烷氧基、烷基氨基基团、氰基或硝基，p为1至5的整数），硫代烷基团或硫代芳基团（式中Ar、Y和p如上所述），m和n各自为0至4的整数，但m和n不相等，且m+n为3至6的整数，并使用铝烷氧化物（B）。