2,4,6-tris(4-bromo-3-methylphenylene)-1,3,5-triazine | 1010396-47-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,4,6-tris(4-bromo-3-methylphenylene)-1,3,5-triazine
• 英文别名: 2,4,6-tris(4-bromo-3-methylphenyl)-1,3,5-triazine
• CAS: 1010396-47-0
• 化学式: C₂₄H₁₈Br₃N₃
• 分子量: 588.139
• InChiKey: GMQUPAPEOVXKPJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.1
• 重原子数：
  30
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  38.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2,4,6-tris(4-bromo-3-methylphenylene)-1,3,5-triazine 、 potassium diphenylphosphine 以 四氢呋喃 为溶剂， 反应 48.0h， 生成
  参考文献：
  名称：

  Synthesis of a halo-methylphenylene periphery-functionalized triazine-based dendritic molecule with a 3,3′-dimethyl-biphenyl linker using tris(halo-methylphenylene)triazines as building blocks

  摘要：

  A tris(bromo-methylphenylene)triazine and its corresponding phosphine oxide derivative have been synthesized; the latter compound was found to be a potent ligand for the hydroformylation reaction. Suzuki coupling of the mono-pinacolboronate derivative of the former compound with a tris(iodo-methylphenylene)triazine was possible at two of the three iodine atoms, yielding a bromo- and iodo-methylphenylene periphery-functionalized triazine-based dendritic molecule with a 3,3 '-dimethyl-bipheny) linker. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.02.011
• 作为产物：
  描述：

  4-溴-3-甲基苯甲腈 在 三氟甲磺酸 作用下， 以90%的产率得到2,4,6-tris(4-bromo-3-methylphenylene)-1,3,5-triazine
  参考文献：
  名称：

  Synthesis of a halo-methylphenylene periphery-functionalized triazine-based dendritic molecule with a 3,3′-dimethyl-biphenyl linker using tris(halo-methylphenylene)triazines as building blocks

  摘要：

  A tris(bromo-methylphenylene)triazine and its corresponding phosphine oxide derivative have been synthesized; the latter compound was found to be a potent ligand for the hydroformylation reaction. Suzuki coupling of the mono-pinacolboronate derivative of the former compound with a tris(iodo-methylphenylene)triazine was possible at two of the three iodine atoms, yielding a bromo- and iodo-methylphenylene periphery-functionalized triazine-based dendritic molecule with a 3,3 '-dimethyl-bipheny) linker. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.02.011

文献信息

• 전자적 응용을 위한 전기활성 조성물
  申请人：LG CHEM, LTD. 주식회사 엘지화학(120010134563) Corp. No ▼ 110111-2207995BRN ▼107-81-98139

  公开号：KR20190136140A

  公开（公告）日：2019-12-09

  본 발명은 (a) 도펀트, (b) 화학식 I의 적어도 하나의 단위를 갖는 제1 호스트, 및 (c) 제2 호스트 화합물을 포함하는 조성물에 관한 것이다. 화학식 I은 하기 구조를 갖는다: 화학식 I에서: Ar, Ar, 및 Ar동일하거나 상이하며 H, D, 또는 아릴 기이다. Ar, Ar, 및 Ar 중 적어도 2개는 아릴이고 Ar, Ar, 및 Ar 중 어느 것도 인돌로카르바졸 부분을 포함하지 않는다.

  本发明涉及一种包括(a) 防御剂，(b) 至少具有化学式I中的一个单元的第一宿主，以及(c) 包含第二宿主化合物的组合物。化学式I具有以下结构：在化学式I中：Ar，Ar和Ar可以相同或不同，并且可以是H，D或芳基。Ar，Ar和Ar中至少有2个是芳基，且Ar，Ar和Ar都不包含indolocarbazole部分。
• Efficient Host Material Containing 1,3,5-Triazine Moiety for Red Phosphorescent Organic light-emitting diodes (OLEDs)
  作者：Na-Rae Jung、Eun-Ji Lee、Jin-Ho Kim、Jun-Yeob Lee、Seok-Jong Lee、Young-Jin Kang

  DOI：10.5012/bkcs.2011.32.11.4075

  日期：2011.11.20
• ELECTROACTIVE COMPOSITIONS FOR ELECTRONIC APPLICATIONS
  申请人：Dobbs Kerwin D.

  公开号：US20130264561A1

  公开（公告）日：2013-10-10

  This invention relates to a composition including (a) a dopant, (b) a first host having at least one unit of Formula I, and (c) a second host compound. Formula I has the structure In Formula I: Ar 1 , Ar 2 , and Ar 3 are the same or different and are H, D, or aryl groups. At least two of Ar 1 , Ar 2 , and Ar 3 are aryl and none of Ar 1 , Ar 2 , and Ar 3 includes an indolocarbazole moiety.
• [EN] ELECTROACTIVE COMPOSITIONS FOR ELECTRONIC APPLICATIONS<br/>[FR] COMPOSITIONS ÉLECTROACTIVES POUR APPLICATIONS ÉLECTRONIQUES
  申请人：DU PONT

  公开号：WO2012087961A2

  公开（公告）日：2012-06-28

  This invention relates to a composition including (a) a dopant, (b) a first host having at least one unit of Formula I, and (c) a second host compound. Formula I has the structure INSERT FORMULA I HERE In Formula I: Ar1, Ar2, and Ar3 are the same or different and are H, D, or aryl groups. At least two of Ar1, Ar2, and Ar3 are aryl and none of Ar1, Ar2, and Ar3 includes an indolocarbazole moiety.