2-Hydroperoxy-2-phenylcyclohexan-1-one | 57272-34-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-Hydroperoxy-2-phenylcyclohexan-1-one
• 英文别名: 2-hydroperoxy-2-phenylcyclohexan-1-one
• CAS: 57272-34-1
• 化学式: C₁₂H₁₄O₃
• 分子量: 206.241
• InChiKey: ILZYQFOMOBXIOZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-苯基环己酮 在 potassium tert-butylate 、 氧气 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 2-Hydroperoxy-2-phenylcyclohexan-1-one
  参考文献：
  名称：

  Kinetics of the base-catalyzed decomposition of .alpha.-hydroperoxy ketones

  摘要：

  DOI：

  10.1021/ja00857a007

文献信息

• Process for Producing Phenol
  申请人：Kuechler Keith H.

  公开号：US20140330044A1

  公开（公告）日：2014-11-06

  In a process for producing phenol, cyclohexylbenzene hydroperoxide is cleaved to produce a cleavage effluent stream comprising phenol and cyclohexanone and at least a portion of the cleavage effluent stream is fractionated to produce a first fraction richer in cyclohexanone than the cleavage effluent stream portion and a second fraction richer in phenol and depleted in cyclohexanone as compared with said cleavage effluent stream portion. At least a portion of the second fraction is then contacted with a dehydrogenation catalyst in a dehydrogenation reaction zone under dehydrogenation conditions effective to convert at least a portion of the cyclohexanone in said second fraction portion into phenol and cyclohexanol.

  在生产苯酚的过程中，环己基苯醌过氧化物被分解，产生一个分解产物流，其中包括苯酚和环己酮，至少部分分解产物流被分馏，以产生一个第一馏分，比分解产物流富含环己酮，和一个第二馏分，比分解产物流富含苯酚，且缺乏环己酮。然后，至少部分第二馏分与脱氢催化剂在脱氢反应区接触，在脱氢条件下有效地将第二馏分中的至少部分环己酮转化为苯酚和环己醇。
• US9115060B2
  申请人：——

  公开号：US9115060B2

  公开（公告）日：2015-08-25
• [EN] PROCESS FOR PRODUCING PHENOL FROM CYCLOHEXYLBENZENE HYDROPEROXIDE<br/>[FR] PROCÉDÉ DE PRODUCTION DE PHÉNOL À PARTIR D'HYDROPEROXYDE DE CYCLOHEXYLBENZÈNE
  申请人：EXXONMOBIL CHEM PATENTS INC

  公开号：WO2013052216A1

  公开（公告）日：2013-04-11

  In a process for producing phenol, cyclohexylbenzene hydroperoxide is cleaved to produce a cleavage effluent stream comprising phenol and cyclohexanone and at least a portion of the cleavage effluent stream is fractionated to produce a first fraction richer in cyclohexanone than the cleavage effluent stream portion and a second fraction richer in phenol and depleted in cyclohexanone as compared with said cleavage effluent stream portion. At least a portion of the second fraction is then contacted with a dehydrogenation catalyst in a dehydrogenation reaction zone under dehydrogenation conditions effective to convert at least a portion of the cyclohexanone in said second fraction portion into phenol and cyclohexanol. In another embodiment, a composition of cyclohexanone (>99 wt%) and impurities of methylcy-clopentanone, cyclohexenol, cyclohexanedione or hydroxycyclohex-anone and cyclohexanol is claimed.