2-allyloxycarbonylethyltin trichloride | 183174-48-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-allyloxycarbonylethyltin trichloride
• 英文别名: Prop-2-enyl 3-trichlorostannylpropanoate
• CAS: 183174-48-3
• 化学式: C₆H₉Cl₃O₂Sn
• 分子量: 338.205
• InChiKey: WZXITGFNRHFIFM-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  2.76
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-allyloxycarbonylethyltin trichloride 、 2-羟基缩苯胺 在 氨 作用下， 以 氯仿 为溶剂， 以68%的产率得到
  参考文献：
  名称：

  Synthesis and Characterization of 2-Alkoxycarbonylethyltin Trichlorides and their Complexes

  摘要：

  The synthesis of 2-alkoxycarbonylethyltin trichlorides, ROCOCH(2)CH(2)SnCl(3) (R = CH3CH2CH2, CH2=CHCH2, (CH3)(2)CHCH2), and their complexes with dimethylsufloxide (DMSO), 2,2'-bipyridyl (bpy), 8-hydroxyquinoline (Hoxin) and 2-salicylideneaminophenol (H(2)SAP) and characterization by means of elemental analyses, UV, IR and H-1 NMR spectral data are described.

  DOI：

  10.1080/00945719708000188
• 作为产物：
  描述：

  烯丙醇 、 3-(三氯锡)丙酸甲酯 以 further solvent(s) 为溶剂， 以90.2%的产率得到2-allyloxycarbonylethyltin trichloride
  参考文献：
  名称：

  The Transesterification Reaction of β-methoxycarbonylethyltin Trichloride and its Dimethylsulfoxide Adduct with Alcohols

  摘要：

  DOI：

  10.1080/00945710009351839

文献信息

• SYNTHESIS AND CHARACTERIZATION OF ORGANOTIN(IV) COMPLEXES OF N-(2-MERCAPTOPHENYL)-SALICYLALDIMINE
  作者：Laijin Tian、Bin Zhao、Qingsen Yu、Zhicai Shang

  DOI：10.1081/sim-120014296

  日期：2002.9.18

  The organotin(IV) complexes of N-(2-mercaptophenyl)salicylaldimine, ROCOCH2CH2SnClL (L = OC6H4CH=-NC6H4S, R = alkyl), were synthesized by the reaction of 2-alkoxycarbonylethyltin trichlorides with N-(2-mercaptophenyl)salicylaldimine (H2L) in the presence of triethylamine and were characterized by elemental analyses, IR, H-1 NMR spectra and X-ray single crystal diffraction. The structural features of these compounds are discussed.
• Synthesis and characterization of β-alkoxycarbonylethyltin trichloride complexes with dibutylsulfoxide. Crystal structure of CH3CH2OCOCH2CH2SnCl3 · (n-C4H9)2SO
  作者：Laijin Tian、Zhengyu Zhou、Bin Zhao、Wentao Yu

  DOI：10.1016/s0277-5387(97)00378-1

  日期：1998.1

  The organotin(IV) complexes, ROCOCH2CH2SnCl3 . nL (R = Me, Et, n-Pr, Allyl, n-Bu, i-Bu; n = 1, 2; L = dibutylsulfoxide) have been synthesized and characterized. The spectral data (IR, H-1 and C-13 NMR) indicate that the 1:1 (n = 1) and 1:2 (n = 2) complexes are all hexa-coordinated tin compounds, and the carbonyl oxygen is coordinated to intramolecular tin atom in 1:1 complexes and is free in 1:2 complexes. The crystal structure of EtOCOCH2CH2SnCl3 . L shows that the fin atom adopts a distorted octahedral geometry via the oxygens of dibutylsulfoxide and intramolecular carbonyl group to tin coordination. (C) 1998 Elsevier Science Ltd. All rights reserved.
• Synthesis and Characterization of 2-Alkoxycarbonylethyltin Trichlorides and their Complexes
  作者：Laijin Tian、Shuxiang Liu、Siwei Bi、Fangxin Fu

  DOI：10.1080/00945719708000188

  日期：1997.1

  The synthesis of 2-alkoxycarbonylethyltin trichlorides, ROCOCH(2)CH(2)SnCl(3) (R = CH3CH2CH2, CH2=CHCH2, (CH3)(2)CHCH2), and their complexes with dimethylsufloxide (DMSO), 2,2'-bipyridyl (bpy), 8-hydroxyquinoline (Hoxin) and 2-salicylideneaminophenol (H(2)SAP) and characterization by means of elemental analyses, UV, IR and H-1 NMR spectral data are described.
• The Transesterification Reaction of β-methoxycarbonylethyltin Trichloride and its Dimethylsulfoxide Adduct with Alcohols
  作者：Laijin Tian、Zhengyu Zhou、Bin Zhao、Wentao Yu、Ping Yang

  DOI：10.1080/00945710009351839

  日期：2000.8.1