4-(2-Ethenylphenyl)phenol | 115237-80-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(2-Ethenylphenyl)phenol
• CAS: 115237-80-4
• 化学式: C₁₄H₁₂O
• 分子量: 196.249
• InChiKey: MNEYNBNCEJYCPF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  甲醇 、 4-(2-Ethenylphenyl)phenol 在 lithium perchlorate 、 溶剂黄146 作用下， 以 乙腈 为溶剂， 反应 3.0h， 以17%的产率得到1-Methoxyspiro[1,2-dihydroindene-3,4'-cyclohexa-2,5-diene]-1'-one
  参考文献：
  名称：

  Spiro-annulated cyclohexa-2,5-dienones via electrooxidation of p-aryl phenols a novel mode of anodic carbon-carbon bond formation

  摘要：

  DOI：

  10.1016/s0040-4039(00)96750-9
• 作为产物：
  描述：

  4,4-二甲氧基-2,5-环己二烯-1-酮 在 正丁基锂 、 铜 、 溶剂黄146 、 锌 作用下， 以 四氢呋喃 为溶剂， 反应 21.5h， 生成 4-(2-Ethenylphenyl)phenol
  参考文献：
  名称：

  在阳极氧化的4-苯基苯酚上2'-油酸侧链的分子内环化。烯烃取代基对碳-碳键形成的影响

  摘要：

  在乙腈/甲醇中对4-（2'-链烯基苯基）苯酚进行阳极氧化可提供螺二烯酮，该螺二烯酮是由烯属侧链环化至苯酚的4-位以及所得苄基阳离子与甲烷反应而产生的。形成碳-碳键的反应的效率取决于烯烃取代基。

  DOI：

  10.1016/s0040-4020(01)87055-1

文献信息

• Spiro-annulated 2,5-cyclohexadienones via oxidation of 2′-alkenyl-p-phenyl phenols with iodobenzene diacetate
  作者：Andrew Callinan、Ying Chen、Gary W. Morrow、John S. Swenton

  DOI：10.1016/s0040-4039(00)97673-1

  日期：1990.1

  The oxidation of 2′-alkenyl-substituted p-phenyl phenols via iodobenzene diacetate gives spiro-annulated-2,5-cyclohexadienones.

  经由碘代苯二乙酸酯对2'-烯基取代的对苯基苯酚的氧化得到螺环化的2,5-环己二酮。
• [EN] POLYMERISABLE DIKETOPYRROLOPYRROLES, USE OF SUCH COMPOUNDS IN COLOUR FILTERS AND POLYMERS PREPARED FROM THESE COMPOUNDS<br/>[FR] DICETOPYRROLOPYRROLES POLYMERISABLES, UTILISATION DE CES COMPOSES DANS DES FILTRES COULEURS ET POLYMERES PREPARES A BASE DE CES COMPOSES
  申请人：CIBA SC HOLDING AG

  公开号：WO2004009710A1

  公开（公告）日：2004-01-29

  The present invention relates to the use of polymerisable diketopyrrolopyrroles in colour filters, which can themselves be used for example in electro-optical systems such as TV screens, liquid crystal displays, charge coupled devices, plasma displays or electroluminescent displays and the like. In contrast to conventional pigments the polymerisable diketopyrrolopyrroles do not tend to aggregate and, hence, show very good dispersibility. Color filters prepared by using the polymerisable diketopyrrolopyrroles have high transparence and pure hue. In addition, they facilitate adjustment of color points and enable a large choice of shades.

  本发明涉及在色彩滤光片中使用可聚合的二酮吡咯吡咯，这些色彩滤光片本身可以用于例如电视屏幕、液晶显示器、电荷耦合器件、等离子显示器或电致发光显示器等电光系统中。与传统颜料相比，可聚合的二酮吡咯吡咯不易聚集，因此具有非常好的分散性。通过使用可聚合的二酮吡咯吡咯制备的色彩滤光片具有高透明度和纯净的色调。此外，它们有助于调整颜色点并提供大量的色调选择。
• Fluorescent diketopyrrolopyrroles
  申请人：——

  公开号：US20030187106A1

  公开（公告）日：2003-10-02

  Fluorescent diketopyrrolopyrroles (“DPPs”) of the formula I 1 wherein R 1 and R 2 , independently from each other, stand for C 1 -C 25 -alkyl, allyl which can be substituted one to three times with C 1 -C 3 alkyl or Ar 3 , —CR 3 R 4 —(CH 2 ) m —Ar 3 , wherein R 3 and R 4 independently from each other stand for hydrogen or C 1 -C 4 alkyl, or phenyl which can be substituted on to three times with C 1 -C 3 alkyl, Ar 3 stands for phenyl or 1- or 2-naphthyl which can be substituted one to three times with C 1 -C 8 alkyl, C 1 -C 8 alkoxy, halogen or phenyl, which can be substituted with C 1 -C 8 alkyl or C 1 -C 8 alkoxy one to three times, and m stands for 0, 1, 2, 3 or 4, and wherein C 1 -C 25 -alkyl or —CR 3 R 4 —(CH 2 ) m —Ar 3 , preferably C 1 -C 25 -alkyl, can be substituted with a functional group capable of increasing the solubility in water such as a tertiary amino group, —SO 3 − , or PO 4 2− , Ar 1 , and Ar 2 , independently from each other, stand for 2 wherein R 5 stands for C 1 -C 6 alkyl, —NR 8 R 9 , —OR 10 , —S(O) n R 8 , —Se(O) n R 8 , or phenyl, which can be substituted one to three times with C 1 -C 8 alkyl or C 1 -C 8 alkoxy, wherein R 8 and R 9 , independently from each other, stand for hydrogen, C 1 -C 25 -alkyl, C 5 -C 12 -cycloalkyl, —CR 3 R 4 —(CH 2 ) m —Ph, R 10 , wherein R 10 stands for C 6 -C 24 -aryl, or a saturated or unsaturated heterocyclic radical comprising five to seven ring atoms, wherein the ring consists of carbon atoms and one to three hetero atoms selected from the group consisting of nitrogen, oxygen and sulfur, wherein Ph, the aryl and heterocyclic radical can be substituted one to three times with C 1 -C 8 alkyl, C 1 -C 8 alkoxy, or halogen, or R 8 and R 9 stand for —C(O)R 10 , wherein R 11 can be C 1 -C 25 -alkyl, C 5 -C 12 -cycloalkyl, R 10 , —OR 12 or —NR 13 R 14 , wherein R 12 , R 13 , and R 14 stand for C 1 -C 25 -alkyl, C 5 -C 12 -cycloalkyl, C 6 -C 24 -aryl, or a saturated or unsaturated heterocyclic radical comprising five to seven ring atoms, wherein the ring consists of carbon atoms and one to three hetero atoms selected from the group consisting of nitrogen, oxygen and sulfur, wherein the aryl and heterocyclic radical can be substituted one to three times with C 1 -C 8 alkyl or C 1 -C 8 alkoxy, or —NR 8 R 9 stands for a five- or sixmembered heterocyclic radical in which R 8 and R 9 together stand for tetramethylene, pentamethylene, —CH 2 —CH 2 —O—CH 2 —CH 2 —, or —CH 2 —CH 2 —NR 5 —CH 2 —CH 2 —, preferably —CH 2 —CH 2 —O—CH 2 —CH 2 —, and n stands for 0, 1, 2 or 3, and wherein R 6 and R 7 , independently from each other, stand for hydrogen or R 5 , but do not stand simultaneously for hydrogen, processes for its preparation, its uses and compositions comprising the compounds I.

  荧光二酮吡咯烷酮（“DPPs”）的公式I1，其中R1和R2，独立地代表C1-C25烷基，可以用C1-C3烷基或Ar3取代的丙烯基，—CR3R4—（CH2）m—Ar3，其中R3和R4独立地代表氢或C1-C4烷基，或苯基，可以用C1-C3烷基取代，Ar3代表苯基或1-或2-萘基，可以用C1-C8烷基，C1-C8烷氧基，卤素或苯基取代一至三次，m代表0、1、2、3或4，其中C1-C25烷基或—CR3R4—（ ）m—Ar3，优选为C1-C25烷基，可以用增加水溶性的功能基团取代，例如三级胺基，—SO3−或PO42−，Ar1和Ar2独立地代表2，其中R5代表C1-C6烷基，—NR8R9，—OR10，—S（O）nR8，—Se（O）nR8或苯基，可以用C1-C8烷基或C1-C8烷氧基取代一至三次，其中R8和R9独立地代表氢，C1-C25烷基，C5-C12环烷基，—CR3R4—（ ）m—Ph，其中R10代表C6-C24芳基，或由五至七个环原子组成的饱和或不饱和杂环基团，其中环由碳原子和从氮、氧和硫中选择的一至三个杂原子组成，其中Ph，芳基和杂环基团可以用C1-C8烷基，C1-C8烷氧基或卤素取代一至三次，或R8和R9代表—C（O）R10，其中R11可以是C1-C25烷基，C5-C12环烷基，R10，—OR12或—NR13R14，其中R12、R13和R14代表C1-C25烷基，C5-C12环烷基，C6-C24芳基，或由五至七个环原子组成的饱和或不饱和杂环基团，其中环由碳原子和从氮、氧和硫中选择的一至三个杂原子组成，其中芳基和杂环基团可以用C1-C8烷基或C1-C8烷氧基取代一至三次，或—NR8R9代表一个五元或六元杂环基团，其中R8和R9一起代表四亚甲基，五亚甲基，— — —O— — —或— — —NR5— — —，优选为— — —O— — —，n代表0、1、2或3，其中R6和R7独立地代表氢或R5，但不同时代表氢，其制备方法，其用途和包含化合物I的组合物。
• Fluorescent maleimides and uses thereof
  申请人：——

  公开号：US20030189191A1

  公开（公告）日：2003-10-09

  Fluorescent maleimides of the formula I 1 wherein R 1 and R 2 independently from each other stand for 2 wherein Q 1 stands for hydrogen, halogen, phenyl, —E—C 1 -C 8 alkyl, —E-phenyl, wherein phenyl can be substituted up to three times with C 1 -C 8 alkyl, halogen, C 1 -C 8 alkoxy, diphenylamino, —CH═CH—Q 2 , wherein Q 2 stands for phenyl, pyridyl, or thiophenyl, which can be substituted up to three times with C 1 -C 8 alkyl, halogen, C 1 -C 8 alkoxy, —CN, wherein E stands for oxygen or sulfur, and wherein R 21 stands for C 1 -C 8 alkyl, phenyl, which can be substituted up to three times with C 1 -C 4 alkyl, C 1 -C 4 alkoxy, or dimethylamino, and R 22 and R 23 independently from each other stand for hydrogen, R 21 , C 1 -C 8 alkoxy, or dimethylamino, or —NR 4 R 5 , wherein R 4 and R 5 , independently from each other stand for hydrogen, phenyl, or C 1 -C 8 alkyl-carbonyl, or —NR 4 R 5 stands for a five- or six-membered ring system, and R 3 stands for allyl, 3 wherein Q 3 stands for hydrogen, halogen, C 1 -C 8 alkoxy, or C 1 -C 8 alkyl-amido, unsubstituted or substituted C 1 -C 8 alkyl, unsubstituted or up to three times with halogen, —NH 2 , —OH, or C 1 -C 8 alkyl substituted phenyl, and Z stands for a di- or trivalent radical selected from the group consisting of substituted or unsubstituted cyclohexylene, preferably 1,4-cyclohexylene, triazin-2,4,6-triyl, C 1 -C 6 alkylene, 1,5-naphthylene, 4 wherein Z 1 , Z 2 and Z 3 , independently from each other stand for cyclohexylene or up to three times with C 1 -C 4 alkyl substituted or unsubstituted phenylene, preferably unsubstituted or substituted 1,4-phenylene, and wherein R 6 and R 7 , independently from each other, stand for 5 n stands for 1, 2 or 3, and m stands for 1 or 2, with the proviso, that R 1 and R 2 not simultaneously stand for phenyl, and its different uses such as in electroluminescent devices and as void detection compounds.

  公式I1的荧光马来酰亚胺，其中R1和R2互相独立地为2，其中Q1代表氢，卤素，苯基，-E-C1-C8烷基，-E-苯基，其中苯基可以被C1-C8烷基，卤素，C1-C8烷氧基，二苯胺基，-CH═CH-Q2取代，其中Q2代表苯基，吡啶基或噻吩基，可以被C1-C8烷基，卤素，C1-C8烷氧基，-CN取代，其中E代表氧或硫，且R21代表C1-C8烷基，苯基，其中苯基可以被C1-C4烷基，C1-C4烷氧基或二甲基氨基取代，而R22和R23互相独立地代表氢，R21，C1-C8烷氧基或二甲基氨基，或-NR4R5，其中R4和R5互相独立地代表氢，苯基或C1-C8烷基-羰基，或-NR4R5代表五元或六元环系统，而R3代表丙烯基，其中Q3代表氢，卤素，C1-C8烷氧基或C1-C8烷基酰胺，未取代或取代C1-C8烷基，未取代或最多三次取代卤素，-NH2，-OH或取代苯基的C1-C8烷基，而Z代表从取代或未取代的环己烷基，优选为1,4-环己烷基，三嗪-2,4,6-三基基，C1-C6烷基，1,5-萘基选择的二价或三价基团，其中Z1，Z2和Z3互相独立地代表环己烷基或取代或未取代的苯基，优选为未取代或取代的1,4-苯基，而R6和R7互相独立地代表5，n代表1、2或3，m代表1或2，但R1和R2不能同时代表苯基，其在发光电子器件和空隙检测化合物等不同用途中的应用。
• Colouration of high molecular weight organic materials in the mass with soluble phthalocyanine precursors
  申请人：CIBA-GEIGY AG

  公开号：EP0742255A1

  公开（公告）日：1996-11-13

  The invention relates to the colouration of high molecular weight organic materials in the mass with soluble phthalocyanine precursors of structure or isomers thereof, to the soluble phthalocyanine precursors as such wherein M in Zn, Ti or V or wherein L1 is morpholino, pyrrolidino or C1-C12alkyl substituted piperidino, to compositions containing high molecular weight organic materials and the above soluble phthalocyanine precursors, and to a process for making structured colour images and applications thereof.

  本发明涉及用可溶性酞菁前体对大量高分子量有机材料进行着色，其结构为 或其异构体，涉及 M 为 Zn、Ti 或 V 或 L1 为吗啉基、吡咯烷基或 C1-C12 烷基取代哌啶基的可溶性酞菁前体，涉及含有高分子量有机材料和上述可溶性酞菁前体的组合物，还涉及制作结构化彩色图像的工艺及其应用。