(E)-6-hydroxy-2,6-dimethylocta-2,7-dien-1-yl acetate | 64777-00-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (E)-6-hydroxy-2,6-dimethylocta-2,7-dien-1-yl acetate
• 英文别名: 8-acetoxylinalool；(E)-8-acetoxy-3,7-dimethyl-1,6-octadiene-3-ol；[(2E)-6-hydroxy-2,6-dimethylocta-2,7-dienyl] acetate
• CAS: 64777-00-0
• 化学式: C₁₂H₂₀O₃
• 分子量: 212.289
• InChiKey: BOJXRPGLMTUOEQ-JXMROGBWSA-N

物化性质

• 沸点：
  302.5±42.0 °C(Predicted)
• 密度：
  0.982±0.06 g/cm3(Predicted)
• 保留指数：
  2362

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  15
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.58
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  6-氯-3,7-二甲基辛-1,7-二烯-3-醇 以 N,N-二甲基乙酰胺 为溶剂， 以60% and 29%的产率得到(E)-6-hydroxy-2,6-dimethylocta-2,7-dien-1-yl acetate
  参考文献：
  名称：

  Functionalization of terminal trisubstituted alkenes and derivatives

  摘要：

  该发明涉及一种制备具有以下一般结构的化合物的过程：其中R是氢或包含1到约10个碳原子的非环状或脂环状片段，R1是氢或含有1到约4个碳原子的烷基或芳基。

  公开号：

  US04510319A1

文献信息

• Chirality and biosynthesis of lilac compounds in Actinidia arguta flowers
  作者：A.J. Matich、B.J. Bunn、D.J. Comeskey、M.B. Hunt、D.D. Rowan

  DOI：10.1016/j.phytochem.2007.03.023

  日期：2007.7

  Biosynthesis of lilac compounds in 'Hortgem Tahi' kiwifruit (Actinidia arguta) flowers was investigated by treating inflorescences with d(5)-linalool. The incorporation of the deuterium label into 8-hydroxylinalool, 8-oxolinalool, the lilac aldehydes, alcohols, and alcohol epoxides was followed by GGMS and enantioselective GC-MS. Both (R)- and (S)-linalool were produced naturally by the flowers, but 8-hydroxylinalool, 8-oxolinalool, and the lilac aldehydes and alcohols occurred predominantly as the (S) and 5'(S)-diastereoisomers, respectively. The enantio selective step in the biosynthesis of the lilac aldehydes and alcohols was concluded to be the oxidation of linalool to (S)-8-hydroxylinalool. In contrast, the lilac alcohol epoxides had a 5'(R):(S) ratio, the same as for linalool, which suggests that either these compounds are not synthesised from the 5'(S)-configured lilac aldehydes and alcohols, or that if indeed they are, then it is by an enantioselective step that favours utilisation of the 5'(R)-configured compounds. (c) 2007 Elsevier Ltd. All rights reserved.
• US4510319A
  申请人：——

  公开号：US4510319A

  公开（公告）日：1985-04-09
• Functionalization of terminal trisubstituted alkenes and derivatives
  申请人：Fritzsche Dodge & Olcott Inc.

  公开号：US04510319A1

  公开（公告）日：1985-04-09

  The invention relates to a process for preparing compounds having the general structure: ##STR1## wherein R is hydrogen or an acyclic or alicyclic fragment containing between one and about ten carbon atoms, and R.sub.1 is hydrogen or an alkyl containing between one and about four carbon atoms or an aryl group.

  该发明涉及一种制备具有以下一般结构的化合物的过程：其中R是氢或包含1到约10个碳原子的非环状或脂环状片段，R1是氢或含有1到约4个碳原子的烷基或芳基。