Pentaerythritoltrichloridmonoacetat | 13103-49-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Pentaerythritoltrichloridmonoacetat
• 英文别名: Pentaerythrit-trichlorhydrin-monoacetat；Monoacetyl-trichlor-pentaerythrit；Pentaerythrittrischlorhydrinacetat；Pentaerythrittrichlorhydrinacetat；acetic acid-(3-chloro-2,2-bis-chloromethyl-propyl ester)；Essigsaeure-(3-chlor-2,2-bis-chlormethyl-propylester)；[3-Chloro-2,2-bis(chloromethyl)propyl] acetate；[3-chloro-2,2-bis(chloromethyl)propyl] acetate
• CAS: 13103-49-6
• 化学式: C₇H₁₁Cl₃O₂
• 分子量: 233.522
• InChiKey: QNEVLHBCVBSUMX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Pentaerythritoltrichloridmonoacetat 在 sodium hydroxide 作用下， 生成 3-氯-2,2-二(氯甲基)丙-1-醇
  参考文献：
  名称：

  US2835709

  摘要：

  公开号：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 三氯化铝 作用下， 生成 Pentaerythritoltrichloridmonoacetat
  参考文献：
  名称：

  Dobrjanski; Ssiwerzew, Zhurnal Obshchei Khimii, 1947, vol. 17, p. 910

  摘要：

  DOI：

文献信息

• Synthesis of energetic polyester thermoplastic homopolymers and energetic thermoplastic elastomers formed therefrom
  申请人：Department of National Defence

  公开号：EP1229009A1

  公开（公告）日：2002-08-07

  Polymerization of α-bromomethyl-α-methyl-β-propiolactone (BMMPL) or α-chloromethyl-α-methyl-β-propiolactone (CMMPL) yielded thermoplastic homopolymers that upon azidation led to a novel energetic thermoplastic polyester: poly(α-azidomethyl-α-methyl-β-propiolactone) (PAMMPL). An energetic copolyether-ester thermoplastic elastomer was prepared by using glycidyl azide polymer, a dihydroxyl terminated energetic polymer, as a macroinitiator for the polymerization of BMMPL or CMMPL. The azidation of the resulting copolyether-ester yielded an energetic thermoplastic elastomer that melted at between 80°C and 85°C. Polymerization of α-dibromomethyl-β-propiolactone (DBMPL) resulted in a polymer which upon azidation yielded a new energetic polymer that can be used as a binder or into an energetic thermoplastic elastomer synthesis.

  α-溴甲基-α-甲基-β-丙内酯（BMMPL）或α-氯甲基-α-甲基-β-丙内酯（CMMPL）聚合生成热塑性均聚物，叠氮化后可生成新型高能热塑性聚酯：聚（α-叠氮甲基-α-甲基-β-丙内酯）（PAMMPL）。使用缩水甘油叠氮聚合物（一种二羟基封端的高能聚合物）作为 BMMPL 或 CMMPL 聚合的大引发剂，制备了一种高能共聚醚酯热塑性弹性体。对所得到的共聚醚酯进行叠氮化处理后，可得到一种高能热塑性弹性体，其熔化温度在 80°C 至 85°C 之间。α-dibromomethyl-β-propiolactone (DBMPL) 的聚合产生了一种聚合物，叠氮化后产生了一种新的高能聚合物，可用作粘合剂或合成高能热塑性弹性体。
• SYNTHESIS OF ENERGETIC POLYESTER THERMOPLASTIC HOMOPOLYMERS AND ENERGETIC THERMOPLASTIC ELASTOMERS FORMED THEREFROM
  申请人：——

  公开号：US20020103307A1

  公开（公告）日：2002-08-01

  Polymerization of &agr;-bromomethyl-&agr;-methyl-&bgr;-propiolactone (BMMPL) or &agr;-chloromethyl-&agr;-methyl-&bgr;-propiolactone (CMMPL) yielded thermoplastic homopolymers that upon azidation led to a novel energetic thermoplastic polyester: poly(&agr;-azidomethyl-&agr;-methyl-&bgr;-propiolactone) (PAMMPL). An energetic copolyether-ester thermoplastic elastomer was prepared by using glycidyl azide polymer, a dihydroxyl terminated energetic polymer, as a macroinitiator for the polymerization of BMMPL or CMMPL. The azidation of the resulting copolyether-ester yielded an energetic thermoplastic elastomer that melted at between 80° C. and 85° C. Polymerization of &agr;-dibromomethyl-&bgr;-propiolactone (DBMPL) resulted in a polymer which upon azidation yielded a new energetic polymer that can be used as a binder or into an energetic thermoplastic elastomer synthesis.

  &agr;-溴甲基-&agr;-甲基-&bgr;-丙内酯（BMMPL）或&agr;-氯甲基-&agr;-甲基-&bgr;-丙内酯（CMMPL）聚合生成热塑性均聚物，叠氮化后可生成新型高能热塑性聚酯：聚（&agr;-叠氮甲基-&agr;-甲基-&bgr;-丙内酯）（PAMMPL）。使用缩水甘油叠氮聚合物（一种二羟基封端的高能聚合物）作为 BMMPL 或 CMMPL 聚合的大引发剂，制备了一种高能共聚醚酯热塑性弹性体。叠氮化后的共聚醚酯可生成一种高能热塑性弹性体，其熔融温度在 80°C 至 85°C 之间。
• Some Reactions of 3,3-Bis(chloromethyl)oxetane
  作者：TOD W. CAMPBELL

  DOI：10.1021/jo01360a008

  日期：1957.9
• Ssiwerzew, Vestnik, Leningradskogo Universiteta, 1947, vol. 2, # 8, p. 98
  作者：Ssiwerzew

  DOI：——

  日期：——
• US2835709
  申请人：——

  公开号：——

  公开（公告）日：——