N-[2-bromo-6-chloro-4-[1,1,1,2,3,3,3-heptafluoroprop-2-yl]phenyl]-3-[(4-cyanobenzoyl)ethylamino]-2-methoxybenzamide | 1609007-65-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-[2-bromo-6-chloro-4-[1,1,1,2,3,3,3-heptafluoroprop-2-yl]phenyl]-3-[(4-cyanobenzoyl)ethylamino]-2-methoxybenzamide
• 英文别名: N-[2-bromo-6-chloro-4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]phenyl]-3-[(4-cyanobenzoyl)ethylamino]-2-methoxybenzamide；N-[2-bromo-6-chloro-4-[1,1,1,2,3,3,3-heptafluoroprop-2-yl]phenyl]-3-[(4-cyanobenzoyl)-N-ethylamino]-2-methoxybenzamide；N-[2-bromo-6-chloro-4-[1,1,1,2,3,3,3-heptafluoro-prop-2-yl]phenyl]-3-[(4-cyanobenzoyl)-ethyl-amino]-2-methoxy-benzamide；N-[2-bromo-6-chloro-4-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)phenyl]-3-[(4-cyanobenzoyl)-ethylamino]-2-methoxybenzamide
• CAS: 1609007-65-9
• 化学式: C₂₇H₁₈BrClF₇N₃O₃
• 分子量: 680.804
• InChiKey: RNECUELNFAHXNK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  42
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  82.4
• 氢给体数：
  1
• 氢受体数：
  11

反应信息

• 作为产物：
  描述：

  N-[2-bromo-6-chloro-4-(1,1,1,2,3,3,3-heptafluoroprop-2-yl)phenyl]-2-methoxy-3-nitrobenzamide 在 吡啶 、 sodium dithionite 、 四丁基溴化铵 、 sodium cyanoborohydride 、 溶剂黄146 、 sodium hydroxide 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 反应 6.5h， 生成 N-[2-bromo-6-chloro-4-[1,1,1,2,3,3,3-heptafluoroprop-2-yl]phenyl]-3-[(4-cyanobenzoyl)ethylamino]-2-methoxybenzamide
  参考文献：
  名称：

  INSECTICIDAL COMPOUNDS

  摘要：

  本发明涉及具有杀虫活性的新型三唑衍生物（I）的公式，以及用于制备它们的过程和中间体，包括含有它们的杀虫剂、杀螨剂、杀线虫剂或杀软体动物剂的组合物，以及使用它们来对抗和控制昆虫、螨类、线虫或软体动物害虫的方法，其中R1、R2、G1、G2、Q1和Q2如权利要求1所定义；或其盐。

  公开号：

  US20170305839A1

文献信息

• HETEROCYCLIC COMPOUNDS AND NOXIOUS ARTHROPOD CONTROL AGENT CONTAINING SAME
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20200399278A1

  公开（公告）日：2020-12-24

  The present invention provides a compound having an excellent control effect on a harmful arthropod. A compound represented by formula (I) [wherein Q represents a group represented by Q1 or a group represented b Q2; Z represents an oxygen atom or a sulfur atom; A 1 represents a nitrogen atom or the like; A 2 represents a CR 4a or the like; A 3 represents a nitrogen atom, a CR 4b , or the like; B 1 represents a CR 1 or the like; B 2 represents a nitrogen atom, a CR 6b , or the like; B 3 represents a nitrogen atom, a CR 6c , or the like; R 1 represents a C1-C6 chain hydrocarbon group having one or more substituent(s) selected from the group consisting of a cyano group and a halogen atom, or the like; R 2 represents a C1-C6 chain hydrocarbon group or the like; R 3 represents a C1-C6 chain hydrocarbon group or the like; R 4a , R 4b , R 6b , and R 6c are identical to or different from each other, and each represent a hydrogen atom or the like; n represents 0, 1, or 2; and q represents 0, 1, 2, or 3] or an N-oxide compound thereof has an excellent control effect on a harmful arthropod.

  本发明提供了一种对有害节肢动物具有优异控制效果的化合物。由式（I）表示的化合物 [其中 Q代表由Q1表示的基团或由Q2表示的基团; Z代表氧原子或硫原子; A 1 代表氮原子或类似物; A 2 代表CR 4a 或类似物; A 3 代表氮原子、CR 4b 或类似物; B 1 代表CR 1 或类似物; B 2 代表氮原子、CR 6b 或类似物; B 3 代表氮原子、CR 6c 或类似物; R 1 代表具有来自氰基团和卤原子等组成的一个或多个取代基的C1-C6链烃基，或类似物; R 2 代表C1-C6链烃基或类似物; R 3 代表C1-C6链烃基或类似物; R 4a 、R 4b 、R 6b 和R 6c 彼此相同或不同，每个代表氢原子或类似物; n代表0、1或2;以及 q代表0、1、2或3] 或其N-氧化物在有害节肢动物上具有优异的控制效果。
• HETEROCYCLIC COMPOUND AND ARTHROPOD PEST CONTROL COMPOSITION CONTAINING SAME
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20210030003A1

  公开（公告）日：2021-02-04

  The present invention provides a compound that has an excellent control effect on arthropod pests, and is represented by formula (I) [wherein Q represents a group represented by Q1, or the like, n is 0, 1, or 2, R 2 represents a C1-C6 alkyl group which may optionally have one or more halogen atoms, or the like, Y a represents an oxygen atom, a sulfur atom, or NR 3a , G 1 represents a nitrogen atom or CR 5a , G 2 represents a nitrogen atom or CR 5b , A 2 represents a nitrogen atom or CR 4a , A 3 represents a nitrogen atom or CR 4b , A 4 represents a nitrogen atom or CR 4c , and R 3a , R 4a , R 4b , R 4c , R 5a , and R 5b represent a C1-C6 chain hydrocarbon group or the like, and T represents a C1-C10 chain hydrocarbon group which may optionally have one or more halogen atoms, or the like].

  本发明提供了一种对节肢动物害虫具有优异控制效果的化合物，其化学式表示为（I）[其中Q代表由Q1等表示的基团，n为0、1或2，R2代表可能含有一个或多个卤素原子等的C1-C6烷基基团，Ya代表氧原子、硫原子或NR3a，G1代表氮原子或CR5a，G2代表氮原子或CR5b，A2代表氮原子或CR4a，A3代表氮原子或CR4b，A4代表氮原子或CR4c，而R3a、R4a、R4b、R4c、R5a和R5b代表C1-C6链烃基团等，T代表可能含有一个或多个卤素原子等的C1-C10链烃基团]。
• HETEROCYCLIC COMPOUND
  申请人：Sumitomo Chemical Company, Limited

  公开号：US20190040038A1

  公开（公告）日：2019-02-07

  A compound represented by formula (I) or an N-oxide compound thereof is provided with excellent control efficacies against harmful arthropods, wherein A 1 represents a nitrogen atom or a CR 4 ; R 4 represents a hydrogen atom, a OR 27 , a NR 27 R 28 , a cyano group, a nitro group, or a halogen atom; hereinafter referred to as “Het”, represents Het-1, Het-2, Het-3, or Het-4: wherein # 1 represents the binding position of Het and T, and # 2 represents the binding position of Het and T represents T-1, T-2, T-3, T-4, T-5, T-6, or T-7: R 1 represents a C1-C10 chain hydrocarbon group having one or more halogen atoms or the like; and R 2 represents a C1-C6 alkyl group optionally having one or more halogen atoms or the like.

  提供了由化学式（I）表示的化合物或其N-氧化物，对有害节肢动物具有出色的控制效果，其中A1表示氮原子或CR4；R4表示氢原子、OR27、NR27R28、氰基、硝基或卤素原子；下文中所称的“Het”表示Het-1、Het-2、Het-3或Het-4：其中#1表示Het和T的结合位置，#2表示Het和T的结合位置，T表示T-1、T-2、T-3、T-4、T-5、T-6或T-7：R1表示具有一个或多个卤素原子的C1-C10链烃基；R2表示可选地具有一个或多个卤素原子的C1-C6烷基基团。
• FUSED HETEROCYCLIC COMPOUND AND COMPOSITION CONTAINING SAME
  申请人：Sumitomo Chemical Company, Limited

  公开号：US20200071320A1

  公开（公告）日：2020-03-05

  A compound of formula (I) is provided. In the compound of formula (I), Q represents a group represented by formula Q1 or the like and the rest of the variable definitions are as set forth in the specification. The compounds of formula (I) have excellent control efficacy against harmful arthropods.

  提供了一种化合物的化学式（I）。在化合物的化学式（I）中，Q代表由化学式Q1或类似化学式表示的基团，其余变量定义如规范中所述。化学式（I）的化合物对有害的节肢动物具有出色的控制效果。
• HETEROCYCLIC COMPOUND AND HARMFUL ARTHROPOD CONTROLLING AGENT CONTAINING SAME
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20210084903A1

  公开（公告）日：2021-03-25

  The present invention provides a compound substituted with an excellent control effect against a harmful arthropod, which is represented by formula (I) Het-Q  (I) wherein Q represents a group represented by Q1, etc., Het represents a group represented by Het1, etc., R 2 represents a C1-C6 alkyl group, etc., G 1 represents a nitrogen atom or CR 3a , G 2 represents a nitrogen atom or CR 3b , G 3 represents a nitrogen atom or CR 3c , G 4 represents a nitrogen atom or CR 3d , R 3a , R 3b , R 3c , and R 3d are identical to or different from each other and represent a C1-C6 chain hydrocarbon group, etc., n represents 0, 1, or 2, T represents a C1-C10 chain hydrocarbon group substituted with one or more halogen atoms, etc., A 2 represents a nitrogen atom or CR 4a , A 3 represents a nitrogen atom or CR 4b , R 4a and R 4b are identical to or different from each other and represent a C1-C6 chain hydrocarbon group, W 1 represents an oxygen atom, etc., and R 6 represents a C1-C6 chain hydrocarbon group, etc.

  本发明提供了一种具有对有害节肢动物具有优异控制效果的化合物，其表示为公式（I）Het-Q（I），其中Q代表由Q1等表示的基团，Het代表由Het1等表示的基团，R2代表C1-C6烷基基团等，G1代表氮原子或CR3a，G2代表氮原子或CR3b，G3代表氮原子或CR3c，G4代表氮原子或CR3d，R3a、R3b、R3c和R3d彼此相同或不同且代表C1-C6链烃基团等，n代表0、1或2，T代表一个或多个卤原子取代的C1-C10链烃基团等，A2代表氮原子或CR4a，A3代表氮原子或CR4b，R4a和R4b彼此相同或不同且代表C1-C6链烃基团，W1代表氧原子等，R6代表C1-C6链烃基团等。