Rh(5,10,15,20-tetratolylporphyrinato)(β-N,N-dibenzylaminoethyl) | 855308-12-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: Rh(5,10,15,20-tetratolylporphyrinato)(β-N,N-dibenzylaminoethyl)
• CAS: 855308-12-2
• 化学式: C₆₄H₅₄N₅Rh
• 分子量: 996.072
• InChiKey: AGMPNJZJKRWFOM-HTMHXADGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Rh(5,10,15,20-tetratolylporphyrinato)(β-N,N-dibenzylaminoethyl) 以 氘代苯 为溶剂， 生成 Rh(5,10,15,20-tetratolylporphyrinato)(α-N,N-dibenzylaminoethyl)
  参考文献：
  名称：

  1,2-Rearrangements of β-Nitrogen-Substituted (Porphyrinato)rhodium(III) Ethyls

  摘要：

  (Porphyrinato)rhodium(III) ethyls containing beta-nitrogen substituents have been showed to undergo clean, thermal 1,2-rearrangements into the alpha-nitrogen-substituted rhodium ethyls. The rates and the equilibrium positions were found to be dependent on the electronic nature of the N substituents. Complexes 1a-3a were characterized by X-ray crystallography.

  DOI：

  10.1021/om0501475
• 作为产物：
  描述：

  rhodium(III) tetrakis(4-tolyl)porphyrin chloride 、 N,N-二苄基-2-溴乙胺 在 sodium tetrahydroborate 作用下， 以 not given 为溶剂， 以39%的产率得到Rh(5,10,15,20-tetratolylporphyrinato)(β-N,N-dibenzylaminoethyl)
  参考文献：
  名称：

  1,2-Rearrangements of β-Nitrogen-Substituted (Porphyrinato)rhodium(III) Ethyls

  摘要：

  (Porphyrinato)rhodium(III) ethyls containing beta-nitrogen substituents have been showed to undergo clean, thermal 1,2-rearrangements into the alpha-nitrogen-substituted rhodium ethyls. The rates and the equilibrium positions were found to be dependent on the electronic nature of the N substituents. Complexes 1a-3a were characterized by X-ray crystallography.

  DOI：

  10.1021/om0501475