1,1-Dimesityl-2,2-bis-(2,4,6-triisopropylphenyl)disilan | 149792-92-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,1-Dimesityl-2,2-bis-(2,4,6-triisopropylphenyl)disilan
• CAS: 149792-92-7
• 化学式: C₄₈H₇₀Si₂
• 分子量: 703.255
• InChiKey: RWCNBWHFUCIPLT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.74
• 重原子数：
  50.0
• 可旋转键数：
  11.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  1,1-Dimesityl-2,2-bis-(2,4,6-triisopropylphenyl)disilan 在 N-氯代丁二酰亚胺 、 lithium 作用下， 以 乙二醇二甲醚 为溶剂， 反应 144.0h， 生成 1,1-Dimesityl-2,2-bis(2,4,6-triisopropylphenyl)disilen
  参考文献：
  名称：

  Siliciumverbindungen mit starken intramolekularen sterischen wechselwirkungen

  摘要：

  Treatment of chlorobis(2,4,6-triisopropylphenyl)silane (Ar2SiHCl) with lithium naphthalenide and subsequent,addition of the chlorosilanes R2SiHCl (R =(i)Pr, (t)Bu, Mes) gives the unsymmetrical disilanes R2HSiSiHAr2 which are smoothly converted into the 1,2-dichlorodisilanes 8-10. The X-ray structure analysis of the 1,1-dimesityldisilane 10 reveals a staggered conformation with the chlorine atoms disposed in an anti orientation. Whilst the reductive chloride elimination from the 1,1-dialkyldichlorodisilanes 8 and 9 did not give the corresponding disilenes, the same reaction of 10 provided bright yellow crystals of 1,1-dimesityl-2,2-bis(2,4,6-triisopropylphenyl)disilene, the structure of which was confirmed by a complete NMR study.

  DOI：

  10.1016/0022-328x(93)80138-2
• 作为产物：
  描述：

  Chlordimesitylsilan 、 chlorobis(2,4,6-triisopropylphenyl)silane 在 naphthalen-1-yl-lithium 作用下， 生成 1,1-Dimesityl-2,2-bis-(2,4,6-triisopropylphenyl)disilan
  参考文献：
  名称：

  Siliciumverbindungen mit starken intramolekularen sterischen wechselwirkungen

  摘要：

  Treatment of chlorobis(2,4,6-triisopropylphenyl)silane (Ar2SiHCl) with lithium naphthalenide and subsequent,addition of the chlorosilanes R2SiHCl (R =(i)Pr, (t)Bu, Mes) gives the unsymmetrical disilanes R2HSiSiHAr2 which are smoothly converted into the 1,2-dichlorodisilanes 8-10. The X-ray structure analysis of the 1,1-dimesityldisilane 10 reveals a staggered conformation with the chlorine atoms disposed in an anti orientation. Whilst the reductive chloride elimination from the 1,1-dialkyldichlorodisilanes 8 and 9 did not give the corresponding disilenes, the same reaction of 10 provided bright yellow crystals of 1,1-dimesityl-2,2-bis(2,4,6-triisopropylphenyl)disilene, the structure of which was confirmed by a complete NMR study.

  DOI：

  10.1016/0022-328x(93)80138-2