2-iodo-4-methyl-1-(p-tolyloxy)benzene | 2236-41-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-iodo-4-methyl-1-(p-tolyloxy)benzene
• 英文别名: 2-Iod-4,4'-dimethyl-diphenylether；2-Iodo-4-methyl-1-(4-methylphenoxy)benzene；2-iodo-4-methyl-1-(4-methylphenoxy)benzene
• CAS: 2236-41-1
• 化学式: C₁₄H₁₃IO
• 分子量: 324.161
• InChiKey: NWBYLTFHWRUEKN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-iodo-4-methyl-1-(p-tolyloxy)benzene 生成 3,7-dimethyl-pheniodoxinium; iodide
  参考文献：
  名称：

  Iodonium Salts Containing Heterocyclic Iodine^1-3

  摘要：

  DOI：

  10.1021/jo01015a046
• 作为产物：
  描述：

  5-Methyl-2-(4-methylphenoxy)benzenamine 在 对甲苯磺酸 、 potassium iodide 、 sodium nitrite 作用下， 以 水 、 乙腈 为溶剂， 反应 16.0h， 以26%的产率得到2-iodo-4-methyl-1-(p-tolyloxy)benzene
  参考文献：
  名称：

  四和六重串联多米诺骨牌反应导致适合分子开关的二聚四取代的烯烃。

  摘要：

  由两个carbopalladation和两个C的A高效钯催化四倍串联多米诺反应 H-活化步骤是为两种类型的四取代烯烃的合成开发3和6与固有螺旋从手性起始衬底1和4， 分别。通过包括Sonogashira反应，还开发了六倍串联-多米诺反应。制备了20种具有不同取代模式的化合物，收率高达97％。X射线晶体学对结构的阐明证实了两个烯烃部分的螺旋手性。对某些化合物的光物理研究表明，通过光控制其立体化学构型的变化，可以获得明显的开关性能。

  DOI：

  10.1002/anie.201503538

文献信息

• Liquid crystal display device
  申请人：SHARP KABUSHIKI KAISHA

  公开号：US10989964B2

  公开（公告）日：2021-04-27

  The present invention provides a liquid crystal display device that can retain a favorable VHR and a low residual DC voltage and minimize display unevenness such as stains and image sticking, in long-term use at high temperatures. The liquid crystal display device includes a first substrate including a pixel electrode; a second substrate facing the first substrate; a liquid crystal layer sandwiched between the first substrate and the second substrate; an aromatic polyimide-based alignment film disposed on at least one of the first substrate and the second substrate; and a radical generator capable of supplying a radical to the liquid crystal layer upon being irradiated with light, the liquid crystal layer containing a liquid crystal compound with an alkenyl group, the aromatic polyimide-based alignment film containing at least one polymer selected from a polyimide and a polyamic acid and being in no contact with the pixel electrode, the at least one polymer containing an aromatic tetracarboxylic dianhydride monomer unit.

  本发明提供了一种液晶显示装置，该装置在高温下长期使用时可保持良好的 VHR 和较低的残余直流电压，并最大限度地减少显示不平整现象，例如污点和图像粘连。该液晶显示装置包括：包括像素电极的第一基板；面向第一基板的第二基板；夹在第一基板和第二基板之间的液晶层；设置在第一基板和第二基板中至少一个基板上的芳香族聚酰亚胺基配向膜；液晶层含有带烯基的液晶化合物，芳香族聚酰亚胺对位膜含有至少一种选自聚酰亚胺和聚酰胺酸的聚合物，且与像素电极不接触，至少一种聚合物含有芳香族四羧酸二酐单体单元。
• LIQUID CRYSTAL DISPLAY DEVICE
  申请人：SHARP KABUSHIKI KAISHA

  公开号：US20190033665A1

  公开（公告）日：2019-01-31

  The present invention provides a liquid crystal display device that can retain a favorable VHR and a low residual DC voltage and minimize display unevenness such as stains and image sticking, in long-term use at high temperatures. The liquid crystal display device includes a first substrate including a pixel electrode; a second substrate facing the first substrate; a liquid crystal layer sandwiched between the first substrate and the second substrate; an aromatic polyimide-based alignment film disposed on at least one of the first substrate and the second substrate; and a radical generator capable of supplying a radical to the liquid crystal layer upon being irradiated with light, the liquid crystal layer containing a liquid crystal compound with an alkenyl group, the aromatic polyimide-based alignment film containing at least one polymer selected from a polyimide and a polyamic acid and being in no contact with the pixel electrode, the at least one polymer containing an aromatic tetracarboxylic dianhydride monomer unit.