[1,1';3',1'']Terphenyl-4,4''-dicarbonyl dichloride | 158228-76-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [1,1';3',1'']Terphenyl-4,4''-dicarbonyl dichloride
• CAS: 158228-76-3
• 化学式: C₂₀H₁₂Cl₂O₂
• 分子量: 355.22
• InChiKey: UIENLXGVHVNSHA-UHFFFAOYSA-N

物化性质

• 沸点：
  504.8±43.0 °C(predicted)
• 密度：
  1.301±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.78
• 重原子数：
  24.0
• 可旋转键数：
  4.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  34.14
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  [1,1';3',1'']Terphenyl-4,4''-dicarbonyl dichloride 、 5-(3-Amino-2,6-dichlorophenyl)-10,15,20-tris(2,6-dichlorophenyl)porphyrin 以 N,N-二甲基乙酰胺 为溶剂， 以57%的产率得到bis-<5,5'-<3-(4,4''-dicarbamoyl-1,1':3',1''-terphenyl)-2,6-dichlorophenyl>-10,10',15,15',20,20'-tri-(2,6-dichlorophenyl)>porphyrin
  参考文献：
  名称：

  Dimeric Mn(III)-tetraarylporphyrins as catalysts for H2O2-promoted olefin epoxidation.

  摘要：

  The first example of dimeric Mn(III)-tetraarylporphyrins able to catalyze olefin epoxidation is reported. In the presence of one equivalent of lipophilic bidentate ligand 3 the efficiency of some of these catalysts is among the highest reported to now in 30% H2O2-promoted epoxidation (up to 1500 overall catalytic cycles). Slightly better results were obtained replacing 3 with two equivalents of N-hexylimidazole 10.

  DOI：

  10.1016/s0040-4020(01)85369-2
• 作为产物：
  描述：

  4,4''-dicarbomethoxy-1,1':3',1''-terphenyl 在 氯化亚砜 、 hydroxide 作用下， 生成 [1,1';3',1'']Terphenyl-4,4''-dicarbonyl dichloride
  参考文献：
  名称：

  Dimeric Mn(III)-tetraarylporphyrins as catalysts for H2O2-promoted olefin epoxidation.

  摘要：

  The first example of dimeric Mn(III)-tetraarylporphyrins able to catalyze olefin epoxidation is reported. In the presence of one equivalent of lipophilic bidentate ligand 3 the efficiency of some of these catalysts is among the highest reported to now in 30% H2O2-promoted epoxidation (up to 1500 overall catalytic cycles). Slightly better results were obtained replacing 3 with two equivalents of N-hexylimidazole 10.

  DOI：

  10.1016/s0040-4020(01)85369-2