6-(4-氨基苯基)磺酰己烷-1-醇 | 131110-20-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 6-(4-氨基苯基)磺酰己烷-1-醇
• 英文名称: 4-aminophenyl-6-hydroxysulfone
• 英文别名: 4-aminophenyl 6-hydroxyhexyl sulfone；6-(4-Aminobenzene-1-sulfonyl)hexan-1-ol；6-(4-aminophenyl)sulfonylhexan-1-ol
• CAS: 131110-20-8
• 化学式: C₁₂H₁₉NO₃S
• 分子量: 257.354
• InChiKey: BXZMJZRUPDRVFD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  17
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  88.8
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  6-(4-氨基苯基)磺酰己烷-1-醇 在 盐酸 、 sodium nitrite 作用下， 以 乙醇 、 N,N-二甲基甲酰胺 为溶剂， 反应 48.0h， 生成
  参考文献：
  名称：

  Organic-Inorganic Hybrid Materials for Nonlinear Optics Applications

  摘要：

  Three types of organic-inorganic hybrid materials were prepared by the sol-gel processable monomers derived from 3-isocyanatopropyltriethoxysilane with three different hydroxy-functionalized nonlinear optical chromophores. The measured values of NLO coefficient strongly depended on conditions such as poling temperature, poling time and heating rate. The hybrid films heated at 200 degreesC exhibited d(33) = 50-58 pm/V in Maker-fringe measurement. It was found that the thermal stabilities of the films were greatly enhanced as poling time increased and a poling temperature became higher. Also, we observed good waveguiding properties of the films at 810 nm and 1063 nm. The optical propagation losses of the films for TE mode were about 2 dB/cm at 810 nm and 0.5 dB/cm at 1064 nm.

  DOI：

  10.1080/10587250008025686
• 作为产物：
  描述：

  6-((4-nitrophenyl)thio)hexan-1-ol 在 间氯过氧苯甲酸 、 tin(ll) chloride 作用下， 以 乙醇 、 二氯甲烷 为溶剂， 反应 16.0h， 生成 6-(4-氨基苯基)磺酰己烷-1-醇
  参考文献：
  名称：

  手性脯氨醇取代发色团的合成及二阶非线性

  摘要：

  合成了一系列新的含噻吩和呋喃的发色团，具有手性脯氨醇供体和砜受体。描述了紫外-可见吸收、二阶非线性光学特性和 X 射线晶体结构。

  DOI：

  10.1002/jccs.200400072

文献信息

• Optical article containing a linear condensation polymer exhibiting a
  申请人：Eastman Kodak Company

  公开号：US05075043A1

  公开（公告）日：1991-12-24

  An optical article is disclosed containing, for the transmission of electromagnetic radiation, a medium exhibiting a second order polarization susceptibility greater than 10.sup.-9 electrostatic units comprised of a linear polymer containing polar aligned noncentrosymmetric molecular dipoles having an electron donor moiety linked through a conjugated .pi. bonding system to an electron acceptor moiety to permit oscillation of the molecular dipole between a ground state exhibiting a first dipole moment and an excited state exhibiting a differing dipole moment. The linear polymer is a condensation polymer including in its backbone a plurality of molecular dipoles including sulfonyl electron acceptor moieties sequentially arranged to reinforce electron displacement along the polymer backbone.

  本发明揭示了一种光学物品，用于传输电磁辐射，其介质具有二级极化敏感性大于10.sup.-9静电单位，包括线性聚合物，其中包含极性对齐的非中心对称分子偶极子，具有通过共轭π键系统连接到电子受体基团的电子给体基团，以允许分子偶极子在展示第一偶极矩的基态和展示不同偶极矩的激发态之间振荡。线性聚合物是一种缩合聚合物，其主链中包含多个分子偶极子，包括顺序排列的磺酰基电子受体基团，以加强沿聚合物主链的电子位移。
• An optical article containing a linear condensation polymer exhibiting a high level of second order polarization susceptibility
  申请人：EASTMAN KODAK COMPANY

  公开号：EP0370922A2

  公开（公告）日：1990-05-30

  An optical article is disclosed containing, for the transmission of electromagnetic radiation, a medium exhibiting a second order polarization susceptibility greater than 10⁻⁹ electrostatic units comprised of a linear polymer containing polar aligned noncentrosymmetric molecular dipoles having an electron donor moiety linked through a conjugated π bonding system to an electron acceptor moiety to permit oscillation of the molecular dipole between a ground state exhibiting a first dipole moment and an excited state exhibiting a differing dipole moment. The linear polymer is a condensation polymer including in its backbone a plurality of molecular dipoles including sulfonyl electron acceptor moieties sequentially arranged to reinforce electron displacement along the polymer backbone.

  本发明公开了一种用于传输电磁辐射的光学产品，该产品含有一种介质，该介质显示出大于 10-𠞙 静电单位的二阶偏振电感，该介质由线性聚合物组成，该线性聚合物含有极性排列的非中心对称分子偶极子，该分子偶极子具有电子供体分子，该电子供体分子通过共轭 π 键系统与电子受体分子相连，从而允许分子偶极子在显示第一偶极矩的基态和显示不同偶极矩的激发态之间摆动。线性聚合物是一种缩聚聚合物，在其骨架中包含多个分子偶极，其中包括依次排列的磺酰电子受体分子，以加强沿聚合物骨架的电子位移。
• Synthesis and Characterization of Photorefractive Polymer containing Multifunctional Chromophore
  作者：Joo Yeon Kim、Kwang-Sup Lee

  DOI：10.1080/10587250108030059

  日期：2001.10

  The main chain photorefractive polymer (PUA-M) having multifunctional chromophore was synthesized by the step-growth polymerization from N-hydroxyethycarbazole-4'-[6-(hydroxysulfonyl)]-azobenzene (Azo-2OH) and 1,6-hexamethylene diisocyanate. The molecular weight of the resulting polymer was determined to be M-w=41,300 (M-w/M-n=1.19) by the gel permeation chromatography using polystyrene as a standard, and could be processed into optical quality films. The thermal properties of PUA-M were detected by DSC and TGA. It shows a glass transition temperature of 183 degreesC and an initial decomposition temperature of 223 degreesC. The absorption maximum in UV/vis spectrum of PUA-M film was detected at 416 mn. The second-order nonlinear coefficient (d(33)) of PUA-M was about 27 pm/V. The studies into the detailed photorefractive properties for this polymer is in progress.
• US5075043A
  申请人：——

  公开号：US5075043A

  公开（公告）日：1991-12-24
• Organic-Inorganic Hybrid Materials for Nonlinear Optics Applications
  作者：Kwang-Sup Lee、Tae-Dong Kim、Yu Hong Min、Choon Sup Yoon、Marek Samoc、Anna Samoc

  DOI：10.1080/10587250008025686

  日期：2000.12

  Three types of organic-inorganic hybrid materials were prepared by the sol-gel processable monomers derived from 3-isocyanatopropyltriethoxysilane with three different hydroxy-functionalized nonlinear optical chromophores. The measured values of NLO coefficient strongly depended on conditions such as poling temperature, poling time and heating rate. The hybrid films heated at 200 degreesC exhibited d(33) = 50-58 pm/V in Maker-fringe measurement. It was found that the thermal stabilities of the films were greatly enhanced as poling time increased and a poling temperature became higher. Also, we observed good waveguiding properties of the films at 810 nm and 1063 nm. The optical propagation losses of the films for TE mode were about 2 dB/cm at 810 nm and 0.5 dB/cm at 1064 nm.