2-methoxy-5-methylcyclohepta-2,4,6-trien-1-one | 38768-21-7

• 分子结构分类: 有机化合物 - 碳氢化合物衍生物 - 环庚三烯酮
• 英文名称: 2-methoxy-5-methylcyclohepta-2,4,6-trien-1-one
• 英文别名: 2-methoxy-5-methyltropolone；2-methoxy-5-methyl-cycloheptatrienone；2-Methoxy-5-methyl-cycloheptatrienon；2-methoxy-5-methyl-2,4,6-cycloheptatrien-1-one
• CAS: 38768-21-7
• 化学式: C₉H₁₀O₂
• 分子量: 150.177
• InChiKey: WYYYRLDUBAISHA-UHFFFAOYSA-N

物化性质

• 沸点：
  290.6±29.0 °C(Predicted)
• 密度：
  1.05±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-methoxy-5-methylcyclohepta-2,4,6-trien-1-one 在 盐酸 、 水 、 一水合肼 、 copper(II) sulfate 作用下， 反应 2.0h， 生成 2-Chlor-5-methyl-tropon
  参考文献：
  名称：

  Sato, Nippon Kagaku Zasshi, 1959, vol. 80, p. 1347

  摘要：

  DOI：
• 作为产物：
  描述：

  2-methoxy-5-phenylcyclohepta-2,4,6-trien-1-one 以2%的产率得到
  参考文献：
  名称：

  BANWELL, MARTIN G.;CAMERON, JENNIFER M.;COLLIS, MAREE P.;CRISP, GEOFFREY +, AUSTRAL. J. CHEM., 44,(1991) N, C. 705-728

  摘要：

  DOI：

文献信息

• Methine dyes
  申请人：Fuji Photo Film Co., Ltd.

  公开号：US05003077A1

  公开（公告）日：1991-03-26

  Methine dye which contains a cycloheptimidazole nucleus having a substituent at its 1-position thereof and in which the 7-membered ring moiety is substituted by a methine bond having an auxochrome, at the terminal thereof, for forming a conjugated resonance chromophoric group with the 10 .pi. electron series of the nucleus, showing a long absorption with one or a few methine bonds and have high light-stability and solution-stability.

  含有环庚咪唑核并在其1-位置具有取代基的甲烷染料，其中7-成员环部分被具有辅基的甲烷键取代，用于与核心的10个.π.电子系列形成共轭共振色团，显示出具有一个或几个甲烷键的长吸收，并具有高光稳定性和溶液稳定性。
• The palladium-mediated cross-coupling of bromotropolones with organostannanes; application to concise syntheses of β-dolabrin, β-thujaplicin, 7-methoxy-4-isopropyltropolone, and β-thujaplicinol
  作者：Martin G. Banwell、Maree P. Collis、Geoffrey T. Crisp、John N. Lambert、Monica E. Reum、Judith A. Scoble

  DOI：10.1039/c39890000616

  日期：——

  The bromotropolones (1), (2), and (3) cross-couple with organostannanes in the presence of palladium(0) to produce alkyl, alkenyl, or aryl substituted tropolones; the methodology has been applied to the synthesis of the monoterpenes β-dolabrin (4), β-thujaplicin (5), 7-methoxy-4-isopropyltropolone (7), and β-thujaplicinol (8).

  在钯（0）的存在下，溴对苯二酮（1），（2）和（3）与有机锡烷交联以产生烷基，烯基或芳基取代的对苯二酚；该方法已被应用于合成单萜β-杜拉布林（4），β-thujaplicin（5），7-甲氧基-4-异丙基Tropolone （7）和β-thujaplicinol（8）。
• Optical information recording medium
  申请人：Fuji Photo Film Co., Ltd.

  公开号：US04900648A1

  公开（公告）日：1990-02-13

  The present invention relates to an optical information recording medium for carrying out recording, reproduction and erasing with laser beams which comprises a support having carried thereon at least one methine dye which consists of an azulene nucleus, at least one of 10 carbon atoms of which is replaced by chalcogen atom(s) and/or nitrogen atom(s), and further whose 7-membered ring part is substituted with a methine bond having at the terminal an auxochrome which forms a conjugated resonance chromophore together with a 10 .pi. electron system of the nucleus. Optical information recording media of the invention have adequate recording characteristics having high C/N, and have high stabilities against long-term preservation or against long-time reading.

  本发明涉及一种光学信息记录介质，用于通过激光束进行记录、再生和擦除，其包括一个支撑体，其上搭载至少一种甲基染料，该甲基染料由一个蓝莓核组成，其中至少有10个碳原子被硫族原子和/或氮原子所取代，且其7元环部分被一个甲基键取代，该甲基键在末端具有一个辅基，该辅基与核的10个π电子系统形成一个共轭共振色团。本发明的光学信息记录介质具有高C/N的充分记录特性，并且对长期保存或长时间阅读具有高稳定性。
• Triazole compounds and methods of making and using the same
  申请人：Bhattacharjee Ashoke

  公开号：US20100016956A1

  公开（公告）日：2010-01-21

  The present invention provides triazole macrocyclic compounds useful as therapeutic agents. More particularly, these compounds are useful as anti-infective, anti-proliferative, anti-inflammatory, and prokinetic agents. The compounds have the following structure: wherein T is the macrocyclic part.

  本发明提供了三唑大环化合物，作为治疗剂非常有用。更具体地说，这些化合物可用作抗感染、抗增殖、抗炎和促动力剂。化合物具有以下结构：其中T是大环部分。
• Triazole Compounds and Methods of Making and Using the Same
  申请人：Bhattacharjee Ashoke

  公开号：US20130065845A1

  公开（公告）日：2013-03-14

  The present invention provides triazole macrocyclic compounds useful as therapeutic agents. More particularly, these compounds are useful as anti-infective, anti-proliferative, anti-inflammatory, and prokinetic agents.

  本发明提供了三唑大环化合物，其作为治疗剂具有用途。更具体地说，这些化合物可作为抗感染、抗增殖、抗炎和促动力剂使用。