4-methyl-cyclohexane-1,2,3-tricarboxylic acid | 24447-82-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 4-methyl-cyclohexane-1,2,3-tricarboxylic acid
• 英文别名: 6-Methyl-3-carboxy-cis-hexahydrophthalsaeure；4-Methyl-cyclohexan-1,2,3-tricarbonsaeure；4-Methylcyclohexane-1,2,3-tricarboxylic acid
• CAS: 24447-82-3
• 化学式: C₁₀H₁₄O₆
• 分子量: 230.218
• InChiKey: FYGVLURPKLFVAB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  112
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  6-methyl-cyclohex-4-ene-1,2,3-tricarboxylic acid 在 钯 作用下， 生成 4-methyl-cyclohexane-1,2,3-tricarboxylic acid
  参考文献：
  名称：

  Farmer; Warren, Journal of the Chemical Society, 1929, p. 906

  摘要：

  DOI：

文献信息

• PROCESS FOR PRODUCING TRICARBOXYLIC ACID TRIS (ALKYL-SUBSTITUTED CYCLOHEXYLAMIDE)
  申请人：Kitagawa Sachio

  公开号：US20090069599A1

  公开（公告）日：2009-03-12

  Disclosed are, for example, a process for producing a tricarboxylic acid tris(alkyl-substituted cyclohexylamide), the process comprising subjecting a tricarboxylic acid and an alkyl-substituted cyclohexylamine to an amidation reaction, either (a) in the presence of a boric acid compound and a phenol compound or (b) in the presence of a boric acid ester obtained by the dehydration condensation of a boric acid compound and a phenol compound, and optionally purifying the resulting crude reaction product.

  例如，本发明公开了一种生产三羧酸三（烷基取代的环己基）酰胺的方法，该方法包括将三羧酸和烷基取代的环己基胺置于酰胺反应中，（a）在硼酸化合物和酚化合物的存在下或（b）在通过脱水缩合一种硼酸化合物和一种酚化合物所得的硼酸酯的存在下进行反应，并可选择性地纯化所得的粗反应产物。
• Film having a good adhesive property and process for producing it
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP1092745A1

  公开（公告）日：2001-04-18

  A film having a good adhesive property comprises a base film and a coated layer formed on at least one surface of the base film. The coated layer has carboxylic acid and primary groups such that, at a surface thereof, the concentration of the carboxylic acid groups is not less than 0.005 and the concentration of the primary amine groups is not less than 0.0015.

  一种具有良好粘合性能的薄膜包括基膜和形成在基膜至少一个表面上的涂层。涂布层具有羧酸和伯胺基团，在其表面，羧酸基团的浓度不低于 0.005，伯胺基团的浓度不低于 0.0015。
• PROCESS FOR PRODUCING TRICARBOXYLIC ACID TRIS(ALKYL-SUBSTITUTED CYCLOHEXYLAMIDE)
  申请人：NEW JAPAN CHEMICAL CO.,LTD.

  公开号：EP1867630A1

  公开（公告）日：2007-12-19

  Disclosed are, for example, a process for producing a tricarboxylic acid tris(alkyl-substituted cyclohexylamide), the process comprising subjecting a tricarboxylic acid and an alkyl-substituted cyclohexylamine to an amidation reaction, either (a) in the presence of a boric acid compound and a phenol compound or (b) in the presence of a boric acid ester obtained by the dehydration condensation of a boric acid compound and a phenol compound, and optionally purifying the resulting crude reaction product.

  例如，公开了一种生产三羧酸三(烷基取代的环己胺)的工艺，该工艺包括将三羧酸和烷基取代的环己胺进行酰胺化反应、(a)在硼酸化合物和苯酚化合物存在的情况下，或(b)在硼酸化合物和苯酚化合物脱水缩合得到的硼酸酯存在的情况下，进行酰胺化反应，并选择性地纯化得到的粗反应产物。
• US4101493A
  申请人：——

  公开号：US4101493A

  公开（公告）日：1978-07-18
• US7745661B2
  申请人：——

  公开号：US7745661B2

  公开（公告）日：2010-06-29