bis-(4-amino-3-methoxy-phenyl)-disulfide | 29811-61-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: bis-(4-amino-3-methoxy-phenyl)-disulfide
• 英文别名: 2,2'-Dimethoxy-4,4'-disulfandiyl-di-anilin；Bis-(4-amino-3-methoxy-phenyl)-disulfan；Bis-(4-amino-3-methoxy-phenyl)-disulfid；4.4'-Diamino-3.3'-dimethoxy-diphenyldisulfid；(4-((4-Amino-3-methoxyphenyl)dithio)-2-methoxyphenyl)amine；4-[(4-amino-3-methoxyphenyl)disulfanyl]-2-methoxyaniline
• CAS: 29811-61-8
• 化学式: C₁₄H₁₆N₂O₂S₂
• 分子量: 308.425
• InChiKey: FZOHAJVWFPMQRW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  121
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  光气 、 bis-(4-amino-3-methoxy-phenyl)-disulfide 生成 bis-(4-isocyanato-3-methoxy-phenyl)-disulfide
  参考文献：
  名称：

  Siefken, Justus Liebigs Annalen der Chemie, 1949, vol. 562, p. 75,1114

  摘要：

  DOI：
• 作为产物：
  描述：

  bis-(3-methoxy-4-nitro-phenyl)-disulfide 在 sodium sulfide 、 水 作用下， 生成 bis-(4-amino-3-methoxy-phenyl)-disulfide
  参考文献：
  名称：

  Hodgson; Handley, Journal of the Chemical Society, 1928, p. 626

  摘要：

  DOI：

文献信息

• RESIN DISPERSIONS HAVING UNIFORM PARTICLE DIAMETERS, RESIN PARTICLES AND PROCESSES FOR PRODUCING BOTH
  申请人：SANYO CHEMICAL INDUSTRIES, LTD.

  公开号：EP1283236A1

  公开（公告）日：2003-02-12

  The present invention provides a method of producing an aqueous dispersion which comprises    dispersing a resin (b) or a solvent solution thereof, or a precursor (b0) of said resin (b) or a solvent solution thereof in an aqueous dispersion of resin particles (A) composed of resin (a) and    causing the precursor (b0) to react in the case where the precursor (b0) or a solvent solution thereof is used, to prepare resin particles (B) composed of said resin (b) in said aqueous dispersion of resin particles (A) and    thereby give an aqueous dispersion (X1) of resin particles (C) having a structure such that the resin particle (A) adheres to the surface of the resin particle (B). Further, an aqueous dispersion (X2) of resin particles (B) can be produced by a method    which comprises cleaving the resin particle (A) and resin particle (B) from each other and    removing resin particles (A), or    which comprises dissolving resin particles (A). The present invention can make it possible to obtain resin particles of uniform particle diameter.

  本发明提供了一种生产水性分散体的方法，该方法包括 将树脂 (b) 或其溶剂溶液，或所述树脂 (b) 的前体 (b0) 或其溶剂溶液分散在由树脂 (a) 组成的树脂颗粒 (A) 的水分散液中，以及 在使用前体（b0）或其溶剂溶液的情况下，使前体（b0）发生反应，以制备在所述树脂颗粒（A）的水分散液中由所述树脂（b）组成的树脂颗粒（B），并由此得到水分散液。 从而得到树脂颗粒（C）的水分散液（X1），该树脂颗粒（C）具有使树脂颗粒（A）粘附在树脂颗粒（B）表面的结构。 此外，树脂颗粒（B）的水性分散液（X2）可通过以下方法制得 该方法包括将树脂颗粒（A）和树脂颗粒（B）相互分离并 去除树脂颗粒（A），或 包括溶解树脂颗粒（A）。 本发明可以获得粒径均匀的树脂颗粒。
• ADHESIVE FOR RESIN ROLL ASSEMBLY AND RESIN ROLL
  申请人：Sanyo Chemical Industries, Ltd.

  公开号：EP1293549A1

  公开（公告）日：2003-03-19

  An adhesive for resin roll assembly which is to be used in such a manner that the adhesive is injected into the space between a cylindrical object made of a resin and either a roll core or a fiber-reinforced underlayer formed by winding a fibrous material impregnated with a thermosetting resin on the outer periphery of a roll core and is then gradationally cured to unite the cylindrical object to the roll core or underlayer. It comprises an epoxy resin (a) and one or more amine compound curing agents (b) selected from the group consisting of aliphatic polyamines, alicyclic polyamines, heterocyclic polyamines, polyamide-polyamines having a number-average molecular weight of 800 or lower, polyether polyamines having a number-average molecular weight of 1,000 or lower, and cyanoethylated polyamines.

  一种用于树脂辊装配的粘合剂，其使用方式是将粘合剂注入由树脂制成的圆柱形物体与辊芯或通过在辊芯外围缠绕浸渍有热固性树脂的纤维材料而形成的纤维增强底层之间的空间，然后逐步固化，使圆柱形物体与辊芯或底层结合在一起。它包括环氧树脂（a）和一种或多种胺化合物固化剂（b），这些胺化合物固化剂选自脂肪族多胺、脂环族多胺、杂环族多胺、平均分子量为 800 或更低的多胺、平均分子量为 1 000 或更低的聚醚多胺和氰乙基化多胺。
• POLISHING LIQUID FOR CMP PROCESS AND POLISHING METHOD
  申请人：SANYO CHEMICAL INDUSTRIES LTD.

  公开号：EP1628334A1

  公开（公告）日：2006-02-22

  An abrasive liquid for CMP process characterized by comprising an abrasive material, an aqueous solvent and an addition agent, and containing abrasive particles having a particle diameter of 20 to 80 nm by 15 weight % or more on the basis of the weight of the abrasive liquid; and a method of polishing by using the abrasive liquid are appropriate for the processing of flattening the surface of a device wafer on which at least a silicon oxide film is formed, and take effect of being capable of stably performing superior abrasive properties such as flattening properties, low flaw properties and high washing properties, and then are the most appropriate for the processing of flattening the surface of a semiconductor device comprising a layer insulation film or an element separation film, a magnetic head and a substrate for a liquid crystal display in the semiconductor industry.

  一种用于CMP工艺的研磨液，其特征在于由研磨材料、水性溶剂和添加剂组成，并含有颗粒直径为20至80纳米的研磨颗粒，其重量占研磨液重量的15%或以上；以及使用该研磨液进行抛光的方法，适用于至少形成了氧化硅薄膜的器件晶片表面的平整处理，并能稳定地发挥优异的研磨性能，如平整性能、低缺陷性能和高清洗性能，因此最适用于半导体工业中包括层绝缘膜或元件分离膜、磁头和液晶显示器基板的半导体器件表面的平整处理。
• RESIN DISPERSION AND RESIN PARTICLE
  申请人：Sanyo Chemical Industries, Ltd.

  公开号：EP1710271A1

  公开（公告）日：2006-10-11

  Disclosed are core-shell resin particles (C2) each comprising one or more film-like shell layers (P) comprising a resin (a) which is a polyurethane resin and a core layer (Q) comprising a resin (b). A core-shell resin particle (C2) is characterized in that the weight ratio between (P) and (Q) is from 0.1:99.9 to 70:30, the volatile content in the resin particle (C2) is not more than 2 weight %, and the content of vinyl resins in the resin (b) is not more than 30 weight %. Such resin particles have a uniform particle diameter and are excellent in electrostatic properties, thermal and storage stability and thermal characteristics.

  本发明公开了芯壳树脂颗粒（C2），每个芯壳树脂颗粒（C2）包括一个或多个由聚氨酯树脂（a）组成的薄膜状壳层（P）和由树脂（b）组成的芯层（Q）。芯壳树脂颗粒（C2）的特点是：（P）和（Q）的重量比从 0.1:99.9 到 70:30，树脂颗粒（C2）中的挥发物含量不超过 2 重量%，树脂（b）中的乙烯基树脂含量不超过 30 重量%。这种树脂颗粒的粒径均匀，静电性能、热稳定性、储存稳定性和热特性都很好。
• RESIN PARTICLE AND RESIN DISPERSION
  申请人：Sanyo Chemical Industries, Ltd.

  公开号：EP1887027A1

  公开（公告）日：2008-02-13

  Resin particles which are excellent in electrostatic property, thermal storage stability and thermal properties, and have evenness of particle diameter are to be provided. The resin particles are core-shell resin particles (C2) each comprising one or more film-like shell layers (P) comprising a first resin (a) and a core layer (Q) comprising a second resin (b). Core-shell type resin particles (C2) each comprising a film-like shell layer (P) in one or more layer structure comprising a first resin (a) and a core layer (Q) in one layer structure comprising a second resin (b), wherein the weight ratio of (P) and (Q) is in a range of (0.1:99.9) to (70:30), the content of volatile components of (C2) is 2% by weight or lower, and (a) has an initial softening temperature of 40 to 270°C, a glass transition temperature of 20 to 250°C, a flow temperature of 60 to 300°C, and the difference of the glass transition temperature and the flow temperature in a range of 0 to 120°C and contains 20 to 80% by weight of vinyl acetate as constituent units.

  需要提供在静电特性、热储存稳定性和热特性方面都非常出色且颗粒直径均匀的树脂颗粒。这种树脂颗粒是芯壳型树脂颗粒（C2），每个芯壳型树脂颗粒由一个或多个由第一种树脂（a）构成的膜状外壳层（P）和由第二种树脂（b）构成的芯层（Q）组成。芯壳型树脂颗粒（C2）各自包括一个或多个由第一树脂（a）组成的层结构中的膜状外壳层（P）和一个由第二树脂（b）组成的层结构中的芯层（Q），其中（P）和（Q）的重量比范围为（0.1:99.9）至（70:30）的范围内，(C2)中挥发性成分的含量为 2%（重量比）或更低，(a)的初始软化温度为 40 至 270°C，玻璃化转变温度为 20 至 250°C，流动温度为 60 至 300°C，玻璃化转变温度与流动温度之差为 0 至 120°C，且含有 20 至 80%（重量比）的醋酸乙烯酯作为组成单元。