[1,3-C6H4(OPPh2AuSC6H5)2] | 279214-83-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [1,3-C6H4(OPPh2AuSC6H5)2]
• 英文别名: benzenethiolate;(3-diphenylphosphanyloxyphenoxy)-diphenylphosphane;gold(1+)
• CAS: 279214-83-4
• 化学式: C₄₂H₃₄Au₂O₂P₂S₂
• 分子量: 1090.74
• InChiKey: YRPCHQYEPFNSIB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  11.02
• 重原子数：
  50.0
• 可旋转键数：
  14.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  18.46
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  [1,3-C6H4(OPPh2AuSC6H5)2] 、 水 以 丙酮 为溶剂， 生成 [(Au2(μ-SPh)(PPh2O)(PPh2OH))2]
  参考文献：
  名称：

  Self-Association in Gold Chemistry:  A Tetragold(I) Complex Linked by Both Aurophilic and Hydrogen Bonding

  摘要：

  Hydrolysis of the complex [1,3-C6H4(OPPh2AuSPh)(2)] gives the emissive, neutral tetragold(I) complex [{Au-2(mu-SPh)(PPh2O)(PPh2OH)}(2)], which is associated through pairs of gold ... gold interactions and P-O-H ... O-P hydrogen bonds.

  DOI：

  10.1021/ic991497k
• 作为产物：
  描述：

  resorcinolbis(diphenyl)phosphinite 在 triethyl amine 作用下， 以 四氢呋喃 为溶剂， 生成 [1,3-C6H4(OPPh2AuSC6H5)2]
  参考文献：
  名称：

  Self-Association in Gold Chemistry:  A Tetragold(I) Complex Linked by Both Aurophilic and Hydrogen Bonding

  摘要：

  Hydrolysis of the complex [1,3-C6H4(OPPh2AuSPh)(2)] gives the emissive, neutral tetragold(I) complex [{Au-2(mu-SPh)(PPh2O)(PPh2OH)}(2)], which is associated through pairs of gold ... gold interactions and P-O-H ... O-P hydrogen bonds.

  DOI：

  10.1021/ic991497k