N-methyl-2-(1-adamantyl)benzimidazole | 57278-12-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: N-methyl-2-(1-adamantyl)benzimidazole
• 英文别名: 2-adamantan-1-yl-1-methyl-1H-benzoimidazole；1-Methyl-2-<1'-adamantyl>-benzimidazol；2-(1-Adamantyl)-1-methylbenzimidazole
• CAS: 57278-12-3
• 化学式: C₁₈H₂₂N₂
• 分子量: 266.386
• InChiKey: VKISKMKITQCLRT-UHFFFAOYSA-N

物化性质

• 沸点：
  437.4±14.0 °C(Predicted)
• 密度：
  1.33±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  20
• 可旋转键数：
  1
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.61
• 拓扑面积：
  17.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1-金刚烷甲酸 在 ammonium peroxydisulfate 、 硫酸 、 silver nitrate 作用下， 以 甲醇 、 水 、 乙腈 为溶剂， 反应 4.0h， 生成 N-methyl-2-(1-adamantyl)benzimidazole
  参考文献：
  名称：

  Pellicciari; Fioretti; Cogolli, Arzneimittel-Forschung/Drug Research, 1980, vol. 30, # 12, p. 2103 - 2105

  摘要：

  DOI：

文献信息

• POLYMER, RESIST COMPOSITION, AND PATTERN FORMING PROCESS
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：US20160229940A1

  公开（公告）日：2016-08-11

  A polymer comprising recurring units having an acid generator bound to the backbone, and recurring units having an optionally acid labile group-substituted carboxyl group and/or recurring units having an optionally acid labile group-substituted hydroxyl group is obtained by polymerizing corresponding monomers in a solution of a non-polymerizable compound containing a nitrogen atom to which an acid labile group is bound. This prevents deprotection reaction of the acid labile group in the case of positive resist-forming polymer or crosslinking reaction in the case of negative resist-forming polymer.
• METHOD FOR PRODUCING POLYMER
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：US20170097567A1

  公开（公告）日：2017-04-06

  A polymer comprising recurring units having an acid generator bound to the backbone, and recurring units having an optionally acid labile group-substituted carboxyl group and/or recurring units having an optionally acid labile group-substituted hydroxyl group is obtained by polymerizing corresponding monomers in a solution of a non-polymerizable compound containing a nitrogen atom to which an acid labile group is bound. This prevents deprotection reaction of the acid labile group in the case of positive resist-forming polymer or crosslinking reaction in the case of negative resist-forming polymer.
• Pellicciari; Fioretti; Cogolli, Arzneimittel-Forschung/Drug Research, 1980, vol. 30, # 12, p. 2103 - 2105
  作者：Pellicciari、Fioretti、Cogolli、Tiecco

  DOI：——

  日期：——