[bis[N-tris(hydroxymethyl)methyl]-3-aminopropane sulfonato]diaquoneodymium(III) nitrate | 366804-91-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: [bis[N-tris(hydroxymethyl)methyl]-3-aminopropane sulfonato]diaquoneodymium(III) nitrate
• 英文别名: 3-[[1,3-dihydroxy-2-(hydroxymethyl)propan-2-yl]amino]propane-1-sulfonate;neodymium(3+);nitrate;dihydrate
• CAS: 366804-91-3
• 化学式: C₁₄H₃₆N₂NdO₁₄S₂*NO₃
• 分子量: 726.822
• InChiKey: NXLZTKAYRXUXCU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  neodymium(III) nitrate hexahydrate 、 三羟甲基甲胺基丙磺酸 以 水 为溶剂， 生成 [bis[N-tris(hydroxymethyl)methyl]-3-aminopropane sulfonato]diaquoneodymium(III) nitrate
  参考文献：
  名称：

  PHYSICO-CHEMICAL PROPERTIES OF Nd(III) AND Er(III) COMPLEXES WITH SOME BIOLOGICAL BUFFER LIGANDS

  摘要：

  The new Nd(III) and Er(III) complexes with the zwitterionic buffer ligands N-tris[hydroxymethyl]methyl-3-aminopropane-sulfonic acid sodium salt (NaTAPS) and 3-[N,N-bis(2-hydroxyethyl)amino]-2-hydroxypropanesulfonic acid sodium salt (NaDIPSO) have been prepared and characterized by IR, DTA, TG, mass, elemental analyses and electrical conductivity measurements. The Nd(III) complexes may be formulated as [Nd(DIPSO)(2)(H2O)(n)]NO3 . mH(2)O, where n = 1 and m = 1 for NaDIPSO as ligand while n = 2 and m = 0 for NaTAPS as ligand, [Nd(TAPS)(2)(H2O)(n)]NO3. The Er(III) complexes may be described as [Er(DIPSO)(2)(H2O)n]Cl . mH(2)O, where n = m = 2 for NaDIPSO as ligand while n = 2 and m = 0 for NaTAPS as ligand. Thermogravemetric studies show that the Er(III) complexes are thermally more stable than the Nd(III) complexes. The electrical conductivity of DMF solutions of these complexes indicate 1:1 electrolytic behavior.

  DOI：

  10.1081/sim-100104797