piperonal-piperonyloylhydrazone | 90754-81-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并间二氧杂环戊烯类
• 英文名称: piperonal-piperonyloylhydrazone
• 英文别名: Piperonal-piperonyloylhydrazon；N'-(Benzo[d][1,3]dioxol-5-ylmethylene)benzo[d][1,3]dioxole-5-carbohydrazide；N-[(E)-1,3-benzodioxol-5-ylmethylideneamino]-1,3-benzodioxole-5-carboxamide
• CAS: 90754-81-7
• 化学式: C₁₆H₁₂N₂O₅
• 分子量: 312.282
• InChiKey: ZLEXMGDSSQQDGN-REZTVBANSA-N

物化性质

• 溶解度：
  0.4 [ug/mL]

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  23
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  78.4
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  piperonal-piperonyloylhydrazone 在 溴 、 sodium acetate 作用下， 以 溶剂黄146 为溶剂， 以80%的产率得到2,5-bis-benzo[1,3]dioxol-5-yl-[1,3,4]oxadiazole
  参考文献：
  名称：

  Mazzone; Bonina; Puglisi, Farmaco, Edizione Scientifica, 1984, vol. 39, # 5, p. 414 - 420

  摘要：

  DOI：
• 作为产物：
  描述：

  胡椒醛 、 3,4-亚甲基二氧苄肼 以 1,4-二氧六环 为溶剂， 反应 0.5h， 以74%的产率得到piperonal-piperonyloylhydrazone
  参考文献：
  名称：

  Mazzone; Bonina; Puglisi, Farmaco, Edizione Scientifica, 1984, vol. 39, # 5, p. 414 - 420

  摘要：

  DOI：

文献信息

• USE OF METAL HYDRAZIDE COMPLEX COMPOUNDS AS OXIDATION CATALYSTS
  申请人：BASF SE

  公开号：EP3524347A1

  公开（公告）日：2019-08-14

  The present invention relates to the use of selected metal complex compounds as oxidation catalysts as well as to a process for removing stains and soil on textiles and hard surfaces. The metal complex compounds have hydrazide ligands, preferably with electron withdrawing groups in the phenyl ring adjacent to the acyl group. Further aspects of the invention are formulations comprising such metal complex compounds, novel metal complex compounds and novel ligands.

  本发明涉及使用选定的金属络合物作为氧化催化剂，以及去除纺织品和硬表面污渍和污垢的工艺。金属络合物具有酰肼配体，最好是在邻近酰基的苯基环上具有取电子基团。本发明的其他方面是包含此类金属络合物、新型金属络合物和新型配体的制剂。
• The So-Called “Anthraquinonediimines”; Symmetrical Trisubstituted Triazines
  作者：C. V. Wilson

  DOI：10.1021/ja01185a072

  日期：1948.5
• 763. Phthalazines. Part I. Re-investigation of the preparation of phthalazines by cyclodehydration of acylhydrazones
  作者：H. J. Rodda、P. E. Rogasch

  DOI：10.1039/jr9560003927

  日期：——
• MAZZONE, G.;BONINE, F.;PUGLISI, G.;PANICO, A. M.;ARRIGO, REINA, R., FARMACO. ED. SCI., 1984, 39, N 5, 414-420
  作者：MAZZONE, G.、BONINE, F.、PUGLISI, G.、PANICO, A. M.、ARRIGO, REINA, R.

  DOI：——

  日期：——
• Use of Metal Hydrazide Complex Compounds as Oxidation Catalysts
  申请人：BASF SE

  公开号：US20130281353A1

  公开（公告）日：2013-10-24

  The present invention relates to the use of selected metal complex compounds and ligands as oxidation catalysts as well as to a process for removing stains and soil on textiles and hard surfaces. The metal complex compounds have hydrazide ligands, preferably with electron withdrawing groups in the phenyl ring adjacent to the acyl group. Further aspects of the invention are formulations comprising such metal complex compounds, novel metal complex compounds and novel ligands.