1-bromo-3,5,7-triphenyladamantane | 1007117-93-2

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: 1-bromo-3,5,7-triphenyladamantane
• 英文别名: 1,3,5-triphenyl-7-bromoadamantane
• CAS: 1007117-93-2
• 化学式: C₂₈H₂₇Br
• 分子量: 443.426
• InChiKey: KHZOVSGBTYMFOF-UHFFFAOYSA-N

物化性质

• 沸点：
  531.2±50.0 °C(Predicted)
• 密度：
  1.362±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.2
• 重原子数：
  29
• 可旋转键数：
  3
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-bromo-3,5,7-triphenyladamantane 、 乙腈 在 硫酸 作用下， 反应 24.0h， 以80%的产率得到1,3,5-triphenyl-7-acetylaminoadamantane
  参考文献：
  名称：

  HYDRAmers: design, synthesis and characterization of different generation novel Hydra-like dendrons based on multifunctionalized adamantane

  摘要：

  在本次交流中，我们提出了一种新的合成策略，以四官能化金刚烷为基础，合成不同代的Hydra样树枝。这种新型树突，我们称之为“HYDRAMers”，在外围和中心核心具有正交保护，可用于缀合靶向配体、药物和/或成像探针。

  DOI：

  10.1039/c1cc11689d
• 作为产物：
  描述：

  trimethyl adamantane-1,3,5-tricarboxylate 在 lithium aluminium tetrahydride 作用下， 以71%的产率得到1-bromo-3,5,7-triphenyladamantane
  参考文献：
  名称：

  [EN] COMPOUNDS AND METHODS FOR MODULATING RNA FUNCTION
  [FR] COMPOSÉS ET MÉTHODES PERMETTANT DE MODULER LA FONCTION DE L'ARN

  摘要：

  公开号：

  WO2018006074A3

文献信息

• ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：UDC Ireland Limited

  公开号：EP2113548B1

  公开（公告）日：2016-05-25
• Organic electroluminescence element
  申请人：Sotoyama Wataru

  公开号：US20090218935A1

  公开（公告）日：2009-09-03

  An organic electroluminescence element having at least one organic compound layer including a light-emitting layer, which is disposed between a pair of electrodes, wherein the light-emitting layer includes a light emitting material, a compound represented by the following formula (1) and a charge transporting material. An organic EL element that exhibits high light-emission efficiency and low driving voltage, and is excellent in drive durability is provided.
• ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：KINOSHITA Ikuo

  公开号：US20100171418A1

  公开（公告）日：2010-07-08

  An organic electroluminescent device is provided and includes: a pair of electrodes; an organic layer including a light emitting layer between the electrodes. The organic layer contains a compound represented by formula (I). In formula (I), R 11 , R 12 , and R 13 each independently represents a C 1-6 alkyl group, Q 1 represents a carbon atom or a silicon atom, R 14 represents a hydrogen atom or -Q 2 (R 16 )(R 17 )R 18 in which Q 2 represents a carbon atom or a silicon atom and R 16 , R 17 , and R 18 each independently represents a C 1-6 alkyl group, R 15 represents a hydrogen atom, a substituted or unsubstituted alkyl group, a cyano group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heteroaryl group, and n stands for 1 or 2.
• CHARGE TRANSPORT MATERIAL AND ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：KITAMURA Tetsu

  公开号：US20100171417A1

  公开（公告）日：2010-07-08

  Provided is a charge transport material represented by the following general formula (1) or (2). In the foregoing general formulae, each of L 1 and L 2 independently represents a connecting group; each of R and R N independently represents a substituent; each of R 1 and R 2 independently represents a substituent, provided that R 1 and R 2 do not represent an aryl group at the same time; each A independently represents a carbon atom or a nitrogen atom; n represents an integer of 2 or more and not more than 10; and each m independently represents an integer.
• MATERIAL FOR ORGANIC ELECTROLUMINESCENCE DEVICE AND ELECTROLUMINESCENCE DEVICE
  申请人：TAKADA Saki

  公开号：US20110050092A1

  公开（公告）日：2011-03-03

  Provided is a material for organic electroluminescence device containing (a) a phosphorescent metal complex containing a monoanionic bidentate ligand and a metal having an atomic weight of 40 or greater, wherein the monoanionic bidentate ligand is represented by the following formula (A): wherein, each of E 1a , E 1d , E 1e , E 1f , E 1k , E 1l , E 1p , and E 1q independently represents a carbon atom or a hetero atom, each of Z 1 , Z 2 , and Z 3 independently represents an aromatic ring or aromatic heterocycle, the aromatic ring or aromatic heterocycle may have a substituent, and a skeleton represented by the formula (A) has, in total, a 18π electron structure, and the bidentate ligand represented by the formula (A) may be coupled to another ligand to form a tridentate or higher-dentate ligand; and (b) a structural isomer represented by the same chemical formula as that of the phosphorescent metal complex (a) but different sterically in a coordination method of the ligand, wherein the structural isomer (b) is contained in an amount of 0.05 mass % or greater but not greater than 5 mass % relative to the phosphorescent metal complex (a).