1,4,5-triacetoxy-9,10-anthraquinone | 75314-06-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1,4,5-triacetoxy-9,10-anthraquinone
• 英文别名: 1,4,5-triacetoxy-anthraquinone；1,4,5-Triacetoxy-anthrachinon；9,10-Dioxo-9,10-dihydroanthracene-1,4,5-triyl triacetate；(4,5-diacetyloxy-9,10-dioxoanthracen-1-yl) acetate
• CAS: 75314-06-6
• 化学式: C₂₀H₁₄O₈
• 分子量: 382.326
• InChiKey: SRKUTLVNIVHQBV-UHFFFAOYSA-N

物化性质

• 熔点：
  225 °C
• 沸点：
  581.5±50.0 °C(Predicted)
• 密度：
  1.405±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  28
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  113
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  1,4,5-triacetoxy-9,10-anthraquinone 生成 1,4,5,9,10-pentaacetoxy-anthracene
  参考文献：
  名称：

  Brockmann; Budde, Chemische Berichte, 1953, vol. 86, p. 432,441

  摘要：

  DOI：
• 作为产物：
  描述：

  5,8-diacetoxy-1,4-naphthoquinone 在 硫酸 、 lead dioxide 作用下， 以 乙腈 为溶剂， 反应 21.17h， 生成 1,4,5-triacetoxy-9,10-anthraquinone
  参考文献：
  名称：

  Polycyclic hydroxyquinones. 13. A novel synthesis of islandicin and digitopurpone

  摘要：

  DOI：

  10.1021/jo00174a047

文献信息

• Harrison, Charles R.; Hodge, Philip; Khan, Naeem, Journal of the Chemical Society. Perkin transactions I, 1980, p. 1592 - 1594
  作者：Harrison, Charles R.、Hodge, Philip、Khan, Naeem

  DOI：——

  日期：——
• Platinum-group elements for the Kudi ophiolite, western Kunlun
  作者：Zhihong Wang、Quanlin Hou、Jiliang Li、Haihong Chen

  DOI：10.1007/bf02887105

  日期：2000.3

  The analyses of PGE characteristics for the Kudi ophiolite, western Kunlun, are reported in this note. The Ir-depleted anomalous ancient upper mantle represented by the Kudi mantle peridotites had been percolated and mixed by remelted oceanic crust material from a supra-subduction zone, leaving the rocks relatively enriched in Pd. The PGE contents in the Kudi cumulate pyroxenites and gabbros vary from 2.4 to 23.94 ng/g, and the highest values are in pyroxenites. The Pd/Ir ratios increase from the pyroxenites to the gabbros. The PGE patterns for the Kudi cumulate rocks are steeply positively sloped. The Pd enrichment in these rocks is similar to that in pyroxenites from the Thetford ophiolite and the Troodos ophiolite. The Kudi diabase and basalts have low PGE contents and positively sloped PGE patterns, and are comparable with the upper pillow lavas from the Troodos ophiolite, indicative of the environment of back-are spreading center in a supra-subduction zone.
• FARINA, F.;PRIMO, J., AN. QUIM. PUBL. REAL SOC. ESP. FIS. Y QUIM., 1980, 76, N 3, 249-254
  作者：FARINA, F.、PRIMO, J.

  DOI：——

  日期：——
• Brockmann; Budde, Chemische Berichte, 1953, vol. 86, p. 432,441
  作者：Brockmann、Budde

  DOI：——

  日期：——
• Polycyclic hydroxyquinones. 13. A novel synthesis of islandicin and digitopurpone
  作者：Pilar Cano、Antonio Echavarren、Pilar Prados、Francisco Farina

  DOI：10.1021/jo00174a047

  日期：1983.12