1-Methyl-3-Phenyl-6,6-Dimethylfulvene | 138863-08-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-Methyl-3-Phenyl-6,6-Dimethylfulvene
• 英文别名: (4-methyl-3-propan-2-ylidenecyclopenta-1,4-dien-1-yl)benzene
• CAS: 138863-08-8
• 化学式: C₁₅H₁₆
• 分子量: 196.292
• InChiKey: SBIRCXUZWUAURB-UHFFFAOYSA-N

物化性质

• 沸点：
  303.2±9.0 °C(Predicted)
• 密度：
  0.994±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  四氢呋喃 、 1-Methyl-3-Phenyl-6,6-Dimethylfulvene 在 magnesium 作用下， 以 四氯化碳 为溶剂， 以15%的产率得到
  参考文献：
  名称：

  ansa-Metallocene derivatives

  摘要：

  Titanocene and zirconocene complexes with a phenyl or 1-naphthyl substituent in one beta-position of each C5-ring ligand and with an interannular tetramethylethano- or dimethylsilano-bridge have been prepared. Racemic complex isomers, which are formed together with varying amounts of their meso isomers, were separated from the latter and characterised by H-1 NMR spectroscopy and X-ray crystallographic studies.

  DOI：

  10.1016/0022-328x(91)80157-f
• 作为产物：
  描述：

  3-甲基-2-环戊烯-1-酮 在 四氢吡咯 作用下， 以 乙醚 为溶剂， 160.0 ℃ 、1.33 kPa 条件下， 反应 5.0h， 生成 1-Methyl-3-Phenyl-6,6-Dimethylfulvene
  参考文献：
  名称：

  ansa-Metallocene derivatives

  摘要：

  Titanocene and zirconocene complexes with a phenyl or 1-naphthyl substituent in one beta-position of each C5-ring ligand and with an interannular tetramethylethano- or dimethylsilano-bridge have been prepared. Racemic complex isomers, which are formed together with varying amounts of their meso isomers, were separated from the latter and characterised by H-1 NMR spectroscopy and X-ray crystallographic studies.

  DOI：

  10.1016/0022-328x(91)80157-f

文献信息

• Process for the preparation of ethylene polymers
  申请人：——

  公开号：US20020198339A1

  公开（公告）日：2002-12-26

  Ethylene based polymers having high molecular weights can be obtained in high yields at temperatures of industrial interest, by carrying out the polymerization reaction in the presence of catalysts comprising single carbon bridged metallocenes, which has a particular ligand system containing a heteroatom.

  具有高分子量的乙烯基聚合物可以在工业温度下，在单碳桥联的金属茂络合物催化剂的存在下进行聚合反应，该催化剂具有特定的配体系统，其中包含一个杂原子，从而可以高产得到。
• ansa-Metallocene derivatives
  作者：Peter Burger、Kai Hortmann、Josef Diebold、Hans-Herbert Brintzinger

  DOI：10.1016/0022-328x(91)80157-f

  日期：1991.10

  Titanocene and zirconocene complexes with a phenyl or 1-naphthyl substituent in one beta-position of each C5-ring ligand and with an interannular tetramethylethano- or dimethylsilano-bridge have been prepared. Racemic complex isomers, which are formed together with varying amounts of their meso isomers, were separated from the latter and characterised by H-1 NMR spectroscopy and X-ray crystallographic studies.