cyclohexane-1,3,5-trithiol | 25276-86-2

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醇
• 英文名称: cyclohexane-1,3,5-trithiol
• CAS: 25276-86-2
• 化学式: C₆H₁₂S₃
• 分子量: 180.359
• InChiKey: AYJBSWRPWFFDAI-UHFFFAOYSA-N

物化性质

• 沸点：
  281.2±40.0 °C(Predicted)
• 密度：
  1.16±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3
• 氢给体数：
  3
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  乙烯亚胺 、 cyclohexane-1,3,5-trithiol 反应 2.0h， 以5.0 g的产率得到2,2',2''-<(cyclohexane-1,3,5-triyl)trithio>tris(ethanamine)
  参考文献：
  名称：

  Gahan, Lawrence R.; Sargeson, Alan M., Australian Journal of Chemistry, 1981, vol. 34, # 12, p. 2499 - 2504

  摘要：

  DOI：

文献信息

• Novel crystalline metal-organic microporous materials
  申请人：NALCO CHEMICAL COMPANY

  公开号：EP0790253A2

  公开（公告）日：1997-08-20

  Novel metal-organic microporous materials are prepared in solution using mild reaction conditions from a metal or metalloid ion with a ligand containing multidentate functional groups in the presence of a templating agent. The resultant microporous materials are useful in the purification of liquids and gases.

  新型金属有机微孔材料是在温和的反应条件下，由金属或类金 属离子与含有多叉官能团的配体在模板剂的存在下在溶液中制备而成。制备出的微孔材料可用于液体和气体的净化。
• APPARATUS AND METHOD FOR PRODUCING RESIN
  申请人：TEIJIN LIMITED

  公开号：EP1120435A1

  公开（公告）日：2001-08-01

  A method of producing a polycarbonate or the like which is excellent in hydrolysis and heat stability such as a reduction in molecular weight at the time of molding and color retention and moldability such as releasability and transferability, rarely experiences residence deterioration such as coloring, crosslinking and gel formation and has an extremely small content of foreign matter by employing a special structure for an opening in the side surface of a horizontal cylindrical vacuum resin treating apparatus, supplying a molten polycarbonate into a unidirectional rotary intermeshing double-screw extruder under specific conditions, adding a specific agent under specific conditions and cleaning the inner surface of a production apparatus by a specific method.

  一种聚碳酸酯或类似物的生产方法，该聚碳酸酯或类似物具有优异的水解稳定性和热稳定性（如成型时分子量降低）以及保色性和成型性（如脱模性和转移性），很少发生着色等居住劣化、通过在卧式圆柱形真空树脂处理装置的侧表面开口处采用特殊结构，在特定条件下将熔融聚碳酸酯送入单向旋转啮合双螺杆挤出机，在特定条件下添加特定药剂，并通过特定方法清洁生产装置的内表面，可生产出异物含量极低的聚碳酸酯。
• POLYCARBONATE, PROCESS FOR PRODUCING THE SAME, AND MOLDED ARTICLE THEREOF
  申请人：TEIJIN LIMITED

  公开号：EP1191049A1

  公开（公告）日：2002-03-27

  A polycarbonate which is stable against thermal decomposition at a temperature range for melt molding without adding a heat resistant stabilizer and suitable for the melt molding of a thin product, production method and molded products thereof. The polycarbonate is comprising mainly a recurring unit represented by the following formula (1), and has a percentage of the total of integrated intensities of all signals detected at four ranges, δ = 2.14 to 2.17 ppm, δ = 3.46 to 3.49 ppm, δ = 3.62 to 3.69 ppm and δ = 5.42 to 5.46 ppm to the integrated intensity of a signal derived from a methyl group detected at a range of δ = 1.50 to 2.00 ppm of 0.01 to 2.0 % in its 1H-NMR spectrum in heavy chloroform and a viscosity average molecular weight of 10,000 to 100,000.

  一种聚碳酸酯，在熔融成型温度范围内对热分解稳定，无需添加耐热稳定剂，适合熔融成型薄型产品，及其生产方法和成型产品。这种聚碳酸酯主要由下式（1）所代表的递归单元组成、 并在δ＝2.14 至 2.17 ppm、δ＝3.46 至 3.49 ppm、δ＝3.62 至 3.69 ppm 和δ＝5.42 至 5.46 ppm 四个范围内检测到的所有信号的综合强度总和的百分比。在重氯仿中的 1H-NMR 光谱中，在 δ = 1.50 至 2.00 ppm 范围内检测到的来自甲基的信号的综合强度为 0.01 至 2.0%，粘度平均分子量为 10,000 至 100,000。
• ELECTRET AND ELECTROSTATIC INDUCTION CONVERSION DEVICE
  申请人：Asahi Glass Company Limited

  公开号：EP2330159A1

  公开（公告）日：2011-06-08

  To provide an electret having high stability with time and thermal stability of retained electric charge and having excellent charge retention performance, and an electrostatic induction conversion device comprising such an electret. An electret obtained from a composition comprising a compound (A) having a molecular weight of from 50 to 2000 and having at least two polar functional groups, and a polymer (B) having a number average molecular weight of more than 2000 and having reactive functional groups reactive with the above polar functional groups. An electrostatic induction conversion device comprising such an electret.

  提供一种驻极体，该驻极体具有较高的时间稳定性和保留电荷的热稳定性，并具有优异的电荷保留性能，以及一种包含这种驻极体的静电感应转换装置。 一种由化合物（A）和聚合物（B）组成的驻极体，化合物（A）的分子量在 50 到 2000 之间，并具有至少两个极性官能团，聚合物（B）的平均分子量大于 2000，并具有与上述极性官能团反应的活性官能团。一种静电感应转换装置，包括上述驻极体。
• Cureable formulations for forming low-k dielectric silicon-containing films using polycarbosilazane
  申请人：L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude

  公开号：US11499014B2

  公开（公告）日：2022-11-15

  Disclosed are silicon and carbon containing film forming compositions comprising a polycarbosilazane polymer or oligomer formulation that consists of silazane-bridged carbosilane monomers, the carbosilane containing at least two —SiH2— moieties, either as terminal groups (—SiH3R) or embedded in a carbosilane cyclic compound, wherein R is H, a C1-C6 linear, branched, or cyclic alkyl- group, a C1-C6 linear, branched, or cyclic alkenyl- group, or combination thereof. Also disclosed are methods of forming a silicon and carbon containing film comprising forming a solution comprising a polycarbosilazane polymer or oligomer formulation and contacting the solution with the substrate via a spin-on coating, spray coating, dip coating, or slit coating technique to form the silicon and carbon containing film.

  本发明公开了含硅和碳的成膜组合物，该组合物包含聚碳硅氮烷聚合物或低聚物配方，该配方由硅氮烷桥接的碳硅烷单体组成，碳硅烷包含至少两个-SiH2-分子，可作为末端基团（-SiH3R）或嵌入碳硅烷环状化合物中，其中R为H、C1-C6直链、支链或环状烷基、C1-C6直链、支链或环状烯基或其组合。还公开了形成含硅和碳薄膜的方法，包括形成包含聚碳硅烷聚合物或低聚物配方的溶液，并通过旋涂、喷涂、浸涂或缝涂技术将溶液与基底接触，以形成含硅和碳的薄膜。