9-[3-[3-(3-Triphenylen-2-ylphenyl)phenyl]phenyl]carbazole

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 9-[3-[3-(3-Triphenylen-2-ylphenyl)phenyl]phenyl]carbazole
• 英文别名: 9-[3-[3-(3-triphenylen-2-ylphenyl)phenyl]phenyl]carbazole
• 化学式: C₄₈H₃₁N
• 分子量: 621.781
• InChiKey: OIUGFADTSVVLOM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.8
• 重原子数：
  49
• 可旋转键数：
  4
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  9-(3'-bromo-[1,1'-biphenyl]-3-yl)-9H-carbazole 、 3-(2-三亚苯基苯硼酸)频哪醇酯 在 四(三苯基膦)钯 、 potassium carbonate 作用下， 以 水 、 甲苯 为溶剂， 以48%的产率得到9-[3-[3-(3-Triphenylen-2-ylphenyl)phenyl]phenyl]carbazole
  参考文献：
  名称：

  Organic electroluminescent materials and devices

  摘要：

  本文描述了一种按照公式I制备的化合物，包括该化合物的装置和配方。按照公式I制备的化合物可以具有以下结构：其中R1、R2、R3、R4、R5和R6分别代表单个、双个、三个、四个取代基或无取代基；R9代表单个、双个、三个取代基或无取代基；R1、R2、R3、R4、R5、R6和R9各自独立地选自氢、氘、卤素、烷基、环烷基、杂环烷基、芳基烷基、烷氧基、芳氧基、氨基、硅烷基、烯基、环烯基、杂环烯基、炔基、芳基、杂环芳基、酰基、羰基、羧酸、酯、腈、异腈、磺基、亚磺基、磺酰基、膦基及其组合。A1、A2、A3、A4、A5和A6各自独立地选自N或C，n为1到20的整数。

  公开号：

  US09419225B2

文献信息

• Organic electrolumiescent materials and devices
  申请人：Universal Display Corporation

  公开号：EP2866273A1

  公开（公告）日：2015-04-29

  A composition formed of a first mixture of a first compound and a second compound wherein the first compound has different chemical structure than the second compound; the first compound is capable of functioning as a hole transporting material in an organic light emitting device at room temperature; the first compound comprises at least one carbazole group; the first compound has a evaporation temperature T1 of 150 to 350 °C; the second compound has evaporation temperature T2 of 150 to 350 °C; the absolute value of T1-T2 is less than 20 °C; the first compound having a concentration C1 in said first mixture, and the first compound having a concentration C2 in a film formed by evaporating the first mixture in a vacuum deposition tool at a constant pressure between 1x10-6 Torr to 1x10-9 Torr, at a 2Å/sec deposition rate on a surface positioned at a predefined distance away from the mixture being evaporated; and wherein the absolute value of (C1-C2)/C1 is less than 5%.

  一种由第一种化合物和第二种化合物的第一种混合物形成的组合物，其中第一种化合物与第二种化合物具有不同的化学结构；第一种化合物能够在室温下在有机发光器件中用作空穴传输材料；第一种化合物包含至少一个咔唑基团；第一种化合物的蒸发温度T1为150至350 °C；第二种化合物的蒸发温度T2为150至350 °C；T1-T2的绝对值小于20 °C；第一化合物在所述第一混合物中的浓度为C1，而第一化合物在薄膜中的浓度为C2，该薄膜是在真空沉积工具中，在1x10-6托至1x10-9托的恒定压力下，以2埃/秒的沉积速率将第一混合物蒸发在与被蒸发的混合物保持预定距离的表面上形成的；其中(C1-C2)/C1的绝对值小于5%。
• Mixture, composition and organic electronic device
  申请人：GUANGZHOU CHINARAY OPTOELECTRONIC MATERIALS LTD.

  公开号：US10978642B2

  公开（公告）日：2021-04-13

  A mixture consists of three or more organic compounds, wherein the molecular weight difference of any two organic compounds is less than 160 Dalton. In the mixture, the molar percentage of each organic compound is not less than 3% and not more than 90%, and the organic compounds all have at least one same or similar photoelectronic function.

  混合物由三种或三种以上的有机化合物组成，其中任意两种有机化合物的分子量之差小于 160 道尔顿。在混合物中，每种有机化合物的摩尔百分比不小于 3%，也不大于 90%，并且所有有机化合物都具有至少一种相同或相似的光电子功能。
• ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES
  申请人：UNIVERSAL DISPLAY CORPORATION

  公开号：US20160315269A1

  公开（公告）日：2016-10-27

  A compound according to a formula I, devices incorporating the same, and formulations including the same are described. The compound according to the formula I can have the structure wherein R 1 , R 2 , R 3 , R 4 , R 5 and R 6 each represent mono, di, tri, tetra substitutions, or no substitution, R 9 represents mono, di, tri substitutions, or no substitution, R 1 , R 2 , R 3 , R 4 , R 5 , R 6 and R 9 are each independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acid, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof. A 1 , A 2 , A 3 , A 4 , A 5 , and A 6 are each independently selected from N or C, where at least one of A 1 to A 6 is N, and n is an integer from 1 to 20.
• ORGANIC MIXTURE, ORGANIC COMPOSITION, ORGANIC ELECTRONIC COMPONENT AND PREPARATION METHOD THEREFOR
  申请人：GUANGZHOU CHINARAY OPTOELECTRONIC MATERIALS LTD.

  公开号：US20190355911A1

  公开（公告）日：2019-11-21

  An organic mixture, an organic composition, an organic electronic component, and a preparation method therefor. The organic mixture comprises two organic compounds H1 and H2, the organic compound H1 being a spiro compound, the organic compound H1 being a compound comprising rich electrons, min((LUMO(H1)−HOMO(H2)), (LUMO(H2)−HOMO(H1)))≤min (ET(H1), ET(H2))+0.1 eV, the LUMO(H1), HOMO(H1) and ET(H1) respectively indicating a lowest unoccupied molecular orbital, a highest occupied molecular orbital and a triplet-state energy level of the organic compound H1, and the LUMO(H2), HOMO(H2) and ET(H2) respectively indicating a lowest unoccupied molecular orbital, a highest occupied molecular orbital and a triplet-state energy level of the organic compound H2.
• MIXTURE, COMPOSITION AND ORGANIC ELECTRONIC DEVICE
  申请人：GUANGZHOU CHINARAY OPTOELECTRONIC MATERIALS LTD.

  公开号：US20200098992A1

  公开（公告）日：2020-03-26

  A mixture consists of three or more organic compounds, wherein the molecular weight difference of any two organic compounds is less than 160 Dalton. In the mixture, the molar percentage of each organic compound is not less than 3% and not more than 90%, and the organic compounds all have at least one same or similar photoelectronic function.