octane-1,4,8-triol | 4253-26-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: octane-1,4,8-triol
• 英文别名: Octan-1,4,8-triol；(+/-)-Octantriol-(1,4,8)；Octantriol-(1,4,8)
• CAS: 4253-26-3
• 化学式: C₈H₁₈O₃
• 分子量: 162.229
• InChiKey: DLEKVZFIQQXZQZ-UHFFFAOYSA-N

物化性质

• 沸点：
  161-164 °C(Press: 0.5 Torr)
• 密度：
  1.056±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0
• 重原子数：
  11
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  60.7
• 氢给体数：
  3
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  (E)-[2,2']bifurylidene-5,5'-dione 在 1,4-二氧六环 、 钌 作用下， 200.0 ℃ 、19.61 MPa 条件下， 生成 octane-1,4,8-triol
  参考文献：
  名称：

  Bifurandione. III. Addition and Ring-opening Reactions

  摘要：

  DOI：

  10.1021/ja01523a048

文献信息

• Delayed co-initiation process for preparing polyol blends
  申请人：BASF Corporation

  公开号：EP0114072A2

  公开（公告）日：1984-07-25

  A delayed co-initiation process for preparing polyol blends comprising (a) epoxidizing a first initiator compound to obtain a polyol with a predetermined equivalent weight; and (b) adding a second initiator which may be the same as or different from the first and epoxidizing to obtain a polyol with a predetermined equivalent weight based upon the second initiator. The resultant polyols are used in the preparation of polyurethane foams.

  一种用于制备多元醇混合物的延迟共引发工艺，包括 (a) 环氧化第一种引发剂化合物，以获得具有预定当量重量的多元醇；以及 (b) 加入与第一种引发剂相同或不同的第二种引发剂，并进行环氧化，以第二种引发剂为基础得到具有预定当量重量的多元醇。 得到的多元醇可用于制备聚氨酯泡沫。
• Flexible polyurethane foams having high indentation load deflection prepared from polyol blends
  申请人：BASF WYANDOTTE CORPORATION

  公开号：EP0116309A1

  公开（公告）日：1984-08-22

  This invention relates to polyol blends which comprise specific polyoxyalkylene triols and specific polyoxyalkylene diols. It also relates to a process for preparing flexible polyurethane foams with the polyol blends, and the resultant foams prepared by the process. The flexible polyurethane foams are used as furniture cushioning, mattress cores, mattress toppers, carpet underlay, packaging, sponges, toys, athletic padding, and other uses.

  本发明涉及由特定聚氧亚烷基三醇和特定聚氧亚烷基二醇组成的多元醇混合物。本发明还涉及一种用多元醇混合物制备柔性聚氨酯泡沫塑料的工艺，以及用该工艺制备的泡沫塑料。 这种软质聚氨酯泡沫可用作家具衬垫、床垫芯、床垫顶垫、地毯衬垫、包装、海绵、玩具、运动衬垫及其它用途。
• TRANSFER SHEET
  申请人：Aicello Corporation

  公开号：EP3995306A1

  公开（公告）日：2022-05-11

  An object is to provide a transfer sheet offers a single-sheet solution for achieving both normal temperature transfer and thermal transfer when transferring a material having high adhesion to polyester or other material constituting the backing. A means for achieving the above is a transfer sheet which has a structure in which a polyester layer as a backing layer, a polyvinyl alcohol (PVA) layer, and a transfer layer, are stacked in this order, where the polyvinyl alcohol layer contains a diol compound and/or triol compound whose adjacent hydroxyl groups are positioned at δ or farther positions with respect to each other, and which satisfies the condition in (i) below: (i) the T-peel strength at a peel rate of 100 mm/min between the polyester layer and the polyvinyl alcohol layer before a transfer layer is formed but after the humidity has been adjusted in an environment of 23°C, 50% RH, is 30 mN/20 mm or greater.

  目的是提供一种转印纸，在转印与聚酯或其他构成背衬的材料具有高粘合力的材料时，提供一种既能实现常温转印又能实现热转印的单张纸解决方案。实现上述目的的一种方法是一种转印纸，其结构是依次堆叠作为底层的聚酯层、聚乙烯醇（PVA）层和转印层，其中聚乙烯醇层含有二元醇化合物和/或三元醇化合物，其相邻羟基彼此位于δ或更远的位置，并且满足以下(i)中的条件：(i) 在 23℃、50%相对湿度的环境中，聚酯层和聚乙烯醇层之间在形成转移层之前但在湿度调整之后，以 100 毫米/分钟的剥离速度进行剥离时，T-剥离强度为 30 毫牛顿/20 毫米或更大。
• Proximity Effects. IV. Reaction of Cycloöctene Dibromide with Silver Acetate¹
  作者：Arthur C. Cope、Geoffrey W. Wood

  DOI：10.1021/ja01571a070

  日期：1957.7
• Synthesis of Glycerol Homologues
  作者：Mark Trudell、Kiran Thota

  DOI：10.1055/s-0033-1339185

  日期：——

  A series of monoprotected glycerol homologues and triols were prepared in high overall yields (>90%) via the hydroboration-oxidation of the corresponding dienols. Hydroboration with disiamylborane and concomitant alkaline oxidation (NaOH, H2O2) was found to be a mild, high-yielding, and highly efficient method for the construction of a variety of glycerol homologues.