溶剂紫14 | 82-20-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 中文名称: 溶剂紫14
• 中文别名: 1,5-双[(4-甲基苯基)氨基]-9,10-蒽二酮；1,8-二[(4-甲基苯基)氨基]-蒽醌
• 英文名称: 1,5-bis(4-methylphenyl)aminoanthraquinone
• 英文别名: 1,5-di-p-toluidino-anthraquinone；1,5-Di-p-toluidino-anthrachinon；1.5-Bis-(p-methyl-phenylamino)-anthrachinon；1,5-Di-p-toluidinoanthraquinone；1,5-bis(4-methylanilino)anthracene-9,10-dione
• CAS: 82-20-2；8005-40-1
• 化学式: C₂₈H₂₂N₂O₂
• 分子量: 418.495
• InChiKey: ZKIVUFFTMWIBCO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.8
• 重原子数：
  32
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  58.2
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  溶剂紫14 在 硫酸 作用下， 生成 NSC 297168
  参考文献：
  名称：

  DE108274

  摘要：

  公开号：
• 作为产物：
  描述：

  1,5-二苯氧基蒽醌 、 乙烷,三氯氟- 生成 溶剂紫14
  参考文献：
  名称：

  DE165728

  摘要：

  公开号：

文献信息

• Process for preparing pigmented thermoplastic polymer compositions and
  申请人：Plasticolors, Inc.

  公开号：US05443775A1

  公开（公告）日：1995-08-22

  A process for preparing a pigmented thermoplastic polymer composition which is useful as a low profile additive composition for thermosetting resins comprises the steps of (A) selecting at least one thermoplastic polymer having a refractive index which is within about 0.06 units of the refractive index of the thermosetting resin; (B) preparing a mixture of said thermoplastic polymer and at least one color pigment, dye or mixture thereof under high shear in a high-intensity mixer; and (C) forming a slurry comprising said mixture obtained in step (B) in at least one liquid copolymerizable monomer containing at least one CH.sub.2 .dbd.C< group. In a preferred embodiment, at least one surfactant is included in the slurry obtained in step (C) in an amount sufficient to enhance the uniformity of the pigmentation of a cured composite produced from the thermosetting resin composition and a low profile additive composition. Additional pigment can be added to the slurry before the slurry is mixed with the thermosetting resin. The cured composites produced from the thermosetting resin composition and the low profile additive composition of the invention are characterized as having improved uniformity and intensity of color.

  一种用作热固性树脂低剖面添加剂组合物的有色热塑性聚合物组合物的制备方法，包括以下步骤：（A）选择至少一种具有与热固性树脂的折射率相差约0.06单位的折射率的热塑性聚合物；（B）在高强度混合器中高剪切下制备所述热塑性聚合物和至少一种颜色颜料、染料或其混合物的混合物；以及（C）在至少一种含有至少一种CH.sub.2.dbd.C<基团的液态共聚单体中形成含有步骤（B）中获得的所述混合物的浆料。在一种优选实施例中，在步骤（C）中获得的浆料中包含至少一种表面活性剂，其量足以提高从热固性树脂组合物和低剖面添加剂组合物制备的固化复合材料的着色均匀性。在将浆料与热固性树脂混合之前，还可以向浆料中添加额外的颜料。从该发明的热固性树脂组合物和低剖面添加剂组合物制备的固化复合材料的特点在于具有改善的颜色均匀性和强度。
• Method of preparing a cured pigmented thermosetting polymer composition
  申请人：Plasticolors, Inc.

  公开号：US05326516A1

  公开（公告）日：1994-07-05

  This invention relates to a process for preparing a pigmented thermoplastic polymer composition which is useful as a low profile additive composition for thermosetting resins. The process includes the steps of (A) selecting at least on thermoplastic polymer having a refractive index which is within about 0.06 units of the refractive index of the thermosetting resin; (B) preparing a mixture of said thermoplastic polymer and at least one color pigment, dye or mixture thereof under high shear in a high-intensity mixer; and (C) forming a slurry containing said mixture obtained in step (B) in at least one liquid copolymerizable monomer containing at least one CH.sub.2 .dbd.C<group. In a preferred embodiment, at least one surfactant is included in the slurry obtained in step (C) in an amount sufficient to enhance the uniformity of the pigmentation of a cured composite produced from the thermosetting resin composition and a low profile additive composition. Additional pigment can be added to the slurry before the slurry is mixed with the thermosetting resin. The cured composites produced from the thermosetting resin composition and the low profile additive composition of the invention are characterized has having improved uniformity and intensity of color.

  本发明涉及一种制备着色热塑性聚合物组合物的过程，该组合物可用作热固性树脂的低剖面添加剂组合物。该过程包括以下步骤：（A）选择至少一种热塑性聚合物，其折射率在热固性树脂的折射率内约0.06个单位；（B）在高强度混合器中高剪切下制备所述热塑性聚合物和至少一种颜色颜料、染料或其混合物的混合物；和（C）在至少一种含有至少一个CH.sub.2.dbd.C<group的液态共聚单体中形成含有步骤（B）中获得的混合物的浆料。在优选实施例中，在步骤（C）中获得的浆料中包含至少一种表面活性剂，其量足以增强从热固性树脂组合物和低剖面添加剂组合物制成的固化复合材料的着色均匀性。在将浆料与热固性树脂混合之前，可以向浆料中添加额外的颜料。从本发明的热固性树脂组合物和低剖面添加剂组合物制成的固化复合材料具有改善的均匀性和颜色强度。
• Imidazolylmethylgruppen enthaltende Farbstoffe und deren Verwendung
  申请人：BASF Aktiengesellschaft

  公开号：EP0034725A2

  公开（公告）日：1981-09-02

  Farbstoffe der Formel in der R1 Wasserstoff, C1-bis C6-Alkyl oder C2- bis C6-Alkenyl, R2 und R3 unabhängig voneinander Wasserstoff, C1 - bis C5-Alkyl oder C2 - bis C6- Alkenyl, R4 C, - bis C12 - Alkyl oder C2 - bis C4-Hydroxyalkyl, Xe ein Äquivalent eines Anions, m O bis 5 und n 0 bis 5, wobei 1 ≤ (m+n) ≤ 5 ist, und F ein (m+n) -wertiger Rest eines Monoazofarbstoffs, eines Disazofarbstoffs, eines Polyazofarbstoffs, eines Chinophthalons, eines Bisdioxazins, einer Verbindung der 5,6-Arylo-2-pyronreihe, eines Naphtholactam-farbstoffs, eine Triphenylmethanfarbstoffs, eines Xanthenfarbstoffs, eines Phthalocyanins, eines Indigoids, eines mindestens eine Phenyl- oder Napthylgruppe enthaltenden Anthrachinonfarbstoffs, eines höher anellierten Carbonylfarbstoffs, eines Chinacridons, eines Perylen-3,4,9,10-tetracarbonsäurediimids, eines Anthrapyrimidins, eines Pyrazoloanthrons, eines Diaminonaphthochinons, eines Naphthazerins oder eines Naphthalin-1,4,5,8-tetracarbonsäurediimids bedeuten. Die Farbstoffe geben auf Cellulose enthaltendes Fasermaterial, insbesondere Papier, brillante Färbungen, die naßecht sind. Bei der Massefärbung von Papier fällt ein farbloses bis praktisch farbloses Abwasser an.

  配方中的着色剂 中的 R1 是氢、C1～C6-烷基或 C2-～C6- 烷基，R2 和 R3 相互独立地为氢、C1-至 C5-烷基或 C2- 至 C6-烯基，R4 为 C, - 至 C12-烷基或 C2- 至 C4-羟基烷基，Xe 为一个当量的阴离子，m 为 O 至 5，n 为 0 至 5，其中 1≤(m+n)≤5、F 是单偶氮染料、二偶氮染料、多偶氮染料、喹酞酮、双二噁嗪、5,6-芳环-2-吡喃酮系列化合物、萘内酰胺染料的 (m+n)- 价基、三苯基甲烷染料、呫吨染料、酞菁染料、靛红染料、至少含有一个苯基或萘基的蒽醌染料、高熔羰基染料、喹吖啶酮、过烯-3,4,9,10-四羧酸二亚胺、蒽嘧啶、吡唑蒽酮、二氨基萘醌、萘泽林或萘-1,4,5,8-四羧酸二亚胺。 这些染料可以在含有纤维素的纤维材料上（尤其是纸张）产生艳丽的染色效果，而且不褪色。在对纸张进行大规模染色时，会产生无色或几乎无色的废水。
• Ferroelectric liquid crystal composition, liquid crystal optical device produced by using the ferroelectric liquid crystal composition, and method of producing the liquid crystal optical device
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0352637A2

  公开（公告）日：1990-01-31

  A ferroelectric liquid crystal composition comprising (A) a ferroelectric liquid crystal material and (B) a non-liquid-crystalline polymeric material; a liquid crystal optical device comprising a layer of the ferroelectric liquid crystal composition, the (A) ferroelectric liquid crystal material in the ferroelectric liquid crystal composition has been uniaxially oriented and two substrates which support the layer of the ferroelectric liquid crystal composition between them and carry on their surfaces facing each other their respective electrode layers, at least one of the electrode layers being a transparent electrode layer; and a method of producing the liquid crystal optical device, which method comprises orienting a liquid crystal optical device yet to be oriented which includes a layer of the ferroelectric liquid crystal composition and two flexible substrates which support the layer of the ferroelectric liquid crystal composition between them and carry on their surfaces facing each other their respective electrode layers, by subjecting the liquid crystal optical device yet to be oriented to a bending treatment.

  一种铁电液晶组合物，包括 (A) 铁电液晶材料和 (B) 非液晶聚合物材料； 一种液晶光学器件，包括 一层铁电液晶组合物，铁电液晶组合物中的 (A) 铁电液晶材料已被单轴取向，以及 两个基底，它们 在它们之间支撑着一层铁电液晶组合物，并且 在它们面对面的表面上带有各自的电极层，其中至少一个电极层是透明电极层；以及 一种生产液晶光学器件的方法，该方法包括定向尚未定向的液晶光学器件，该器件包括 一层铁电液晶组合物和 两块柔性基板，它们 在它们之间支撑铁电液晶成分层，并且 在它们面对面的表面上有各自的电极层、 将待定向液晶光学器件进行弯曲处理。
• Standard samples and methods of instrumental measurement of ASTM color of petroleum products using said samples
  申请人：NIPPON PETROLEUM REFINING COMPANY, Ltd.

  公开号：EP0481519A1

  公开（公告）日：1992-04-22

  A standard sample for use in an instrumental measurement of ASTM color of a petroleum product with a photoelectric colorimeter, which comprises a mixed solution 3-methyl-I-phenyl-4-(phenylazo)-pyrazol-5-ol, 1-(phenylazo)-2-naphthalenol, 1-[[4-[(dimethylphenyl)azo]dimethylphenyl]azo]-2-naphthalenol, 1,5(or 1,8)-bis[(4-methylphenyl)amino]-9,10-anthracenedione, 1-hydroxy-4-[(4-methylphenyl)amino]-9,10-anthracenedione, 1,4-bis-(butylamino)-9,10-anthracenedione and 1,4-bis[(4-butylphenyl)amino]-5,8-dihydroxy-9,10-anthracenedione each as a colorant, 1-phenyl-1-xylylethane as a solvent for said colorants and dodecane as a diluent, and a method of instrumental measurement of ASTM color with the standard sample.

  一种标准样品，用于用光电比色计对石油产品的 ASTM 颜色进行仪器测量，其中包括 3-甲基-I-苯基-4-(苯基偶氮)-吡唑-5-醇混合溶液、1-(苯基偶氮)-2-萘酚、1-[[4-[(二甲基苯基)偶氮]二甲基苯基]偶氮]-2-萘酚、1,5(或 1,8)-双[(4-甲基苯基)氨基]-9,10-蒽二酮、1-羟基-4-[(4-甲基苯基)氨基]-9,10-蒽二酮、1,4-双(丁氨基)-9,10-蒽二酮和 1,4-双[(4-丁基苯基)氨基]-5,8-二羟基-9,10-蒽二酮各自作为着色剂、1-苯基-1-羟乙基乙烷作为上述着色剂的溶剂，十二烷作为稀释剂，以及用标准样品对 ASTM 颜色进行仪器测量的方法。