N-<4-Methoxy-benzyliden>-N'-diphenylmethylen-hydrazin | 31400-19-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-<4-Methoxy-benzyliden>-N'-diphenylmethylen-hydrazin
• 英文别名: N-(4-Methoxy-benzyliden)-N'-diphenylmethylen-hydrazin；N-[(4-methoxyphenyl)methylideneamino]-1,1-diphenylmethanimine
• CAS: 31400-19-8
• 化学式: C₂₁H₁₈N₂O
• 分子量: 314.387
• InChiKey: CYSSHCLEUJAGMB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  24
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  34
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  Bredereck 试剂 、 N-<4-Methoxy-benzyliden>-N'-diphenylmethylen-hydrazin 生成 2,2-Bis-dimethylamino-1-<4-methoxyphenyl>-ethylen
  参考文献：
  名称：

  Bredereck,H. et al., Chemische Berichte, 1971, vol. 104, p. 792 - 801

  摘要：

  DOI：
• 作为产物：
  描述：

  二苯甲酮腙 、 4-甲氧基苯甲醛 在 sulfated anatase-titania 作用下， 反应 0.01h， 以97%的产率得到N-<4-Methoxy-benzyliden>-N'-diphenylmethylen-hydrazin
  参考文献：
  名称：

  An expeditious and solvent free synthesis of azine derivatives using sulfated anatase–titania as a novel solid acid catalyst

  摘要：

  Solid acid catalyst sulfated anatase-titania (TiO2-SO42-) has been used for the synthesis of azine derivatives from benzophenone hydrazone and ketones/aldehydes by simple physical grinding. This sulfated titania gives an excellent yield with short reaction time and is an inexpensive, easily recyclable catalyst for this reaction. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.catcom.2011.08.029

文献信息

• Bredereck,H. et al., Chemische Berichte, 1971, vol. 104, p. 792 - 801
  作者：Bredereck,H. et al.

  DOI：——

  日期：——
• An expeditious and solvent free synthesis of azine derivatives using sulfated anatase–titania as a novel solid acid catalyst
  作者：B. Krishnakumar、M. Swaminathan

  DOI：10.1016/j.catcom.2011.08.029

  日期：2011.11

  Solid acid catalyst sulfated anatase-titania (TiO2-SO42-) has been used for the synthesis of azine derivatives from benzophenone hydrazone and ketones/aldehydes by simple physical grinding. This sulfated titania gives an excellent yield with short reaction time and is an inexpensive, easily recyclable catalyst for this reaction. (C) 2011 Elsevier B.V. All rights reserved.