1,4-di-tert-butyl-2,5-diiodobenzene | 3265-92-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,4-di-tert-butyl-2,5-diiodobenzene
• 英文别名: 1,4-di-tert-butyl-2,5-diiodo-benzene；1,4-Di-tert-butyl-2,5-dijod-benzol；2,5-Dijod-1,4-di-tert.butyl-benzol；1,4-Ditert-butyl-2,5-diiodobenzene
• CAS: 3265-92-7
• 化学式: C₁₄H₂₀I₂
• 分子量: 442.122
• InChiKey: RFGPPZHYQDDSLB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 海关编码：
  2903999090

反应信息

• 作为反应物：
  描述：

  1,4-di-tert-butyl-2,5-diiodobenzene 在 硫酸 、 硝酸 作用下， 生成 1,4-di-tert-butyl-2-iodo-5-nitro-benzene
  参考文献：
  名称：

  25.叔的一些衍生物。丁基苯

  摘要：

  DOI：

  10.1039/jr9580000120
• 作为产物：
  描述：

  2,5-di-tert-butyl-p-dinitrobenzene 在 盐酸 、 乙醇 、 硫酸 、 溶剂黄146 、 potassium iodide 、 tin(ll) chloride 、 sodium nitrite 作用下， 生成 1,4-di-tert-butyl-2,5-diiodobenzene
  参考文献：
  名称：

  25.叔的一些衍生物。丁基苯

  摘要：

  DOI：

  10.1039/jr9580000120

文献信息

• The Direct lodination of Polyalkylbenzenes by the Crossed Jacobsen Reaction
  作者：Hitomi Suzuki、Takashi Sugiyama、Ryozo Goto

  DOI：10.1246/bcsj.37.1858

  日期：1964.12

  A method has been developed for the direct iodination of certain polyalkylbenzenes by the transfer of an iodine atom of iodoanisole. It consists of the simultaneous addition of iodoanisole and sulfuric acid to the polyalkylbenzene to which the transfer is to be made. In this way, iodo compounds have been prepared from eight polyalkylbenzenes.

  已经开发了一种通过转移碘苯甲醚的碘原子直接碘化某些多烷基苯的方法。它包括将碘苯甲醚和硫酸同时添加到要转移到的多烷基苯中。通过这种方式，由八种多烷基苯制备了碘化合物。
• A silver(i) coordinated phenanthroline-based polymer with high ethylene/ethane adsorption selectivity
  作者：Chao Yu、Matthew G. Cowan、Richard D. Noble、Wei Zhang

  DOI：10.1039/c4cc02143f

  日期：——

  We report a non-porous silver(i) coordinated phenanthroline-based polymer, which exhibits a high ideal ethylene/ethane adsorption selectivity (15/1) and high ethylene uptake (5.0 mmol g(-1)) at ambient temperature and pressure. Both silver(i) coordination and polymer structures are important for the high uptake of ethylene.

  我们报告了一种无孔的银（i）配合菲咯啉基聚合物，它在环境温度和压力下表现出高的理想乙烯/乙烷吸附选择性（15/1）和高的乙烯吸收率（5.0 mmol g（-1））。银（i）的配位和聚合物结构对于乙烯的高摄取都很重要。
• Identifying Diversity in Nanoscale Electrical Break Junctions
  作者：Santiago Martín、Iain Grace、Martin R. Bryce、Changsheng Wang、Rukkiat Jitchati、Andrei S. Batsanov、Simon J. Higgins、Colin J. Lambert、Richard J. Nichols

  DOI：10.1021/ja103327f

  日期：2010.7.7

  The realization of molecular-scale electronic devices will require the development of novel strategies for controlling electrical properties of metallmoleculelmetal junctions, down to the single molecule level Here, we show that it is possible to exert chemical control over the formation of metallmolecule. moleculelmetal junctions in which the molecules interact by pi-stacking The tip of an STM is used to form one contact, and the substrate the other, the molecules are conjugated oligophenyleneethynylenes (OPEs) Supramolecular pi-pi interactions allow current to flow through the junction, but not if bulky tert-butyl substituents on the phenyl rings prevent such interactions For the first time, we find evidence that pi-stacked junctions can form even for OPEs with two thiol contacts. Furthermore, we find evidence for metallmoleculelmetal junctions involving oligophenyleneethynylene monothiols, in which the second contact must be formed by the interaction of the pi-electrons of the terminal phenyl ring with the metal surface