5-methylbiphenyl-2-thiol | 1370652-72-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-methylbiphenyl-2-thiol
• 英文别名: 4-Methyl-2-phenylbenzenethiol
• CAS: 1370652-72-4
• 化学式: C₁₃H₁₂S
• 分子量: 200.304
• InChiKey: FQPDWLOPQKFGOE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  14
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-(p-tolylsulfinyl)pyridine 在 甲醇 、 palladium diacetate 、 magnesium 、 silver carbonate 、 对苯醌 作用下， 以 1,2-二氯乙烷 为溶剂， 反应 12.0h， 生成 5-methylbiphenyl-2-thiol
  参考文献：
  名称：

  可移动的2-吡啶基亚磺酰基辅助的钯催化的芳烃CH键区域选择性芳基化

  摘要：

  描述了由可除去的2-吡啶基亚磺酰基协助的芳烃CH键的钯催化的芳基化。该反应使用芳基三氟硼酸酯作为芳基化试剂，从而以中等至良好的产率得到了具有宽底物范围的相应产物。可以除去指导基团或将其转换为其他有用的功能，这证明了该方法的潜在综合应用。 CH键活化-芳基化-芳基三氟硼酸酯-亚砜-钯催化

  DOI：

  10.1055/s-0031-1290320

文献信息

• 2-Saccharinylmethyl aryl carboxylates useful as proteolytic enzyme inhibitors and compositions and method of use
  申请人：STERLING WINTHROP INC.

  公开号：EP0483928A1

  公开（公告）日：1992-05-06

  4-R⁴-R⁵-2-Saccharinylmethyl aryl carboxylates, useful in the treatment of degenerative diseases, are prepared by reacting a 4-R⁴-R⁵-2-halomethylsaccharin with an arylcarboxylic acid in the presence of an acid-acceptor.

  4-R⁴-R⁵-2-糖精甲基芳基羧酸盐可用于治疗退行性疾病，其制备方法是将 4-R⁴-R⁵-2-halomethylsaccharin 与芳基羧酸在酸受体存在的情况下进行反应。
• ORGANIC ELECTROLUMINESCENCE DEVICE AND DIAMINE COMPOUND FOR ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：Samsung Display Co., Ltd.

  公开号：EP3828161A2

  公开（公告）日：2021-06-02

  An organic electroluminescence device of an embodiment includes a first electrode, a hole transport region disposed on the first electrode, an emission layer disposed on the hole transport region, an electron transport region disposed on the emission layer, and a second electrode disposed on the electron transport region, wherein the hole transport region includes a diamine compound represented by Formula 1, thereby showing high emission efficiency:

  一个实施例中的有机电致发光器件包括第一电极、设置在第一电极上的空穴传输区、设置在空穴传输区上的发射层、设置在发射层上的电子传输区以及设置在电子传输区上的第二电极，其中空穴传输区包括由式 1 表示的二胺化合物，从而显示出较高的发射效率：
• Curable composition and cured product
  申请人：AGC Inc.

  公开号：US10611869B2

  公开（公告）日：2020-04-07

  Disclosed herein is a curable composition containing a monomer (A) having at least one crosslinkable group and at least one aromatic ring, a monomer (B) having a fluorene skeleton, a compound (C) having an Abbe number of at most 21, and a polymerization initiator (D), wherein the content of the compound (C) is from 1 to 10 mass % based on 100 mass % of the total content of the monomer (A), the monomer (B) and the compound (C). Curable compositions of this disclosure have low viscosities and produce cured products having a high refractive indices, a low Abbe numbers, high transparencies and high heat resistances.

  本文公开了一种可固化组合物，该组合物包含具有至少一个可交联基团和至少一个芳香环的单体 (A)、具有芴骨架的单体 (B)、阿贝数至多为 21 的化合物 (C) 以及聚合引发剂 (D)，其中化合物 (C) 的含量为单体 (A)、单体 (B) 和化合物 (C) 总含量的 1 至 10%。本公开的可固化组合物具有低粘度，生产的固化产品具有高折射率、低阿贝数、高透光率和高耐热性。
• CURABLE COMPOSITION AND CURED PRODUCT
  申请人：AGC Inc.

  公开号：US20190218325A1

  公开（公告）日：2019-07-18

  To provide a curable composition having a low viscosity, from which a cured product having a high refractive index, a low Abbe number, high transparency and high heat resistance can be obtained, and its cured product. A curable composition comprising a monomer (A) having at least one crosslinkable group and at least one aromatic ring, which may have one or more sulfur atoms not constituting the ring skeleton of the aromatic ring, in which the total proportion of the mass of atoms constituting the ring skeleton of the aromatic ring, the mass of hydrogen atoms bonded to the atoms constituting the ring skeleton of the aromatic ring and the mass of the sulfur atom not constituting the ring skeleton of the aromatic ring is at least 47 mass % based on 100 mass % of one monomer molecule, and which has a viscosity at 25° C. of at most 1,000 mPa·s; a specific monomer (B) having a fluorene skeleton; a compound (C) having an Abbe number of at most 21; and a polymerization initiator (D), wherein the content of the compound (C) is from 1 to 10 mass % based on 100 mass % of the total content of the monomer (A), the monomer (B) and the compound (C).
• US5856349A
  申请人：——

  公开号：US5856349A

  公开（公告）日：1999-01-05