2,2',2'',4,4',4'',6,6',6''-九硝基间三联苯 | 51460-84-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2,2',2'',4,4',4'',6,6',6''-九硝基间三联苯
• 英文名称: 2,2',2'',4,4',4'',6,6',6''-nitro-m-terphenyl
• 英文别名: 2,2',2'',4,4',4'',6,6',6''-nonanitro-1,1':3',1''-terphenyl；2,2',2'',4,4',4'',6,6',6''-nonanitro-m-terphenyl；1,3,5-trinitro-2,4-bis(2,4,6-trinitrophenyl)benzene
• CAS: 51460-84-5
• 化学式: C₁₈H₅N₉O₁₈
• 分子量: 635.287
• InChiKey: DYGJZCCUSXSGBE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  45
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  412
• 氢给体数：
  0
• 氢受体数：
  18

反应信息

• 作为反应物：
  描述：

  2,2',2'',4,4',4'',6,6',6''-九硝基间三联苯 2250.0 ℃ 、1.38 MPa 条件下， 生成 二氧化碳 、 氮气
  参考文献：
  名称：

  2,2',2'',4,4',4'',6,6',6''-nonanitro-1,1':3',1'高温热解的反应分子动力学模拟'-三联苯 (NONA)

  摘要：

  2,2',2'',4,4',4'',6,6',6''-Nonanitro-1,1':3',1''-三联苯 (NONA) 目前被认为是优良的耐热炸药。为了提高对 NONA 热分解路径的原子理解，我们在极端温度和压力条件下进行了一系列反应力场 (ReaxFF) 分子动力学模拟。结果表明，两种不同的初始分解机制是C-NO 2键的均裂和硝基-亚硝酸盐（NO 2 → ONO）异构化，然后是NO裂变。在随后的 NONA 分解中发现了双分子和稠环化合物。有限时间步长下的产物识别分析表明，气态产物为CO 2、N 2和H2 O. CO 2的量在能量上对高温或低密度系统更有利。含碳团簇是低温下有利的生长途径，扩散系数分析进一步证明了这一过程。通过反应动力学参数和活化势垒分析判断，晶体密度的增加加速了NONA的分解。在吸热和放热阶段，NONA 密度增加 20%，活化能分别增加 3.24 和 0.48 kcal mol

  DOI：

  10.1039/c9ra10261b

文献信息

• Capsules containing micro-proppant and a substance to produce micro-seismic events
  申请人：Halliburton Energy Services, Inc.

  公开号：US10378345B2

  公开（公告）日：2019-08-13

  A method of mapping micro-fractures of a fracture network comprising: introducing a capsule or coated capsule or containment into the fracture network, where in the capsules or containment comprise an explosive substance and a plurality of micro-proppant; allowing initiation of the explosive substance of some or all of the plurality of the capsules to occur, wherein initiation of the explosive substance causes detonation of the explosive substance, and wherein the detonation produces one or more micro-seismic events; and causing or allowing at least a portion of the micro-proppant to enter one or more of the micro-fractures.

  一种绘制断裂网微断裂图的方法，包括将胶囊或有涂层的胶囊或容器引入断裂网络，其中胶囊或容器包括爆炸物质和多个微支撑剂；允许多个胶囊中的部分或全部的爆炸物质起爆，其中爆炸物质起爆导致爆炸物质爆炸，爆炸产生一个或多个微地震事件；以及导致或允许至少一部分微支撑剂进入一个或多个微断裂。
• Perforating systems with insensitive high explosive
  申请人：Halliburton Energy Services, Inc.

  公开号：US10746002B2

  公开（公告）日：2020-08-18

  The disclosure relates to perforating systems for perforating the casing of a wellbore. The perforating systems contain insensitive high explosives. The disclosure also relates to shaped charges containing insensitive high explosives for use in such perforating systems. The disclosure further relates to methods of using such perforating systems to perforate the casing of a wellbore.

  本公开涉及用于穿孔井筒套管的穿孔系统。穿孔系统含有不敏感的烈性炸药。本公开还涉及用于此类穿孔系统的含有不敏感烈性炸药的定型装药。本公开还涉及使用这种穿孔系统对井筒套管进行穿孔的方法。
• PERFORATING SYSTEMS WITH INSENSITIVE HIGH EXPLOSIVE
  申请人：Halliburton Energy Services, Inc.

  公开号：US20170241245A1

  公开（公告）日：2017-08-24

  The disclosure relates to perforating systems for perforating the casing of a wellbore. The perforating systems contain insensitive high explosives. The disclosure also relates to shaped charges containing insensitive high explosives for use in such perforating systems. The disclosure further relates to methods of using such perforating systems to perforate the casing of a wellbore.
• CAPSULES CONTAINING MICRO-PROPPANT AND A SUBSTANCE TO PRODUCE MICRO-SEISMIC EVENTS
  申请人：Halliburton Energy Services, Inc.

  公开号：US20170350244A1

  公开（公告）日：2017-12-07

  A method of mapping micro-fractures of a fracture network comprising: introducing a capsule or coated capsule or containment into the fracture network, where in the capsules or containment comprise an explosive substance and a plurality of micro-proppant; allowing initiation of the explosive substance of some or all of the plurality of the capsules to occur, wherein initiation of the explosive substance causes detonation of the explosive substance, and wherein the detonation produces one or more micro-seismic events; and causing or allowing at least a portion of the micro-proppant to enter one or more of the micro-fractures.
• HIGH-TEMPERATURE EXPLOSIVE FOR OILFIELD PERFORATING
  申请人：Halliburton Energy Services, Inc.

  公开号：US20210332677A1

  公开（公告）日：2021-10-28

  Included are methods and systems for oilfield perforating. An example system includes a firing head subassembly; a gun subassembly; and 4,10-dinitro-2,6,8,12-tetraoxa-4,10-diazatetracyclo[5.5.0.0 5,9 .0 3,11 ]-dodecane (“TEX”). An example method includes lowering a perforating system into a casing of a wellbore, wherein the perforating system comprises TEX; detonating the TEX; and perforating the casing.