2-ethoxy-6-allyl-phenol | 1755-53-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2-ethoxy-6-allyl-phenol
• 英文别名: 3-Ethoxy-1-allyl-2-hydroxy-benzol (o-Allyl-guetol)；o-Allyl-guetol；Aethyl-(2-hydroxy-3-allyl-phenyl)-aether；2-Hydroxy-3-aethoxy-1-allyl-benzol；2-Aethoxy-6-allyl-phenol；2-allyl-6-ethoxy phenol；2-Ethoxy-6-(2-propen-1-yl)phenol；2-ethoxy-6-prop-2-enylphenol
• CAS: 1755-53-9
• 化学式: C₁₁H₁₄O₂
• 分子量: 178.231
• InChiKey: OAAQJIVRKPUMJP-UHFFFAOYSA-N

物化性质

• 沸点：
  268.9±25.0 °C(Predicted)
• 密度：
  1.031±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-ethoxy-6-allyl-phenol 生成 3-乙氧基水杨醛
  参考文献：
  名称：

  US2457074

  摘要：

  公开号：
• 作为产物：
  描述：

  O-(烯丙氧基)苯乙醚 反应 10.0h， 生成 2-ethoxy-6-allyl-phenol
  参考文献：
  名称：

  反对白菜弯角线虫Trichoplusia ni的二烷氧基苯和二烷氧基烯丙基苯的摄食和产卵抑制剂：潜在的昆虫行为控制剂

  摘要：

  在实验室生物测定中，针对白菜弯角曲霉Trichoplusia ni评估了各个二烷氧基苯化合物/对以及通过取代的烯丙氧基苯的克莱森重排获得的羟基或烷氧基取代的烯丙基苯的拒食剂，产卵抑制物和毒性作用。大多数化合物/组强烈抑制幼虫摄食，有些还表现出温和的毒性和产卵抑制作用。一些化合物/组比商业驱虫剂DEET（N，N- diethyl- m-甲苯胺），因为进食和产卵都可以阻止白菜弯角。根据获得的产卵数据，提出了有关产卵部位的一般假设：一种与苯环同一侧的烷基和烯丙基结合的方式会产生阻吓作用，另一种与烷基和烯丙基的结合方式相反。苯环导致刺激。结果表明，某些构效关系对提高化合物的功效和设计用于农业的新型无毒昆虫控制剂很有用。

  DOI：

  10.1021/jf9045123

文献信息

• Curable compositions
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0399350A2

  公开（公告）日：1990-11-28

  Adducts of an epoxy resin and a compound containing at least one aromatic hydroxyl group and at least one polymerizable ethylenically unsaturated group per molecule are prepared which are optionally reacted with water, a secondary amine or a phenol which product is copolymerized with a polymerizable monoethylenically unsaturated carboxylic acid and a polymerizable monoethylenically unsaturated compound free of carboxylic acid groups. This product is rendered water miscible by reaction with a primary, secondary or tertiary amine or an alkali metal hydroxide, carbonate or bicarbonate. This product can then be cured with any suitable curing agent such as phenol/aldehyde compounds, urea/aldehyde compounds and melamine/aldehyde compounds and blocked isocyanates.

  制备环氧树脂和一种每分子含有至少一个芳香羟基和至少一个可聚合乙烯不饱和基团的化合物的加合物，该加合物可选择与水、仲胺或苯酚反应，其产物与一种可聚合单乙烯不饱和羧酸和一种不含羧酸基团的可聚合单乙烯不饱和化合物共聚。通过与伯胺、仲胺或叔胺或碱金属氢氧化物、碳酸盐或碳酸氢盐反应，使该产品与水混溶。然后，可使用任何合适的固化剂（如苯酚/甲醛化合物、脲/甲醛化合物、三聚氰胺/甲醛化合物和封端异氰酸酯）对该产品进行固化。
• Agonists and Antagonists of Antennal Responses of Gypsy Moth (Lymantria dispar) to the Pheromone (+)-Disparlure and Other Odorants
  作者：Erika Plettner、Regine Gries

  DOI：10.1021/jf904139e

  日期：2010.3.24

  Insects use the sense of smell to guide many behaviors that are important for their survival. The gypsy moth uses a pheromone to bring females and males together over long distances. Male moth antennae are equipped with innervated sensory hairs that selectively respond to pheromone components and other odors. Host plant odors, in particular, are detected by moths and sometimes cause an enhancement of the antennal and behavioral responses of the moths to their pheromone. Inspired by naturally occurring agonists and antagonists of insect pheromone responses, we have screened, by electroantennogram (EAG) recordings, a collection of compound sets and of individual compounds. We have detected interference of some compounds with the EAG responses of male gypsy moth antennae to the pheromone. We describe three activities: (1) short-term inhibition or enhancement of mixed compound + pheromone plumes, (2) long-term inhibition of pure pheromone plumes following a mixed compound 4-pheromone plume, and (3) inhibition of the recovery phase of mixed compound + pheromone plumes. Long-term inhibition was robust, decayed within 30 s, and correlated with the inhibition of recovery; for both activities clear structure-activity patterns were detected. The commercial repellent N,N-diethyltoluamide (DEET) was included for comparison. The most active and reproducible short-term inhibitor was a mixture of 1-allyl-2,4-dimethoxybenzene and 2-allyl-1,3-dimethoxybenzene. The most active long-term inhibitors were a set of 1-alkoxy-4-propoxybenzenes, DEET, and 1-ethoxy-4-propoxybenzene. DEET was more specific in the olfactory responses it inhibited than 1-ethoxy-4-propoxybenzene, and DEET did not inhibit recovery, whereas 1-ethoxy-4-propoxybenzene did. Target sites for the three activities are discussed.
• CERVENY, LIBOR;KREJCIKOVA, ALENA;MARHOUL, ANTONIN;RUZICKA, VLASTIMIL, SB. VSCHT PRAZE, 29,(1986) 29-36
  作者：CERVENY, LIBOR、KREJCIKOVA, ALENA、MARHOUL, ANTONIN、RUZICKA, VLASTIMIL

  DOI：——

  日期：——
• US4138411A
  申请人：——

  公开号：US4138411A

  公开（公告）日：1979-02-06