3-methoxy-2,4,6-triphenyl-pyridine | 28607-91-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 3-methoxy-2,4,6-triphenyl-pyridine
• 英文别名: Pyridine, 3-methoxy-2,4,6-triphenyl-；3-methoxy-2,4,6-triphenylpyridine
• CAS: 28607-91-2
• 化学式: C₂₄H₁₉NO
• 分子量: 337.421
• InChiKey: UKLKXPXVMQXEIO-UHFFFAOYSA-N

物化性质

• 沸点：
  433.5±33.0 °C(Predicted)
• 密度：
  1.115±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  26
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  22.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-甲氧基苯乙酮 、 N-苯甲酰甲基溴吡啶 、 苯甲醛 以 溶剂黄146 为溶剂， 生成 3-methoxy-2,4,6-triphenyl-pyridine
  参考文献：
  名称：

  3-Methoxy-2,4,6-triphenylpyridine at 173K

  摘要：

  In the title compound, C24H19NO, the methoxy group attached at C3 avoids steric hindrance with the neighbouring phenyl rings by emerging almost orthogonally from the pyridine ring [C2-C3-O31-C31 -95.3(2)degrees]. The phenyl rings show a disrotatory arrangement and the angles between them and the pyridyl ring range from 22.66(6) to 47.91(5)degrees, whereas these angles differ by only approximately 6 degrees in 2,4,6-triphenylpyridine.

  DOI：

  10.1107/s0108270197012778

文献信息

• TEUBER H.-J.; SCHUETZ G.; KERN W., CHEM. BER. <CHBE-AM>, 1975, 108, NO 2, 383-394
  作者：TEUBER H.-J.、 SCHUETZ G.、 KERN W.

  DOI：——

  日期：——
• 3-Methoxy-2,4,6-triphenylpyridine at 173K
  作者：M. Bolte

  DOI：10.1107/s0108270197012778

  日期：1998.1.15

  In the title compound, C24H19NO, the methoxy group attached at C3 avoids steric hindrance with the neighbouring phenyl rings by emerging almost orthogonally from the pyridine ring [C2-C3-O31-C31 -95.3(2)degrees]. The phenyl rings show a disrotatory arrangement and the angles between them and the pyridyl ring range from 22.66(6) to 47.91(5)degrees, whereas these angles differ by only approximately 6 degrees in 2,4,6-triphenylpyridine.