N-[4-(4-methoxyphenylamino)phenyl]acetamide | 17785-89-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-[4-(4-methoxyphenylamino)phenyl]acetamide
• 英文别名: N-(4-(4-methoxyphenylamino)phenyl)acetoamide；4-Acetylamino-4'-methoxy-diphenylamin；4-Acetamino-4'-methoxydiphenylamin；Acetyl-N-(p-methoxyphenyl)-p-phenylendiamin；acetic acid-(4-p-anisidino-anilide)；Essigsaeure-(4-p-anisidino-anilid)；N-[4-(4-Methoxyanilino)phenyl]acetamide
• CAS: 17785-89-6
• 化学式: C₁₅H₁₆N₂O₂
• 分子量: 256.304
• InChiKey: BMUMXXZBLKOEEZ-UHFFFAOYSA-N

物化性质

• 熔点：
  142 °C
• 沸点：
  481.5±30.0 °C(Predicted)
• 密度：
  1.205±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  50.4
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  (4-p-anisidino-phenyl)-amidosulfuric acid 生成 N-[4-(4-methoxyphenylamino)phenyl]acetamide
  参考文献：
  名称：

  Lantz; Kremer, Bulletin de la Societe Chimique de France, 1957, p. 526

  摘要：

  DOI：

文献信息

• Synthesis of Arylamines via<i>Non-Aerobic</i>Dehydrogenation Using a Palladium/Carbon-Ethylene System
  作者：Yuya Shimomoto、Ryosuke Matsubara、Masahiko Hayashi

  DOI：10.1002/adsc.201800504

  日期：2018.9.3

  with amines proceeded under an ethylene atmosphere in the presence of a catalytic amount of palladium/carbon to afford a variety of arylamines in good to high yields. The present reaction was carried out under completely non‐aerobic conditions, and which is in contrast with the previously reported aerobic system. has wide applicability affording a variety of aromatic amines, and co‐product of the reaction

  环己酮与胺的反应在乙烯气氛下，在催化量的钯/碳存在下进行，以高收率或高收率得到各种芳基胺。本反应是在完全无氧的条件下进行的，这与先前报道的有氧系统相反。具有广泛的适用性，可提供多种芳族胺，并且反应的副产物仅是气态乙烷。因此，该方法是环境友好的。该方案在分子内应用，为构建喹啉和异喹啉化合物提供了一种新方法。
• Presensitized plate for use in making lithographic printing plate
  申请人：Fuji Photo Film Co., Ltd.

  公开号：EP0530815A1

  公开（公告）日：1993-03-10

  A presensitized plate for use in making a lithographic printing plate comprises a substrate provided thereon with a light-sensitive layer formed from a light-sensitive composition comprising a diazonium polymeric compound having two kinds of specific repeating units and a lipophilic polymeric compound having an acid value of not less than 20 and less than 250. The presensitized plate can provide a lithographic printing plate having excellent printing durability since the diazonium compound used has a high molecular weight. Moreover, since the diazonium compound has alkali-soluble groups and the lipophilic compound having an acid value of not less than 20 and less than 250 and easily soluble in an alkaline water is used as a binder, the presensitized plate has good developability and can provide a lithographic printing plate free of background contamination.

  一种用于制作平版印刷板的预敏板，包括一个基板，基板上有一个感光层，感光层由感光组合物形成，感光组合物包括具有两种特定重复单元的重氮高分子化合物和酸值不小于 20 且小于 250 的亲脂高分子化合物。由于所使用的重氮化合物具有较高的分子量，因此预感光版材可以提供具有出色印刷耐久性的平版印刷版材。此外，由于重氮化合物具有碱溶性基团，而亲脂性化合物的酸值不小于 20 且小于 250，并且易溶于碱水作为粘合剂，因此预敏印版具有良好的显影性，可以提供无背景污染的平版印刷版。
• Pyrrole-2-carboxylic Acid as a Ligand for the Cu-Catalyzed Reactions of Primary Anilines with Aryl Halides
  作者：Ryan A. Altman、Kevin W. Anderson、Stephen L. Buchwald

  DOI：10.1021/jo8008676

  日期：2008.7.1

  Pyrrole 2-carboxylic acid (L5) was found to be an effective ligand for the Cu-catalyzed monoarylation of anilines with aryl iodides and bromides. Under the reported conditions (10% CuI/20% L5/DMSO/K(3)PO(4)/80-100 degrees C/20-24 h), a variety of useful functional groups were tolerated, and moderate to good yields of the diaryl amine products were obtained.
• Erdey et al., Acta Chimica Academiae Scientiarum Hungaricae, 1957, vol. 12, p. 251,257
  作者：Erdey et al.

  DOI：——

  日期：——
• US4581313A
  申请人：——

  公开号：US4581313A

  公开（公告）日：1986-04-08