1-But-3-enylsulfanylhexane | 130934-99-5

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 1-But-3-enylsulfanylhexane
• CAS: 130934-99-5
• 化学式: C₁₀H₂₀S
• 分子量: 172.335
• InChiKey: QHUOUZBBCNPCSE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  11
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-But-3-enylsulfanylhexane 在 ruthenium(IV) oxide 氢气 作用下， 以 甲醇 为溶剂， 60.0 ℃ 、810.6 kPa 条件下， 反应 48.0h， 以87%的产率得到1-丁基硫烷基-己烷
  参考文献：
  名称：

  Low Pressure Hydrogenation of Unsaturated Sulphides with Homogeneous and Heterogeneous Ruthenium Catalysts

  摘要：

  Ru2O . nH(2)O and [Ru3O(AcO)(6)(H2O)(3)](AcO-)-Ac-+ were examined for catalytic activity in the hydrogenation of a series of unsaturated sulphides under heterogeneous and homogeneous conditions, respectively. By the appropriate combination of these two methodologies, a number of saturated sulphides could be synthesized in satisfactory to good yields, thus minimizing side reactions.

  DOI：

  10.1080/00397919608003694
• 作为产物：
  描述：

  n-hexyl(vinyl)sulfide 在 ruthenium(IV) oxide 乙醇 、 氢气 、 sodium 作用下， 以 甲醇 为溶剂， 25.0~60.0 ℃ 、810.6 kPa 条件下， 反应 48.0h， 生成 1-But-3-enylsulfanylhexane
  参考文献：
  名称：

  Low Pressure Hydrogenation of Unsaturated Sulphides with Homogeneous and Heterogeneous Ruthenium Catalysts

  摘要：

  Ru2O . nH(2)O and [Ru3O(AcO)(6)(H2O)(3)](AcO-)-Ac-+ were examined for catalytic activity in the hydrogenation of a series of unsaturated sulphides under heterogeneous and homogeneous conditions, respectively. By the appropriate combination of these two methodologies, a number of saturated sulphides could be synthesized in satisfactory to good yields, thus minimizing side reactions.

  DOI：

  10.1080/00397919608003694

文献信息

• The directed Pauson-Khand reaction
  作者：Marie E. Krafft、Carmelinda A. Juliano、Ian L. Scott、Colin Wright、Michael D. McEachin

  DOI：10.1021/ja00005a038

  日期：1991.2

  The regioselectivity of the cobalt-mediated cocyclization of an alkene, an alkyne, and carbon monoxide has been shown to be directed by the use of a soft atom, either sulfur or nitrogen, tethered to the alkene partner by a carbon chain. Direction from the homoallylic position is more efficient thant from the allylic or bishomoallylic position. A rationale is proposed to explain this observation. Studies

  钴介导的烯烃、炔烃和一氧化碳共环化的区域选择性已被证明是通过使用一个软原子（硫或氮）来指导的，硫或氮通过碳链连接到烯烃伙伴上。来自同位烯丙基位置的方向比来自烯丙基或双烯丙基位置的方向更有效。提出了一个基本原理来解释这一观察结果。研究了不同烷基对硫和氮的影响以及其他修饰
• KRAFFT, MARIE E.;JULIANO, CARMELINDA A.;SCOTT, IAN L.;WRIGHT, COLIN;MCEAC+, J. AMER. CHEM. SOC., 113,(1991) N, C. 1693-1703
  作者：KRAFFT, MARIE E.、JULIANO, CARMELINDA A.、SCOTT, IAN L.、WRIGHT, COLIN、MCEAC+

  DOI：——

  日期：——