o-allylbenzyl chloride | 89121-39-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: o-allylbenzyl chloride
• 英文别名: 2-allylbenzyl chloride；1-Allyl-2-(chloromethyl)benzene；1-(chloromethyl)-2-prop-2-enylbenzene
• CAS: 89121-39-1
• 化学式: C₁₀H₁₁Cl
• mdl: MFCD19232325
• 分子量: 166.65
• InChiKey: WJNWNIZASSEZRR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  o-allylbenzyl chloride 在 四(三苯基膦)钯 、 三乙胺 作用下， 以 乙腈 为溶剂， 反应 1.17h， 以75%的产率得到2-亚甲基茚满
  参考文献：
  名称：

  Spiro(imidazo[1,2-a]pyrano[2,3-c]pyridine-9-indenes) as inhibitors of gastric acid secretion

  摘要：

  Asymmetric and symmetric spiro(imidazo[1,2-a]pyrano[2,3-c]pyridine-9-indenes) were prepared using a synthetic approach that comprised a cross-metathesis reaction and an acid-catalyzed cycloisomerisation as key steps. The target compounds constitute potent inhibitors of the gastric proton pump enzyme with inhibitory activity comparable to potassium-competitive acid blockers (P-CABs) belonging to the known 9-aryl-7H-8,9-dihydropyrano[2,3-c]imidazo[1,2-a]pyridine series. Spiro(imidazo[1,2-a]pyrano[2,3-c]pyridine-9,2'-indenes) represent the first example for P-CABs, in which the distance between the heterocyclic scaffold and the aryl residue has been modified, and are promising candidates for further development as anti-ulcer drugs. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.bmc.2008.10.055
• 作为产物：
  描述：

  2-烯丙基苄醇 在 氯化亚砜 作用下， 以 二氯甲烷 为溶剂， 以89%的产率得到o-allylbenzyl chloride
  参考文献：
  名称：

  新叶酸、1-茚满甲基、2-烯丙基苄基和 2-(2-乙烯基苯基)乙基自由基重排的阿伦尼乌斯参数与从三丁基锡烷中夺氢有关

  摘要：

  已经确定了与从三丁基锡烷中提取氢原子相关的几种自由基重排速率的温度依赖性。2-苯基-2-甲基丙基重排为 1-苯基-2-甲基丙基-2-基（新叶酸重排）相对于夺氢反应由 log (r/M) = (2.48 +/- 0.08) - (8.13) 表示+/-0.16)/theta，theta = 2.3 RT kcal/mol。2-烯丙基苄基重排为2-茚满甲基的重排为log (r/M) = (2.32 +/- 0.16)- (10.47 +/- 0.36/theta, 2-烯丙基苄基重排为2-四烯丙基的用log表示(r/M) = (2.18 +/- 0.28) - (12.47 +/- 0.60)/theta. 1-茚满甲基重排为 2-四烯丙基由 log (r/M) = (2.65 +/- 0.12) 表示) - (11.21 +/- 0.24)/theta. 2-(2-乙烯基苯基)乙基与五元环的闭合发生在

  DOI：

  10.1021/ja00326a013

文献信息

• Arrhenius parameters for rearrangements of the neophyl, 1-indanylmethyl, 2-allylbenzyl, and 2-(2-vinylphenyl)ethyl radicals relative to hydrogen abstraction from tributylstannane
  作者：James A. Franz、Russell D. Barrows、Donald M. Camaioni

  DOI：10.1021/ja00326a013

  日期：1984.7

  The temperature dependence of rates of several radical rearrangements relative to abstraction of hydrogen atom from tributylstannane has been determined. The rearrangement of 2-phenyl-2-methylpropyl to 1-phenyl-2-methylprop-2-yl (neophyl rearrangement) relative to hydrogen abstraction is represented by log (r/M) = (2.48 +/- 0.08) - (8.13 +/-0.16)/theta, theta = 2.3 RT kcal/mol. The rearrangement of

  已经确定了与从三丁基锡烷中提取氢原子相关的几种自由基重排速率的温度依赖性。2-苯基-2-甲基丙基重排为 1-苯基-2-甲基丙基-2-基（新叶酸重排）相对于夺氢反应由 log (r/M) = (2.48 +/- 0.08) - (8.13) 表示+/-0.16)/theta，theta = 2.3 RT kcal/mol。2-烯丙基苄基重排为2-茚满甲基的重排为log (r/M) = (2.32 +/- 0.16)- (10.47 +/- 0.36/theta, 2-烯丙基苄基重排为2-四烯丙基的用log表示(r/M) = (2.18 +/- 0.28) - (12.47 +/- 0.60)/theta. 1-茚满甲基重排为 2-四烯丙基由 log (r/M) = (2.65 +/- 0.12) 表示) - (11.21 +/- 0.24)/theta. 2-(2-乙烯基苯基)乙基与五元环的闭合发生在
• [EN] ORGANOSILANE, IONIC ORGANOSILANE, MEMBRANE COMPOSITION, AND MEMBRANE<br/>[FR] ORGANOSILANE, ORGANOSILANE IONIQUE, COMPOSITION DE MEMBRANE ET MEMBRANE
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2020254930A1

  公开（公告）日：2020-12-24

  A dihaloorganosilane is represented by the formula (I): Each X independently represents C1, Br, or I. Each Ar1 independently represents a phenylene group optionally substituted by 1 to 4 alkyl groups selected from methyl or ethyl. Each R1 independently represents an alkylene group having from 2 to 18 carbon atoms. Each R2 independently represents methyl or ethyl. Each R3 independently represents an alkylene group having from 1 to 18 carbon atoms. Each R4 independently represents an alkylene group having from 2 to 18 carbon atoms, and n is an integer in a range of 0 to 5, inclusive. Ionic organosilanes preparable from the dihaloorganosilanes are represented by the formula (II): Membrane compositions and membranes containing the ionic organosilanes are also disclosed.

  一种二卤有机硅烷的化学式为（I）：每个X独立地代表C1、Br或I。每个Ar1独立地代表一个苯基团，可选择地被1至4个甲基或乙基烷基取代。每个R1独立地代表具有2至18个碳原子的烷基基团。每个R2独立地代表甲基或乙基。每个R3独立地代表具有1至18个碳原子的烷基基团。每个R4独立地代表具有2至18个碳原子的烷基基团，n是一个范围在0至5之间的整数。可由二卤有机硅烷制备的离子有机硅烷的化学式为（II）：还公开了含有离子有机硅烷的膜组合物和膜。
• Photolytic Reactions of (o-Allylbenzyl)dicarbonyl(?5-cyclopentadienyl)iron
  作者：Gebhard Thoma、Bernd Giese

  DOI：10.1002/hlca.19920750415

  日期：1992.6.24

  Photolysis of (o-allylbenzyl)dicarbonyl(η5-cyclopentadienyl)iron (4) at 20° in CH2Cl2 leads to carbon-monoxide loss followed by intramolecular complexation to [η2-(o-allylbenzyl)]carbonyl(η5-cyclopentadienyl)iron (13). At 50° in C6D6, a photochemical rearrangement proceeds forming carbonyl (η5-cyclopentadienyl)η3-[3-(2-methylphenyl)allyl]}iron (17). Depending on the temperature, photolysis of 4 leads

  的（光解ö -allylbenzyl）二羰基（η 5 -环戊二烯基）铁（4 20）°的CH 2氯2所导致一氧化碳损失，随后分子内络合[η 2 - （ø -allylbenzyl）]羰基（η 5-环戊二烯基）铁（13）。在用C 50° 6 d 6，光化学重排进行形成羰基（η 5 -环戊二烯基）η 3 - [3-（2-甲基苯基）烯丙基]}铁（17）。根据温度，光解4分别导致π配合物13和17的苄基或烯丙基位置的分子间反应。
• CYCLOHEXANE POLYCARBOXYLIC ACID DERIVATIVES AS PLASTICIZERS FOR ADHESIVES AND SEALANTS
  申请人：Mack Helmut

  公开号：US20110232825A1

  公开（公告）日：2011-09-29

  The invention provides an adhesive or sealant comprising at least (A) one compound selected from the group consisting of silylated polyurethanes, silylated polyureas, silylated polyethers, silylated polysulfides and silyl-terminated acrylates, and at least (B) one cyclohexane polycarboxylic acid derivative. The composition has enhanced extensibility with good adhesion properties and high tensile strength. A process is disclosed for preparing the adhesive or sealant, and also disclosed is the use thereof for producing material bonds between parts to be joined.

  本发明提供了一种粘合剂或密封剂，包括至少（A）从包括硅化聚氨酯、硅化聚氨基甲酸酯、硅化聚醚、硅化聚硫化物和硅基终止丙烯酸酯的群组中选择的一种化合物，以及至少（B）一种环己烷聚羧酸衍生物。该组合物具有良好的粘附性和高拉伸强度的增强延展性。还公开了制备粘合剂或密封剂的过程，并公开了将其用于在要连接的零件之间产生材料粘结的用途。
• Polyalkylene oxide having unsaturated end group and narrow molecular weight distribution
  申请人：KANEGAFUCHI KAGAKU KOGYO KABUSHIKI KAISHA

  公开号：EP0196565A1

  公开（公告）日：1986-10-08

  polyalkylene oxide having unsaturated end groups. The polymer has a distribution of molecular weight Mw/Mn of not more than 1.5, and a process for the same. The polymer is useful as rubber materials, and can provide cured rubber having an excellent elongation.

  具有不饱和端基的聚环氧烷。该聚合物的分子量分布 Mw/Mn 不大于 1.5，并有相同的工艺。该聚合物可用作橡胶材料，并能提供具有出色伸长率的硫化橡胶。