(S)-1-Bromo-6-methyl-tetradecane | 285141-89-1

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机溴化物
• 英文名称: (S)-1-Bromo-6-methyl-tetradecane
• 英文别名: (s)-6-Methyl-1-bromotetradecane；(6S)-1-bromo-6-methyltetradecane
• CAS: 285141-89-1
• 化学式: C₁₅H₃₁Br
• 分子量: 291.315
• InChiKey: VJJZXOLNIVWQEG-HNNXBMFYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.9
• 重原子数：
  16
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (S)-1-Bromo-6-methyl-tetradecane 在 lithium aluminium tetrahydride 、 正丁基锂 作用下， 以 四氢呋喃 、 六甲基磷酰三胺 、 正己烷 、 二乙二醇二甲醚 为溶剂， 生成 (6Z,13R)-methylheneicosene
  参考文献：
  名称：

  摘要：

  The major component of the female-produced sex pheromone of Scoliopteryx libatrix has been characterized by chemical analysis, synthesis, electrophysiological studies and field tests as (6Z,13)-methylheneicosene, probably the 13S-isomer. This is the first example of a branched chain alkene as a sex pheromone in the Noctuidae and is markedly different from the pheromones of other members of the family. The systematic position of S. libatrix, belonging to a monotypic genus of a one-member subfamily within the Noctuidae, may reflect the unusual structure of the sex pheromone.

  DOI：

  10.1023/a:1005475725742
• 作为产物：
  描述：

  (2S)-methyl-3-decen-1-ol 在 palladium on activated charcoal 正丁基锂 、 氢气 、 溴 、 三苯基膦 作用下， 以 四氢呋喃 、 正己烷 、 二氯甲烷 、 甲苯 为溶剂， 生成 (S)-1-Bromo-6-methyl-tetradecane
  参考文献：
  名称：

  摘要：

  The major component of the female-produced sex pheromone of Scoliopteryx libatrix has been characterized by chemical analysis, synthesis, electrophysiological studies and field tests as (6Z,13)-methylheneicosene, probably the 13S-isomer. This is the first example of a branched chain alkene as a sex pheromone in the Noctuidae and is markedly different from the pheromones of other members of the family. The systematic position of S. libatrix, belonging to a monotypic genus of a one-member subfamily within the Noctuidae, may reflect the unusual structure of the sex pheromone.

  DOI：

  10.1023/a:1005475725742