tridecafluorotetradec-7-yne | 1256917-96-0

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 英文名称: tridecafluorotetradec-7-yne
• 英文别名: perfluoro(7-tetradecyne)；1,1'-Ethynylenebis(1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexane)；1,1,1,2,2,3,3,4,4,5,5,6,6,9,9,10,10,11,11,12,12,13,13,14,14,14-hexacosafluorotetradec-7-yne
• CAS: 1256917-96-0
• 化学式: C₁₄F₂₆
• 分子量: 662.112
• InChiKey: RGVHGTNTYGCAQH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.2
• 重原子数：
  40
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  26

反应信息

• 作为反应物：
  描述：

  tridecafluorotetradec-7-yne 在 溴 、 2,4,6-三甲基苯甲腈N-氧化物 作用下， 以 乙醚 、 二氯甲烷 为溶剂， 反应 92.0h， 生成 2,5-dibromo-3,4-bis(tridecafluorohexyl)-1H-pyrrole
  参考文献：
  名称：

  通过单个NH部分将小β-全氟烷基取代的吡咯作为阴离子响应的小π电子系统

  摘要：

  合成了在小β位具有两个全氟己基（C6F13）链的吡咯衍生物。β-全氟烷基小链的显着吸电子特性引起了令人着迷的阴离子结合行为。

  DOI：

  10.1039/c6cc03619h
• 作为产物：
  描述：

  1H-全氟-1-辛炔 在 potassium hydroxide 作用下， 60.0~220.0 ℃ 、689.49 kPa 条件下， 反应 4.0h， 生成 tridecafluorotetradec-7-yne
  参考文献：
  名称：

  Compositions, methods, and systems comprising fluorous-soluble polymers

  摘要：

  本发明通常涉及包含能够在氟烃相和非氟烃相之间溶解或组织的聚合物的组合物、方法和系统。在某些实施例中，提供了包含聚合物的乳液或薄膜。这些聚合物、乳液和薄膜可用于许多应用，包括用于确定、治疗和/或成像受试者的状况和/或疾病。聚合物还可以被纳入各种光电器件中，例如光伏电池、有机发光二极管、有机场效应晶体管等。在某些实施例中，这些聚合物包括π-共轭主链，并且在某些情况下具有高发光性。

  公开号：

  US09156938B2

文献信息

• COMPOSITIONS, METHODS, AND SYSTEMS COMPRISING FLUOROUS-SOLUBLE POLYMERS
  申请人：Swager Timothy M.

  公开号：US20120177578A1

  公开（公告）日：2012-07-12

  The present invention generally relates to compositions, methods, and systems comprising polymers that are fluorous-soluble and/or organize at interfaces between a fluorous phase and a non-fluorous phase. In some embodiments, emulsions or films are provided comprising a polymer. The polymers, emulsions, and films can be used in many applications, including for determining, treating, and/or imaging a condition and/or disease in a subject. The polymer may also be incorporated into various optoelectronic device such as photovoltaic cells, organic light-emitting diodes, organic field effect transistors, or the like. In some embodiments, the polymers comprise pi-conjugated backbones, and in some cases, are highly emissive.

  本发明通常涉及包含聚合物的组合物、方法和系统，该聚合物是可以在氟化物相和非氟化物相之间界面上溶解或组织的。在某些实施例中，提供了包含聚合物的乳液或薄膜。这些聚合物、乳液和薄膜可以用于许多应用，包括用于确定、治疗和/或成像受试者的状况和/或疾病。该聚合物也可以被纳入各种光电器件中，如光伏电池、有机发光二极管、有机场效应晶体管等。在某些实施例中，该聚合物包括π-共轭骨架，并且在某些情况下，具有高发光性。
• Fluorous Biphase Synthesis of a Poly(p-phenyleneethynylene) and its Fluorescent Aqueous Fluorous-Phase Emulsion
  作者：Jeewoo Lim、Timothy M. Swager

  DOI：10.1002/anie.201003111

  日期：——

  highly fluorinated compound with a rigid three‐dimensional architecture was synthesized as a monomer for poly(p‐phenyleneethynylene)s (PPEs). Fluorous biphase reactions were applied for the synthesis of a PPE that is soluble only in fluorous solvents. A fluorous solution of the polymer could be processed into aqueous emulsions that display high fluorescence quantum yields (see picture).

  这只是一个阶段：合成了具有刚性三维结构的高度氟化的化合物，作为聚对苯撑乙炔撑（PPE）的单体。荧光双相反应用于合成仅可溶于氟溶剂的PPE。可以将聚合物的氟溶液加工成具有高荧光量子产率的水性乳液（参见图片）。
• US9156938B2
  申请人：——

  公开号：US9156938B2

  公开（公告）日：2015-10-13
• [EN] COMPOSITIONS, METHODS, AND SYSTEMS COMPRISING FLUOROUS-SOLUBLE POLYMERS<br/>[FR] COMPOSITIONS, PROCÉDÉS, ET SYSTÈMES COMPRENANT DES POLYMÈRES SOLUBLES DANS LE FLUOR
  申请人：MASSACHUSETTS INST TECHNOLOGY

  公开号：WO2012024592A2

  公开（公告）日：2012-02-23

  The present invention generally relates to compositions, methods, and systems comprising polymers that are fhiorous- soluble and/or organize at interfaces between a fhiorous phase and a non-fluorous phase. In some embodiments, emulsions or films are provided comprising a polymer. The polymers, emulsions, and films can be used in many applications, including for determining, treating, and/or imaging a condition and/or disease in a subject. The polymer may also be incorporated into various optoelectronic device such as photovoltaic cells, organic light-emitting diodes, organic field effect transistors, or the like. In some embodiments, the polymers comprise pi-conjugated backbones, and in some cases, are highly emissive.
• Compositions, methods, and systems comprising fluorous-soluble polymers
  申请人：Swager Timothy M.

  公开号：US09156938B2

  公开（公告）日：2015-10-13

  The present invention generally relates to compositions, methods, and systems comprising polymers that are fluorous-soluble and/or organize at interfaces between a fluorous phase and a non-fluorous phase. In some embodiments, emulsions or films are provided comprising a polymer. The polymers, emulsions, and films can be used in many applications, including for determining, treating, and/or imaging a condition and/or disease in a subject. The polymer may also be incorporated into various optoelectronic device such as photovoltaic cells, organic light-emitting diodes, organic field effect transistors, or the like. In some embodiments, the polymers comprise pi-conjugated backbones, and in some cases, are highly emissive.

  本发明通常涉及包含能够在氟烃相和非氟烃相之间溶解或组织的聚合物的组合物、方法和系统。在某些实施例中，提供了包含聚合物的乳液或薄膜。这些聚合物、乳液和薄膜可用于许多应用，包括用于确定、治疗和/或成像受试者的状况和/或疾病。聚合物还可以被纳入各种光电器件中，例如光伏电池、有机发光二极管、有机场效应晶体管等。在某些实施例中，这些聚合物包括π-共轭主链，并且在某些情况下具有高发光性。