4-Phenyl-1,3-dithiole | 15112-40-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-Phenyl-1,3-dithiole
• 英文别名: 4-Phenyl-2H-1,3-dithiole
• CAS: 15112-40-0
• 化学式: C₉H₈S₂
• 分子量: 180.295
• InChiKey: WEEWCEPQHUKCDY-UHFFFAOYSA-N

物化性质

• 熔点：
  45-46 °C
• 沸点：
  325.5±42.0 °C(Predicted)
• 密度：
  1.259±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  50.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-Phenyl-1,3-dithiole 以 乙腈 为溶剂， 以13%的产率得到4,4'-diphenyl tetrathiafulvalene
  参考文献：
  名称：

  Oxidative electrodimerization of 1,3-dithioles to tetrathiafulvalenes

  摘要：

  DOI：

  10.1021/jo00176a037
• 作为产物：
  描述：

  Chloromethylsulfanylethynyl-benzene 在 sodium sulfide 作用下， 以 甲醇 、 N,N-二甲基甲酰胺 为溶剂， 反应 9.0h， 以85%的产率得到4-Phenyl-1,3-dithiole
  参考文献：
  名称：

  Sukhai, R. S.; Verboom, W.; Meijer, J., Recueil des Travaux Chimiques des Pays-Bas, 1981, vol. 100, # 1, p. 10 - 13

  摘要：

  DOI：

文献信息

• Modified halogenated polyolefin adhesives
  申请人：LORD CORPORATION

  公开号：EP0489495A2

  公开（公告）日：1992-06-10

  An adhesive composition useful for bonding thermoplastic elastomers to substrates such as metal that contains a halogenated polyolefin that has been chemically modified to contain a polyhydroxylic aromatic compound and/or a sulfur-containing compound. The modified polyolefin is preferably prepared by first reacting the polyolefin with an acid anhydride and then reacting the anhydride-modified polyolefin with the polyhydroxylic aromatic compound and/or the sulfur-containing compound.

  一种用于将热塑性弹性体粘合到金属等基材上的粘合剂组合物，它含有一种卤化聚烯烃，该聚烯烃经过化学改性，含有一种多羟基芳香族化合物和/或一种含硫化合物。改性聚烯烃的制备方法最好是先使聚烯烃与酸酐反应，然后使酸酐改性的聚烯烃与多羟基芳香族化合物和/或含硫化合物反应。
• RESIN COMPOSITION, GATE INSULATING LAYER AND ORGANIC THIN FILM TRANSISTOR
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2320467A1

  公开（公告）日：2011-05-11

  The subject of the present invention is to provide an organic thin film transistor with a small hysteresis. The means for solving the subject is a resin composition for an organic thin film transistor gate insulating layer comprising (A) a macromolecule that comprises at least one repeating unit selected from the group consisting of repeating units represented by Formula (1), repeating units represented by Formula (1'), and repeating units represented by Formula (2) and contains two or more first functional groups in its molecule, wherein the first functional group is a functional group that generates, by the action of electromagnetic waves or heat, a second functional group that reacts with active hydrogen, and (B) at least one compound selected from the group consisting of low-molecular compounds containing two or more active hydrogens in each molecule and macromolecules containing two or more active hydrogens in each molecule.

  本发明的目的是提供一种滞后小的有机薄膜晶体管。解决该课题的方法是一种用于有机薄膜晶体管栅极绝缘层的树脂组合物，该树脂组合物包括 (A) 由至少一个重复单元组成的大分子，该重复单元选自由式（1）表示的重复单元、式（1'）表示的重复单元和式（2）表示的重复单元组成的组，并在其分子中含有两个或两个以上的第一官能团、其中第一官能团是在电磁波或热的作用下产生与活性氢反应的第二官能团的官能团，以及 (B) 至少一种化合物，选自由每个分子中含有两个或两个以上活性氢的低分子化合物和每个分子中含有两个或两个以上活性氢的大分子组成的组。
• POLYMER MATERIAL AND METHOD FOR MANUFACTURING SAME
  申请人：Osaka University

  公开号：EP3760646A1

  公开（公告）日：2021-01-06

  Provided are a macromolecular material that can form various structures, and that exhibits excellent toughness and strength; and a method for producing the macromolecular material. The macromolecular material includes in a polymer chain thereof a structural unit represented by the following formula (1):         -R1-RH     (1) (R1 represents NH or O, and RH represents a host group), wherein the host group is a monovalent group formed by removing one hydrogen atom or hydroxy group from a cyclodextrin derivative, and the cyclodextrin derivative has a structure formed such that a hydrogen atom of at least one hydroxy group contained in a cyclodextrin is replaced with at least one group selected from the group consisting of a hydrocarbon group, an acyl group, and -CONHR (R represents a methyl group or an ethyl group).

  本发明提供了一种可形成各种结构、具有优异韧性和强度的高分子材料，以及生产该高分子材料的方法。该高分子材料在其聚合物链中包括由下式（1）表示的结构单元： -R1-RH (1) (R1代表NH或O，RH代表主基)，其中主基是从环糊精衍生物中除去一个氢原子或羟基而形成的单价基团，环糊精衍生物具有这样一种结构，即环糊精中所含至少一个羟基的氢原子被至少一个选自烃基，酰基和-CONHR(R代表甲基或乙基)的基团所取代。
• CATALYST FOR HYDROGENATION REACTION AND METHOD FOR PRODUCING SAME
  申请人：LG Chem, Ltd.

  公开号：EP3909676A1

  公开（公告）日：2021-11-17

  A catalyst for a hydrogenation reaction according to an exemplary embodiment of the present application comprises: a polymer support; and a catalytic component supported on the polymer support, in which the polymer support comprises a repeating unit represented by the following Formula 1 or 2.

  根据本申请的一个示例性实施方案，一种用于氢化反应的催化剂包括：聚合物载体；以及支撑在聚合物载体上的催化组分，其中聚合物载体包括由下式 1 或 2 表示的重复单元。
• Oxidation-reduction reactions of 1,3-dithioles and their ions
  作者：L. P. Yunnikova、T. V. Makhova

  DOI：10.1007/s10593-006-0272-2

  日期：2006.11