4,4'-diphenyl tetrathiafulvalene | 100760-33-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,4'-diphenyl tetrathiafulvalene
• 英文别名: cis-DPh-TTF；Diphenyltetrathiafulvalen；4,4'-DI-Phenyl-tetrathiafulvalene；(2Z)-4-phenyl-2-(4-phenyl-1,3-dithiol-2-ylidene)-1,3-dithiole
• CAS: 100760-33-6
• 化学式: C₁₈H₁₂S₄
• 分子量: 356.557
• InChiKey: UXYULNILNJCKTO-ZCXUNETKSA-N

物化性质

• 沸点：
  462.9±45.0 °C(Predicted)
• 密度：
  1.430±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  22
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  101
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1-(4-苯基-1,3-二硫醇-2-基)哌啶 在 溶剂黄146 、 三氯乙酸 作用下， 以 苯 为溶剂， 反应 4.0h， 生成 4,4'-diphenyl tetrathiafulvalene
  参考文献：
  名称：

  Buza, Daniela; Gradowska, Wanda, Polish Journal of Chemistry, 1984, vol. 58, # 7-8-9, p. 775 - 782

  摘要：

  DOI：

文献信息

• Synthesis and electrochemical studies of tetrathiafulvalene derivatives (TTFs) as redox active ligands
  作者：Abd El-Wareth A. O. Sarhan、Makoto Murakami、Taeko Izumi

  DOI：10.1002/jhet.5570390413

  日期：2002.7

  simple route for synthesis of new tetrathiafulvalene dimethyl ester (TTF-DME) is reported. The tetrathifulvalene dimethylester (TTF-DME) has been prepared by introducing an ester coordination function as a bifunctional new donor. The redox behavior of the TTF-DME was investigated in comparison to the well-known dibenzotetrathiafulvene (DB-TTF) by cyclic voltammetry. A two-electron redox behavior was observed

  报道了合成新的四硫富瓦烯二甲基酯（TTF-DME）的简单途径。四硫富瓦烯二甲酯（TTF-DME）是通过引入酯配位官能团作为双功能新供体而制备的。通过循环伏安法，与已知的二苯并四硫富烯（DB-TTF）相比，研究了TTF-DME的氧化还原行为。观察到两波的两电子氧化还原行为。
• ACCUMULATOR MATERIAL AND ACCUMULATOR DEVICE
  申请人：Hojo Nobuhiko

  公开号：US20110091767A1

  公开（公告）日：2011-04-21

  An electricity storage device including a positive electrode 31 , a negative electrode 32 , and an electrolytic solution 29 located between the positive electrode and the negative electrode. At least one of the positive electrode 31 and the negative electrode 32 contains an electricity storage material containing a polymerization product having a tetrachalcogenofulvalene structure in a repeat unit of a main chain.

  一种电力储存装置，包括正极31、负极32和位于正极和负极之间的电解质29。正极31和负极32中的至少一个包含一种电力储存材料，该电力储存材料包含一个具有四硫属富瓦烯结构的聚合物化合物，在主链的重复单元中。
• POLYMER, SEMICONDUCTOR FILM, ELECTRODE, ELECTRODE ACTIVE MATERIAL, ELECTROCHEMICAL ELEMENT AND ELECTRICITY STORAGE DEVICE
  申请人：Panasonic Corporation

  公开号：EP2308912A1

  公开（公告）日：2011-04-13

  A polymer having a structure represented by the following general formula (1), wherein in general formula (1), Ph is a phenyl group; X is an oxygen atom, a sulfur atom, a selenium atom or a tellurium atom; and R1 and R1 each independently contains at least one selected from the group consisting of a chained saturated hydrocarbon group, a chained unsaturated hydrocarbon group, a cyclic saturated hydrocarbon group, a cyclic unsaturated hydrocarbon group, a phenyl group, a hydrogen atom, a hydroxyl group, a cyano group, an amino group, a nitro group and a nitroso group. The chained saturated hydrocarbon group, the chained unsaturated hydrocarbon group, the cyclic saturated hydrocarbon group and the cyclic unsaturated hydrocarbon group each contain at least one selected from the group consisting of a carbon atom, an oxygen atom, a nitrogen atom, a sulfur atom and a silicon atom.

  一种具有以下通式（1）所代表结构的聚合物，其中在通式（1）中，Ph 是苯基；X 是氧原子、硫原子、硒原子或碲原子；R1和R1各自独立地包含至少一个选自以下组成的组的基团：链状饱和烃基、链状不饱和烃基、环状饱和烃基、环状不饱和烃基、苯基、氢原子、羟基、氰基、氨基、硝基和亚硝基。链状饱和烃基、链状不饱和烃基、环状饱和烃基和环状不饱和烃基各自含有至少一个选自碳原子、氧原子、氮原子、硫原子和硅原子的基团。
• Electrochemical energy storage devices
  申请人：GENTEX CORPORATION

  公开号：US10481456B2

  公开（公告）日：2019-11-19

  An energy storage device includes a cathodic material in an activated state; and an anodic material in an activated state; wherein: the cathodic material is a viologen covalently attached to, or confined within, a first polymer matrix, the first polymer matrix is configured to prevent or minimize substantial diffusion of the cathodic material in the activated state; and the anodic material is a phenazine, a phenothiazine, a triphenodithiazine, a carbazole, a indolocarbazole, a biscarbazole, or a ferrocene covalently attached to, or confined within, a second polymer matrix, the second polymer matrix is configured to prevent or minimize substantial diffusion of the anodic material in the activated state.

  一种储能装置包括处于活化状态的阴极材料；以及处于活化状态的阳极材料；其中阴极材料是共价连接到第一聚合物基体上或限制在第一聚合物基体内的紫胶，第一聚合物基体被配置为防止或最大限度地减少阴极材料在活化状态下的实质性扩散；阳极材料是吩嗪、吩噻嗪、三苯并噻嗪、咔唑、吲哚咔唑、双咔唑或二茂铁，共价连接到第二聚合物基体上或封闭在第二聚合物基体内，第二聚合物基体的配置可防止或尽量减少阳极材料在活化状态下的大量扩散。
• Buza, Daniela; Gradowska, Wanda, Polish Journal of Chemistry, 1980, vol. 54, # 1, p. 145 - 147
  作者：Buza, Daniela、Gradowska, Wanda

  DOI：——

  日期：——